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Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State [Latest edition]

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Chapters

Physical Chemistry

▶ 1: Solid State

    2: Solutions

    3: Electrochemistry

    4: Chemical Kinetics

    5: Surface Chemistry

Inorganic Chemistry

    6: General Principles and Processes of Isolation of Elements

    7: p-Block Elements

    8: d-and ƒ-Block Elements

    9: Coordination Compounds

Organic Chemistry

    10: Haloalkanes and Haloarenes

   Chapter 11: Alcohols, Phenols and Ethers

   Chapter 12: Aldehydes, Ketones and Carboxylic Acids

   Chapter 13: Organic Compounds containing Nitrogen

   Chapter 14: Biomolecules

    15: Polymers

   Chapter 16: Chemistry in Everyday Life

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State - Shaalaa.com
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Solutions for Chapter 1: Solid State

Below listed, you can find solutions for Chapter 1 of CISCE Nootan for Chemistry Part 1 and 2 [English] Class 12 ISC.


REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSINTEGER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNUMERICAL PROBLEMS'NCERT TEXT-BOOK' ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
REVIEW EXERCISES [Pages 21 - 37]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State REVIEW EXERCISES [Pages 21 - 37]

REVIEW EXERCISES | Q 1.1 (i) | Page 21

What do you understand by unit cell?

REVIEW EXERCISES | Q 1.1 (ii) | Page 21

What parameters are used to describe a unit cell?

REVIEW EXERCISES | Q 1.2 | Page 21

Which crystal system can possess all the four types of unit cell?

REVIEW EXERCISES | Q 1.3 | Page 21

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

REVIEW EXERCISES | Q 1.4 | Page 21

Calculate the number of atoms in a cubic based unit cell having one atom at each corner and two atoms on each diagonal.

REVIEW EXERCISES | Q 1.5 | Page 21

A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?

REVIEW EXERCISES | Q 1.6 (a) | Page 21

How many atoms of an element are there in one unit cell of simple cubic?

REVIEW EXERCISES | Q 1.6 (b) | Page 21

How many atoms of an element are there in one unit cell of body-centred cubic?

REVIEW EXERCISES | Q 1.6 (c) | Page 21

How many atoms constitute one unit cell of a face-centered cubic crystal?

REVIEW EXERCISES | Q 1.7 | Page 21

The density of a face-centred cubic element (atomic mass = 60.2) is 6.25 g cm−1. Calculate the length of the edge of the unit cell.

REVIEW EXERCISES | Q 1.8 | Page 21

Crystalline CsBr has a bcc structure. Calculate the unit cell edge length if the density of CsBr crystal is 4.24 g cm−3. (Atomic masses: Cs = 133; Br =  80)

REVIEW EXERCISES | Q 1.9 | Page 21

An element has bcc structure with a cell edge of 288 pm. The density of the element is 7.2 g cm−3. How many atoms are present in 208 g of the element?

REVIEW EXERCISES | Q 1.10 | Page 21

The density of KBr is 2.75 g cm−3. The length of the edge of the unit cell is 654 pm. Show that KBr has a face-centred cubic structure (NA = 6.022 × 1023 mol−1, Atomic masses : K = 39, Br = 80).

REVIEW EXERCISES | Q 1.11 | Page 22

A solid is made up of two elements P and Q. Atoms Q are in hcp arrangement while atoms P occupy all the tetrahedral sites. What is the formula of the compound?

REVIEW EXERCISES | Q 1.12 | Page 22

In an oxide of aluminium, oxide ions are arranged in ccp arranged and the aluminium ions occupy two third of the octahedral voids. What is the formula of the compound?

REVIEW EXERCISES | Q 1.13 | Page 22

In a solid, oxide ions are arranged in hcp. One third of octahedral voids are occupied by the cations A and one sixth of the tetrahedral voids are occupied by the cations B. What is the formula of the compound?

REVIEW EXERCISES | Q 1.14 | Page 22

In a closed packed structure of mixed oxides, the oxide ions are arranged in hcp array. One eighth of tetrahedral voids are occupied by divalent cations (A) while one half of octahedral voids are occupied by trivalent cations (B). What is the formula of the compound?

REVIEW EXERCISES | Q 1.15 | Page 26

Why are molecular solids soft and possess low melting and boiling points?

REVIEW EXERCISES | Q 1.16 | Page 26

What are the constituent particles in ionic solids and how are they held together?

REVIEW EXERCISES | Q 1.17 | Page 26

Sort out the molecular, ionic and covalent solids from the following:

Naphthalene, ZnS, graphite, ice, Agl, silicon carbide.

REVIEW EXERCISES | Q 1.18 | Page 26

What is the significance of radius ratio in deciding the structural arrangement in an ionic solid?

REVIEW EXERCISES | Q 1.19 | Page 26

What is the coordination number of NaCl crystal structure?

REVIEW EXERCISES | Q 1.20 | Page 26

Why are the properties of diamond very different from those of graphite although both are the different forms of the same substance?

REVIEW EXERCISES | Q 1.21 (i) | Page 26

Explain the lubricating property of graphite on the basis of its structure.

REVIEW EXERCISES | Q 1.21 (ii) | Page 26

Describe the structure of graphite with the help of a labelled diagram.

REVIEW EXERCISES | Q 1.22 | Page 26

Discuss the crystal structure of copper metal.

REVIEW EXERCISES | Q 1.23 | Page 26

Why do metals possess lustre and conduct electric current?

REVIEW EXERCISES | Q 1.24 (i) | Page 26

Write a short note on isomorphism.

REVIEW EXERCISES | Q 1.24 (ii) | Page 26

Write a short note on isopolymorphism.

REVIEW EXERCISES | Q 1.25 | Page 31

Define point defects in solids.

REVIEW EXERCISES | Q 1.26 | Page 31

What is Schottky defect in a solid?

REVIEW EXERCISES | Q 1.27 | Page 31

What is the effect of the presence of Schottky defects on the density of a crystal?

REVIEW EXERCISES | Q 1.28 | Page 31

What are F-centres?

REVIEW EXERCISES | Q 1.29 | Page 31

Pure silicon does not conduct electricity. How can it be made a conductor of electricity? Explain with examples.

REVIEW EXERCISES | Q 1.30 | Page 31

AgCl is doped with 10−2 mol% of CdCl2. Find the concentration of cation vacancies.

REVIEW EXERCISES | Q 1.31 | Page 31

What other element may be added to silicon to make electrons available for conduction of an electric current?

REVIEW EXERCISES | Q 1.32 | Page 31

What is the non-stoichiometry defect in crystals?

REVIEW EXERCISES | Q 1.33 | Page 32

Why does Frenkel defect not change the density of AgCl crystals?

REVIEW EXERCISES | Q 1.34 | Page 32

State the difference between Schottky and Frenkel defects. Which of these two changes the density of the solid?

REVIEW EXERCISES | Q 1.35 | Page 32

Name a salt that can be added to AgCl so as to produce cation vacancies.

REVIEW EXERCISES | Q 1.36 | Page 32

Which point defect lowers the density of a crystal?

REVIEW EXERCISES | Q 1.37 | Page 32

Name a salt that can be added to AgCl so as to produce cation vacancies.

REVIEW EXERCISES | Q 1.38 | Page 32

What makes alkali metal halides sometimes coloured, which are otherwise colourless?

REVIEW EXERCISES | Q 1.39 | Page 32

Why does table salt, NaCl, sometimes appear yellow in colour?

REVIEW EXERCISES | Q 1.40 (i) | Page 32

What is a semiconductor?

REVIEW EXERCISES | Q 1.40 (ii) | Page 32

Describe the two main types of semiconductors and contrast their conduction mechanism.

REVIEW EXERCISES | Q 1.41 | Page 32

What type of crystal defect is produced when sodium chloride is doped with MgCl2?

REVIEW EXERCISES | Q 1.42 (i) | Page 37

Name the electrical property possessed by the following oxide:

TiO

REVIEW EXERCISES | Q 1.42 (ii) | Page 37

Name the electrical property possessed by the following oxide:

Ti2O3

REVIEW EXERCISES | Q 1.42 (iii) | Page 37

Name the electrical property possessed by the following oxide:

TiO2

REVIEW EXERCISES | Q 1.42 (iv) | Page 37

Name the electrical property possessed by the following oxide:

CrO2

REVIEW EXERCISES | Q 1.42 (v) | Page 37

Name the electrical property possessed by the following oxide: 

Cr2O3

REVIEW EXERCISES | Q 1.43 | Page 37

Sort out the diamagnetic, paramagnetic and ferromagnetic substances among the following:

O2, Fe, TiO2, Cu2+, Fe3+, Ni, CrO2, C6H6, NaCl.

REVIEW EXERCISES | Q 1.44 (i) | Page 37

What are paramagnetic substances?

REVIEW EXERCISES | Q 1.44 (ii) | Page 37

What are ferromagnetic substances?

REVIEW EXERCISES | Q 1.44 (iii) | Page 37

Account for the paramagnetic character of transition metal compounds.

REVIEW EXERCISES | Q 1.44 (iv) | Page 37

How does the paramagnetic character of the bivalent ions of first transition metal series vary from titanium (Z = 22) to copper (Z = 29)?

REVIEW EXERCISES | Q 1.45 (i) | Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Semiconductor

REVIEW EXERCISES | Q 1.45 (ii) | Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Metallic conductor

REVIEW EXERCISES | Q 1.45 (iii) | Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Superconductor

REVIEW EXERCISES | Q 1.46 | Page 37

Name any two superconducting materials which show superconductivity above 100 K.

REVIEW EXERCISES | Q 1.47 | Page 37

Compare dia, para and ferromagnetism.

REVIEW EXERCISES | Q 1.48 | Page 37

Explain the dielectric properties of solids.

REVIEW EXERCISES | Q 1.49 | Page 37

Distinguish between crystalline solid and amorphous solid.

REVIEW EXERCISES | Q 1.50 | Page 37

How would you convert a crystalline solid into an amorphous solid?

REVIEW EXERCISES | Q 1.51 | Page 37

What is the difference between ferromagnetic and ferrimagnetic substances?

REVIEW EXERCISES | Q 1.52 | Page 37

What is the utility of piezoelectric crystals?

REVIEW EXERCISES | Q 1.53 | Page 37

What happens when ferrimagnetic Fe3O4 is heated at 850 K and why?

REVIEW EXERCISES | Q 1.54 (i) | Page 37

What are amorphous solids?

REVIEW EXERCISES | Q 1.54 (ii) | Page 37

Discuss the properties of amorphous solids.

REVIEW EXERCISES | Q 1.54 (iii) | Page 37

Discuss the uses of amorphous solids.

VERY SHORT ANSWER TYPE QUESTIONS [Pages 42 - 43]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State VERY SHORT ANSWER TYPE QUESTIONS [Pages 42 - 43]

VERY SHORT ANSWER TYPE QUESTIONS | Q 1. | Page 42

What type of solids do possess a long range order?

VERY SHORT ANSWER TYPE QUESTIONS | Q 2. | Page 42

Name different types of crystalline solids.

VERY SHORT ANSWER TYPE QUESTIONS | Q 3. (i) | Page 42

Define the term space lattice.

VERY SHORT ANSWER TYPE QUESTIONS | Q 3. (ii) | Page 42

Define lattice points.

VERY SHORT ANSWER TYPE QUESTIONS | Q 4. | Page 42

What do you understand by unit cell?

VERY SHORT ANSWER TYPE QUESTIONS | Q 5. | Page 42

How many atoms of an element are there in one unit cell of simple cubic?

VERY SHORT ANSWER TYPE QUESTIONS | Q 6. | Page 42

What do you understand by a face-centred unit cell?

VERY SHORT ANSWER TYPE QUESTIONS | Q 7. | Page 42

What is a body-centred cubic system?

VERY SHORT ANSWER TYPE QUESTIONS | Q 8. | Page 42

How many atoms constitute one unit cell of a face-centered cubic crystal?

VERY SHORT ANSWER TYPE QUESTIONS | Q 9. | Page 42

What is the percentage of the occupied space in a simple cubic unit cell?

VERY SHORT ANSWER TYPE QUESTIONS | Q 10. | Page 42

What is the name of the unit cell in which the atoms are present at the corners of all 12 edges of a cube in a unit cell?

VERY SHORT ANSWER TYPE QUESTIONS | Q 11. | Page 42

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

VERY SHORT ANSWER TYPE QUESTIONS | Q 12. | Page 42

What is the edge length of a face-centred cubic unit cell if the radius of the atom is r?

VERY SHORT ANSWER TYPE QUESTIONS | Q 13. | Page 42

What is the coordination number in a two dimensional hexagonal close packing?

VERY SHORT ANSWER TYPE QUESTIONS | Q 14. | Page 42

What is a void?

VERY SHORT ANSWER TYPE QUESTIONS | Q 15. (i) | Page 42

What is the coordination number of atoms in a cubic close-packed structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 15. (ii) | Page 42

What is the coordination number in a close-packed structure (hcp)?

VERY SHORT ANSWER TYPE QUESTIONS | Q 16. | Page 42

What is the coordination number of atoms in a bcc structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 17. | Page 42

Define a tetrahedral void.

VERY SHORT ANSWER TYPE QUESTIONS | Q 18. (i) | Page 42

If a close-packed structure contains n particles, what would be the number of tetrahedral voids in the structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 18. (ii) | Page 42

If a close-packed structure contains n particles, what would be the number of octahedral voids in the structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 19. | Page 42

If the radius of a particle is R, what would be the radius of a tetrahedral void present in the close-packed structure of the given particles?

VERY SHORT ANSWER TYPE QUESTIONS | Q 20. | Page 42

What is the ratio of the radius of an octahedral void to that of the constituent particle?

VERY SHORT ANSWER TYPE QUESTIONS | Q 21. | Page 42

In an ionic crystal, the radius ratio is greater than 0.732. What is the coordination number of the crystal?

VERY SHORT ANSWER TYPE QUESTIONS | Q 22. | Page 42

In the crystal of zinc sulphide, zinc occupies tetrahedral voids. What is the coordination number of zinc?

VERY SHORT ANSWER TYPE QUESTIONS | Q 23. | Page 42

What type of close-packing is possessed by a crystal of NaCl?

VERY SHORT ANSWER TYPE QUESTIONS | Q 24. (i) | Page 42

Name the ions forming the close-packed structure in NaCl crystals.

VERY SHORT ANSWER TYPE QUESTIONS | Q 24. (ii) | Page 42

Name the ions present in voids in NaCl crystals.

VERY SHORT ANSWER TYPE QUESTIONS | Q 25. | Page 42

What is Schottky defect in a solid?

VERY SHORT ANSWER TYPE QUESTIONS | Q 26. | Page 42

What do you understand by the fact that CaF2 has 8 : 4 coordination?

VERY SHORT ANSWER TYPE QUESTIONS | Q 27. | Page 42

What are electronic imperfections in crystals?

VERY SHORT ANSWER TYPE QUESTIONS | Q 28. | Page 42

What type of ionic compounds show Schottky defects?

VERY SHORT ANSWER TYPE QUESTIONS | Q 29. | Page 42

Write the effect on density of a substance in the Frenkel defect?

VERY SHORT ANSWER TYPE QUESTIONS | Q 30. | Page 42

What are F-centres?

VERY SHORT ANSWER TYPE QUESTIONS | Q 31. | Page 42

What do you understand by doping of a crystal?

VERY SHORT ANSWER TYPE QUESTIONS | Q 32. | Page 42

What is a semiconductor?

VERY SHORT ANSWER TYPE QUESTIONS | Q 33. | Page 42

How do paramagnetic substances behave in the absence of a magnetic field?

VERY SHORT ANSWER TYPE QUESTIONS | Q 34. | Page 42

What happens when ferrimagnetic Fe3O4 is heated at 850 K and why?

VERY SHORT ANSWER TYPE QUESTIONS | Q 35. | Page 42

What is pyroelectricity?

VERY SHORT ANSWER TYPE QUESTIONS | Q 36. | Page 42

What is piezoelectricity?

VERY SHORT ANSWER TYPE QUESTIONS | Q 37. | Page 42

What happens when an electric field is applied to a piezoelectric crystal?

VERY SHORT ANSWER TYPE QUESTIONS | Q 38. | Page 42

What do you understand by superconductivity?

VERY SHORT ANSWER TYPE QUESTIONS | Q 39. | Page 42

What happens when amorphous solids are subjected to annealing?

VERY SHORT ANSWER TYPE QUESTIONS | Q 40. | Page 42

What type of order is present in amorphous solids?

VERY SHORT ANSWER TYPE QUESTIONS | Q 41. | Page 42

Give reason for the following:

Ionic compounds do not conduct electricity in solid state.

VERY SHORT ANSWER TYPE QUESTIONS | Q 42. | Page 42

What is the effect of increasing temperature on the conductivity of a semiconductor?

VERY SHORT ANSWER TYPE QUESTIONS | Q 43. | Page 42

How does amorphous silica differ from quartz?

VERY SHORT ANSWER TYPE QUESTIONS | Q 44. | Page 42

What is a void?

VERY SHORT ANSWER TYPE QUESTIONS | Q 45. | Page 42

Compare dia, para and ferromagnetism.

VERY SHORT ANSWER TYPE QUESTIONS | Q 46. | Page 42

In a close packing of spheres, what is the value of radius ratio (radius of an octahedral void/radius of sphere)?

VERY SHORT ANSWER TYPE QUESTIONS | Q 47. (i) | Page 42

How can you convert NaCl structure into CsCl structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 47. (ii) | Page 42

How can you convert CsCl structure into NaCl structure?

VERY SHORT ANSWER TYPE QUESTIONS | Q 48. | Page 42

What causes the conduction of electricity by semiconductors?

VERY SHORT ANSWER TYPE QUESTIONS | Q 49. | Page 42

What type of crystals exhibit piezoelectricity?

VERY SHORT ANSWER TYPE QUESTIONS | Q 50. | Page 42

Agl crystallises in cubic close-packed ZnS structure. What fraction of tetrahedral sites are occupied by Ag+ ions?

VERY SHORT ANSWER TYPE QUESTIONS | Q 51. | Page 43

Classify each of the following solids as ionic, metallic, molecular, covalent or amorphous. 

  1. P4O10
  2. Graphite
  3. Brass
  4. (NH4)3PO4
  5. SiC
  6. Rb
  7. I2
  8. LiBr
  9. P4
  10. Si
  11. Plastic
VERY SHORT ANSWER TYPE QUESTIONS | Q 52. | Page 43

Classify each of the following as being either a p-type or a n-type semiconductor:

  1. Ge doped with In 
  2. B doped with Si
SHORT ANSWER TYPE QUESTIONS [Pages 43 - 44]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State SHORT ANSWER TYPE QUESTIONS [Pages 43 - 44]

SHORT ANSWER TYPE QUESTIONS | Q 1. | Page 43

What are the main characteristics of crystalline solids?

SHORT ANSWER TYPE QUESTIONS | Q 2. (i) | Page 43

What do you understand by space lattice?

SHORT ANSWER TYPE QUESTIONS | Q 2. (ii) | Page 43

What do you understand by unit cell?

SHORT ANSWER TYPE QUESTIONS | Q 3. (i) | Page 43

What do you understand by unit cell?

SHORT ANSWER TYPE QUESTIONS | Q 3. (ii) | Page 43

What parameters are used to describe a unit cell?

SHORT ANSWER TYPE QUESTIONS | Q 4. (i) | Page 43

What is a primitive unit cell?

SHORT ANSWER TYPE QUESTIONS | Q 4. (ii) | Page 43

Name the different types of primitive unit cells.

SHORT ANSWER TYPE QUESTIONS | Q 5. | Page 43

How many types of unit cells are present in different types of crystals? Explain with appropriate figures.

SHORT ANSWER TYPE QUESTIONS | Q 6. | Page 43

Describe the various types of cubic systems.

SHORT ANSWER TYPE QUESTIONS | Q 7. | Page 43

Explain why uncharged atoms or molecules never crystallise in a simple cubic structure.

SHORT ANSWER TYPE QUESTIONS | Q 8. (i) | Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the corner?

SHORT ANSWER TYPE QUESTIONS | Q 8. (ii) | Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the centre of a face?

SHORT ANSWER TYPE QUESTIONS | Q 8. (iii) | Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the body centre?

SHORT ANSWER TYPE QUESTIONS | Q 9. (i) | Page 43

How many atoms of an element are there in one unit cell of simple cubic?

SHORT ANSWER TYPE QUESTIONS | Q 9. (ii) | Page 43

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

SHORT ANSWER TYPE QUESTIONS | Q 9. (iii) | Page 43

Find the number of atoms in the fcc unit cell.

SHORT ANSWER TYPE QUESTIONS | Q 10. | Page 43

What is the percentage of the occupied space in a simple cubic unit cell?

SHORT ANSWER TYPE QUESTIONS | Q 11. | Page 43

Show that the face diagonal of a cube is equal to `sqrt2  a`, where a is the edge length.

SHORT ANSWER TYPE QUESTIONS | Q 12. | Page 43

Show that the packing fraction in a face-centred cubic unit cell is 0.74.

SHORT ANSWER TYPE QUESTIONS | Q 13. | Page 43

In a face-centred cubic arrangement of atoms A and B, A are present at the corners and B at the face-centres. If A atoms are missing from 4 corners in each unit cell, what is the simplest formula of the compound?

SHORT ANSWER TYPE QUESTIONS | Q 14. | Page 43

An element crystallises separately both in hcp and ccp structures. Will the two structures have the same density? If yes, why?

SHORT ANSWER TYPE QUESTIONS | Q 15. | Page 43

Explain why the hexagonal close packing is more efficient than square close packing when considered in a plane?

SHORT ANSWER TYPE QUESTIONS | Q 16. | Page 43

Distinguish between hexagonal close packing and cubic close packing.

SHORT ANSWER TYPE QUESTIONS | Q 17. (i) | Page 43

What is meant by the term ‘coordination number’?

SHORT ANSWER TYPE QUESTIONS | Q 17. (ii) (a) | Page 43

Mention the coordination number of each sphere in a hexagonal close-packed structure.

SHORT ANSWER TYPE QUESTIONS | Q 17. (ii) (b) | Page 43

Mention the coordination number of each sphere in a body-centred close-packed structure.

SHORT ANSWER TYPE QUESTIONS | Q 18. (i) | Page 43

What do you understand by voids in close-packed structures?

SHORT ANSWER TYPE QUESTIONS | Q 18. (ii) | Page 43

Define a tetrahedral void.

SHORT ANSWER TYPE QUESTIONS | Q 18. (iii) | Page 43

Define octahedral void.

SHORT ANSWER TYPE QUESTIONS | Q 19. | Page 43

Show that the radius of a tetrahedral void is 0.225 times the radius of the sphere forming a close-packed structure.

SHORT ANSWER TYPE QUESTIONS | Q 20. | Page 43

Show that a particle of radius less than 0.441 times the radius of the constituent particle can only be placed in an octahedral void without disturbing the crystal lattice.

SHORT ANSWER TYPE QUESTIONS | Q 21. (i) | Page 44

What do you understand by radius ratio?

SHORT ANSWER TYPE QUESTIONS | Q 21. (ii) | Page 44

What is the ideal radius ratio for octahedral arrangement?

SHORT ANSWER TYPE QUESTIONS | Q 22. | Page 44

An ionic solid possesses a body-centred close-packed structure. What is the ideal radius ratio and coordination number for the structure?

SHORT ANSWER TYPE QUESTIONS | Q 23. | Page 44

How would you decide that a given hard and rigid solid possessing high melting and boiling points is ionic or covalent?

SHORT ANSWER TYPE QUESTIONS | Q 24. | Page 44

What types of structures are possessed by ionic solids of the type AB? Explain with diagrams.

SHORT ANSWER TYPE QUESTIONS | Q 25. (i) | Page 44

Explain the structure of NaCl.

SHORT ANSWER TYPE QUESTIONS | Q 25. (ii) | Page 44

Find the number of ion pairs per unit cell in NaCl.

SHORT ANSWER TYPE QUESTIONS | Q 26. (i) | Page 44

What is the effect of pressure on the structures of the ionic crystals of the type AB?

SHORT ANSWER TYPE QUESTIONS | Q 26. (ii) | Page 44

What is the effect of temperature on the structures of the ionic crystals of the type AB?

SHORT ANSWER TYPE QUESTIONS | Q 27. (i) | Page 44

What do you understand by imperfections in ionic crystals?

SHORT ANSWER TYPE QUESTIONS | Q 27. (ii) | Page 44

Name the type of imperfections which generally occur in ionic crystals.

SHORT ANSWER TYPE QUESTIONS | Q 28. | Page 44

Explain why does the presence of Frenkel defects not affect the density of a crystal.

SHORT ANSWER TYPE QUESTIONS | Q 29. (i) | Page 44

How does the Schottky defect increase the conductivity of a crystal?

SHORT ANSWER TYPE QUESTIONS | Q 29. (ii) | Page 44

How does the Frenkel defect increase the conductivity of a crystal?

SHORT ANSWER TYPE QUESTIONS | Q 30. | Page 44

How does a crystal having metal excess defect maintain its electrical neutrality?

SHORT ANSWER TYPE QUESTIONS | Q 31. | Page 44

Why does a crystal of KCl appear violet in colour in spite of the fact that both K+ and Cl ions are colourless?

SHORT ANSWER TYPE QUESTIONS | Q 32. | Page 44

What are F-centres?

SHORT ANSWER TYPE QUESTIONS | Q 33. (i) | Page 44

What do you mean by doping?

SHORT ANSWER TYPE QUESTIONS | Q 33. (ii) | Page 44

Why does the impurity-doped silicon act as a semiconductor?

SHORT ANSWER TYPE QUESTIONS | Q 34. (i) | Page 44

What is a semiconductor?

SHORT ANSWER TYPE QUESTIONS | Q 34. (ii) | Page 44

What factors are responsible for the conduction of current by a semiconductor?

SHORT ANSWER TYPE QUESTIONS | Q 34. (iii) | Page 44

Mention important applications of semiconductors.

SHORT ANSWER TYPE QUESTIONS | Q 35. (i) | Page 44

What is ferromagnetism?

SHORT ANSWER TYPE QUESTIONS | Q 35. (ii) | Page 44

How does ferromagnetism arise?

SHORT ANSWER TYPE QUESTIONS | Q 36. | Page 44

Why do ferrimagnetic substances possess small net magnetic moments in spite of the presence of a large number of unpaired electrons?

SHORT ANSWER TYPE QUESTIONS | Q 37. (i) | Page 44

What happens when a piezoelectric crystal is subjected to a mechanical stress?

SHORT ANSWER TYPE QUESTIONS | Q 37. (ii) | Page 44

What happens when an electric field is applied to a piezoelectric crystal?

SHORT ANSWER TYPE QUESTIONS | Q 38. (i) | Page 44

Why are the amorphous solids said to possess short range order?

SHORT ANSWER TYPE QUESTIONS | Q 38. (ii) | Page 44

Discuss the properties of amorphous solids.

SHORT ANSWER TYPE QUESTIONS | Q 39. | Page 44

What type of crystal defect is produced when sodium chloride is doped with MgCl2?

SHORT ANSWER TYPE QUESTIONS | Q 40. (i) | Page 44

Explain the Schottky defect.

SHORT ANSWER TYPE QUESTIONS | Q 40. (ii) | Page 44

What are the consequences of the Schottky defect in crystals?

SHORT ANSWER TYPE QUESTIONS | Q 40. (iii) | Page 44

What are the consequences of Frenkel defects in crystals?

SHORT ANSWER TYPE QUESTIONS | Q 41. | Page 44

If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.

SHORT ANSWER TYPE QUESTIONS | Q 42. | Page 44

Stability of a crystal is reflected in the magnitude of its melting point. Comment.

LONG ANSWER TYPE QUESTIONS [Pages 44 - 45]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State LONG ANSWER TYPE QUESTIONS [Pages 44 - 45]

LONG ANSWER TYPE QUESTIONS | Q 1. i. | Page 44

How are the solids classified?

LONG ANSWER TYPE QUESTIONS | Q 1. ii. | Page 44

Compare the properties of crystalline and amorphous solids.

LONG ANSWER TYPE QUESTIONS | Q 2. | Page 44

Explain the characteristics of different types of crystalline solids.

LONG ANSWER TYPE QUESTIONS | Q 3. (i) | Page 44

Discuss the characteristics of various types of unit cells.

LONG ANSWER TYPE QUESTIONS | Q 3. (ii) | Page 44

How would you calculate the number of particles in a unit cell?

LONG ANSWER TYPE QUESTIONS | Q 4. (i) | Page 44

How many atoms of an element are there in one unit cell of simple cubic?

LONG ANSWER TYPE QUESTIONS | Q 4. (ii) | Page 44

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

LONG ANSWER TYPE QUESTIONS | Q 4. (iii) | Page 44

Find the number of atoms in the fcc unit cell.

LONG ANSWER TYPE QUESTIONS | Q 5. (i) | Page 44

Calculate the percentage efficiency of packing in the case of a body-centred cubic crystal.

LONG ANSWER TYPE QUESTIONS | Q 5. (ii) | Page 44

Calculate the percentage of the occupied space in a face-centred cubic unit cell.

LONG ANSWER TYPE QUESTIONS | Q 6. | Page 45

Show that the packing fraction in a simple cubic unit cell is 0.524 and the radius of the atom is equal to half of the edge length.

LONG ANSWER TYPE QUESTIONS | Q 7. | Page 45

The unit cell of the crystal of an element has Z atoms and the edge length equal to a. If the molecular mass of the element is M, calculate the density of the crystal.

LONG ANSWER TYPE QUESTIONS | Q 8. (i) | Page 45

Explain with a diagram the hcp mode of packing in crystals. 

LONG ANSWER TYPE QUESTIONS | Q 8. (ii) | Page 45

Explain with diagrams the ccp mode of packing in crystals.

LONG ANSWER TYPE QUESTIONS | Q 8. (iii) | Page 45

Distinguish between hexagonal close packing and cubic close packing.

LONG ANSWER TYPE QUESTIONS | Q 9. (i) | Page 45

What are the voids commonly found in close-packed structures?

LONG ANSWER TYPE QUESTIONS | Q 9. (ii) | Page 45

Show that the radius of a tetrahedral void is 0.225 times the radius of the sphere forming a close-packed structure.

LONG ANSWER TYPE QUESTIONS | Q 9. (iii) | Page 45

Calculate the radii of octahedral voids in terms of the radius of the spheres forming close-packed structures.

LONG ANSWER TYPE QUESTIONS | Q 10. (i) | Page 45

What do you understand by radius ratio?

LONG ANSWER TYPE QUESTIONS | Q 10. (ii) | Page 45

What is the significance of the radius ratio in determining the structural arrangement and coordination number of an ionic solid?

LONG ANSWER TYPE QUESTIONS | Q 11. | Page 45

Explain the structure of NaCl.

LONG ANSWER TYPE QUESTIONS | Q 12. | Page 45

Show that a unit cell of sodium chloride contains four Na+Cl units.

LONG ANSWER TYPE QUESTIONS | Q 13. (i) | Page 45

Explain the Schottky defect.

LONG ANSWER TYPE QUESTIONS | Q 13. (ii) | Page 45

Explain with a diagram the Frenkel defect.

LONG ANSWER TYPE QUESTIONS | Q 13. (iii) | Page 45

How do Schottky defects affect the properties of crystals?

LONG ANSWER TYPE QUESTIONS | Q 13. (iv) | Page 45

How do Frenkel defects affect the properties of crystals?

LONG ANSWER TYPE QUESTIONS | Q 14. | Page 45

Describe the various types of non-stoichiometric defects found in ionic crystals.

LONG ANSWER TYPE QUESTIONS | Q 15. (i) | Page 45

What do you understand by doping of a crystal?

LONG ANSWER TYPE QUESTIONS | Q 15. (ii) | Page 45

How are the impurity defects introduced into covalent solids?

LONG ANSWER TYPE QUESTIONS | Q 15. (iii) | Page 45

How are the impurity defects introduced into ionic solids?

LONG ANSWER TYPE QUESTIONS | Q 15. (iv) | Page 45

In what way is the electrical conductivity of a crystal affected by doping?

LONG ANSWER TYPE QUESTIONS | Q 16. | Page 45

Classify the solids on the basis of their electrical properties.

LONG ANSWER TYPE QUESTIONS | Q 17. | Page 45

Describe the various types of magnetic substances with the help of electron spin and explain their characteristics.

LONG ANSWER TYPE QUESTIONS | Q 18. (i) | Page 45

What is piezoelectricity?

LONG ANSWER TYPE QUESTIONS | Q 18. (ii) | Page 45

Why are the piezoelectric crystals used in record players?

LONG ANSWER TYPE QUESTIONS | Q 19. (i) | Page 45

Write a short note on pyroelectricity.

LONG ANSWER TYPE QUESTIONS | Q 19. (ii) | Page 45

Write a short note on ferroelectricity.

LONG ANSWER TYPE QUESTIONS | Q 19. (iii) | Page 45

Write a short note on antiferroelectricity.

LONG ANSWER TYPE QUESTIONS | Q 20. | Page 45

Explain why all ferroelectric crystals behave as piezoelectric crystals but the reverse is not true.

LONG ANSWER TYPE QUESTIONS | Q 21. | Page 45

Explain why there is no current in a metal although there are free electrons in motion.

LONG ANSWER TYPE QUESTIONS | Q 22. | Page 45

Explain why doping produces cation vacancies and not the anion vacancies.

LONG ANSWER TYPE QUESTIONS | Q 23. (i) | Page 45

What are amorphous solids?

LONG ANSWER TYPE QUESTIONS | Q 23. (ii) | Page 45

Discuss the properties of amorphous solids.

LONG ANSWER TYPE QUESTIONS | Q 23. (iii) | Page 45

Discuss the uses of amorphous solids.

LONG ANSWER TYPE QUESTIONS | Q 24. (i) | Page 45

How would you convert silica into a glassy substance? Explain the structure of the substance thus obtained.

LONG ANSWER TYPE QUESTIONS | Q 24. (ii) | Page 45

Why do the glass objects from ancient civilizations look milky instead of being transparent?

LONG ANSWER TYPE QUESTIONS | Q 25. (a) | Page 45

Explain the following with suitable examples:

Ferromagnetism

LONG ANSWER TYPE QUESTIONS | Q 25. (b) | Page 45

Explain the following with suitable examples:

Paramagnetism

LONG ANSWER TYPE QUESTIONS | Q 25. (c) | Page 45

Explain the following with suitable examples:

Ferrimagnetism

LONG ANSWER TYPE QUESTIONS | Q 25. (d) | Page 45

Explain the following with suitable examples:

Piezoelectric effect

LONG ANSWER TYPE QUESTIONS | Q 25. (e) (i) | Page 45

Explain the following with suitable examples:

12-16 group compounds

LONG ANSWER TYPE QUESTIONS | Q 25. (e) (ii) | Page 45

Explain the following with suitable examples:

13-15 group compounds

LONG ANSWER TYPE QUESTIONS | Q 26. (a) | Page 45

Explain the Schottky defect.

LONG ANSWER TYPE QUESTIONS | Q 26. (b) | Page 45

Explain with a diagram the Frenkel defect.

LONG ANSWER TYPE QUESTIONS | Q 26. (c) | Page 45

Explain the following term with a suitable example:

Interstitials

LONG ANSWER TYPE QUESTIONS | Q 26. (d) | Page 45

Explain the following term with a suitable example:

F-centres

LONG ANSWER TYPE QUESTIONS | Q 27. | Page 45

What makes a glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?

LONG ANSWER TYPE QUESTIONS | Q 28. (i) | Page 45

What is a semiconductor?

LONG ANSWER TYPE QUESTIONS | Q 28. (ii) | Page 45

Describe the two main types of semiconductors and mention their important applications.

LONG ANSWER TYPE QUESTIONS | Q 29. (i) | Page 45

How are the crystalline solids classified?

LONG ANSWER TYPE QUESTIONS | Q 29. (ii) | Page 45

Describe the important characteristics of crystalline solids.

LONG ANSWER TYPE QUESTIONS | Q 30. (i) | Page 45

What are molecular solids?

LONG ANSWER TYPE QUESTIONS | Q 30. (ii) | Page 45

Explain the characteristics of different types of crystalline solids.

LONG ANSWER TYPE QUESTIONS | Q 30. (iii) | Page 45

Discuss the crystal structure of dry ice.

LONG ANSWER TYPE QUESTIONS | Q 31. (i) | Page 45

Give any three characteristics of ionic crystals.

LONG ANSWER TYPE QUESTIONS | Q 31. (ii) | Page 45

Explain the structure of NaCl.

LONG ANSWER TYPE QUESTIONS | Q 32. (i) | Page 45

What is meant by covalent solids?

LONG ANSWER TYPE QUESTIONS | Q 32. (ii) | Page 45

Discuss the structures of diamond. How would you explain the properties of these substances on the basis of their structures?

LONG ANSWER TYPE QUESTIONS | Q 32. (iii) | Page 45

Describe the structure of graphite with the help of a labelled diagram.

LONG ANSWER TYPE QUESTIONS | Q 33. (i) | Page 45

What are metallic solids?

LONG ANSWER TYPE QUESTIONS | Q 33. (ii) | Page 45

What are the characteristics of metallic solids?

LONG ANSWER TYPE QUESTIONS | Q 33. (iii) | Page 45

Describe the important features of metallic bonding.

LONG ANSWER TYPE QUESTIONS | Q 33. (iv) | Page 45

Discuss the crystal structure of copper metal.

INTEGER TYPE QUESTIONS [Page 45]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State INTEGER TYPE QUESTIONS [Page 45]

INTEGER TYPE QUESTIONS | Q 1. | Page 45

The distance between Na+ and Cl ions in solid NaCl of density 43.1 g cm−3 is ______ × 10 −10 m (Nearest integer).

(Given: NA = 6.02 × 1023 mol−1)

INTEGER TYPE QUESTIONS | Q 2. | Page 45

Atoms of element X form hcp lattice and those of element Y occupy `2/3` of its tetrahedral voids. The percentage of element X in the lattice is ______ (Nearest integer).

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 46 - 47]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 46 - 47]

Choose the correct option in the following questions.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 1. | Page 46

Which one is not the property of a crystalline solid?

  • Isotropic

  • Sharp melting point

  • A definite and regular geometry

  • High intermolecular forces

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 2. | Page 46

Tetragonal crystal system has the following unit cell dimensions:

  • a = b = c, α = β = γ = 90°

  • a = b ≠ c, α = β = γ = 90°

  • a ≠ b ≠ c, α = β = γ = 90°

  • a = b ≠ c, α = β = γ = 90°, γ = 120°

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 3. | Page 46

The coordination number of each sphere in hcp arrangement is ______.

  • 8

  • 12

  • 6

  • 4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 4. | Page 46

The number of atoms contained in one face-centred cubic unit cell of a monoatomic substance is ______.

  • 1

  • 2

  • 4

  • 3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 5. | Page 46

How many chloride ions are surrounding sodium ions in sodium chloride crystal?

  • 4

  • 8

  • 6

  • 12

  • 3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 6. | Page 46

For an ionic crystal of general formula AX and coordination number 6, the value of radius ratio will be ______.

  • greater than 0.73

  • in between 0.73 and 0.41

  • in between 0.41 and 0.22

  • less than 0.22

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 7. | Page 46

Potassium crystallises in bcc lattice, the coordination number of potassium in potassium metal is ______.

  • 12

  • 4

  • 6

  • 8

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 8. | Page 46

Coordination number of Cu is ______.

  • 4

  • 6

  • 8

  • 12

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 9. | Page 46

An ionic compound is made up of P cations and Q anions. If P are present at alternate corners and Q is present on the body of the diagonal, then the formula of the ionic compound will be ______.

  • PQ

  • PQ2

  • P2Q

  • P4Q

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 10. | Page 46

In a crystal, the atoms are located at the position of ______.

  • maximum P.E.

  • minimum P.E.

  • zero P.E.

  • infinite P.E.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 11. | Page 46

An element A (atomic mass 60) has simple cubic lattice of edge 100 pm. The density of crystal (N0 = 6 × 1023) is ______.

  • 600 g cm−3

  • 1 × 104 g cm−3

  • 6 × 10−2 g cm−3

  • 1 × 102 g cm−3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 12. | Page 46

The intermetallic compound LiAg crystallises in cubic lattice in which both lithium and silver have coordination number of eight. The crystal class is ______.

  • simple cubic

  • body-centred cubic

  • face-centred cubic

  • none of these

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 13. | Page 46

A solid has a structure in which W atoms are located at the corners of a cubic lattice, O atoms at the centre of edges and Na atoms at the centre of the cube. The formula of the compound is ______.

  • NaWO2

  • NaWO3

  • Na2WO3

  • NaWO4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 14. | Page 46

For tetrahedral coordination, the radius ratio (r+/r) should be ______.

  • 0.155−0.225

  • 0.225−0.414

  • 0.444−0.732

  • 0.732−1

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 15. | Page 46

If edge of a bcc crystal of an element is a cm, M is the atomic mass and N0 the Avogadro’s number, the density of the crystal is ______.

  • `(4M)/(N_0a^3)`

  • `(2N_0)/(Ma^3)`

  • `(2M)/(N_0a^3)`

  • `(Ma^3)/(2N_0)`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 16 | Page 46

In a compound AB2O4, oxide ions are arranged in ccp and cations A are present in octahedral voids. Cations B are equally distributed between octahedral and tetrahedral voids. The fraction of the octahedral voids occupied is ______.

  • `1/2`

  • `1/4`

  • `1/8`

  • `1/6`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 17. | Page 46

Potassium has a bcc structure with nearest neighbour distance of 4.52 Å. Its atomic weight is 39. Its density will be ______.

  • 454 kg m−3

  • 804 kg m−3

  • 852 kg m−3

  • 908 kg m−3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 18. | Page 4

A compound formed by atoms X and Y crystallises in the cubic structure. The atoms X are present at the corners of a cube while atoms Y are at the face-centres. The formula of the compound is ______.

  • XY

  • X2Y

  • X3Y

  • XY3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 19. | Page 46

In a face-centred cubic system, the distance d between the nearest neighbours is given by ______.

  • d = a

  • `d = sqrt 2a`

  • `d = (sqrt 3a)/2`

  • `d = a/sqrt2`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 20. | Page 46

An element crystallises in body-centred cubic structure. If the edge length of the cubic unit cell is 400 pm, the interatomic distance in the crystal is ______.

  • 346.4 pm

  • 282.8 pm

  • 400 pm

  • 200 pm

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 21. | Page 46

A face-centred cubic element (atomic mass = 60) has a cell edge of 400 pm. What is its density?

  • 0.623 g cm−3

  • 6.23 g cm−3

  • 62.3 g cm−3

  • 0.0623 g cm−3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 22. | Page 46

An element occurs in bcc structure. Its density is 8.0 g cm−3. If the cell edge is 250 pm, the atomic mass of the element is ______.

  • 26.4 g mol−1

  • 37.6 g mol−1

  • 54.5 g mol−1

  • 86.1 g mol−1

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 23. | Page 46

Which of the following statements is not true?

  • The radius of a tetrahedral void is 0.225 times the radius of the particle.

  • The radius of an octahedral void is 0.732 times the radius of the particle.

  • The space occupied in bcc arrangement is 68%.

  • The number of tetrahedral voids in a close-packed structure is double that of the number of constituent particles.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 24. | Page 46

Gold crystallises in a ccp lattice. How many nearest neighbours does a gold atom possess?

  • 6

  • 8

  • 10

  • 12

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 25. | Page 46

Which of the following statements is not true for rock salt (NaCl) structure?

  • The structure is of fcc type.

  • Cl ions are present at the corners and face-centres of a cube.

  • Na+ ions are present in alternate tetrahedral voids.

  • The structure has 6 : 6 coordination.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 26. | Page 46

Which of the following substances is ferromagnetic?

  • Fe

  • Ni

  • MnO

  • Fe3O4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 27. | Page 46

The point defect which lowers the density of a crystal is ______.

  • Schottky defect

  • Frenkel defect

  • Schottky defect and Frenkel defect

  • None of these

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 28. | Page 46

The presence of F-centres in a crystal makes it ______.

  • conducting

  • colourless

  • non-conducting

  • coloured

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 29. | Page 46

When a group 13 element is added in small amounts to Ge, the material obtained is ______.

  • an insulator

  • an n-type semiconductor

  • a p-type semiconductor

  • a super conductor

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 30. | Page 46

Which of the following sets of magnetic moments represents an antiferromagnetic substance?

  • ↑↑↑↑↑↑

  • ↑↓↑↓↑↓

  • ↑↑↓↑↑↓

  • ↑↑↓↓↑

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 31. | Page 46

Which of the following statements is not true?

  • Piezoelectric crystals produce electricity when subjected to a mechanical stress.

  • The electric current produced on heating certain polar crystals is called ferroelectricity.

  • PbZrO3 is an antiferroelectric substance.

  • Piezoelectric crystals are used as pickups in record players.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 32. | Page 46

In a solid lattice, the cation has left a lattice site and is located at an interstitial position. The lattice defect is ______.

  • Frenkel defect

  • Schottky defect

  • Non-stoichiometric defect

  • Valence defect

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 33. | Page 46

CsBr contains bcc structure. The length of its one side is 4.3 Å. The minimum distance between Cs+ and Br ions will be ______.

  • 0.897 Å

  • 3.72 Å

  • 1.794 Å

  • none of these

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 34. | Page 46

Germanium is an example of ______.

  • an intrinsic semiconductor

  • an extrinsic semiconductor

  • an insulator

  • an n-type semiconductor

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 35. | Page 46

Which type of semiconductor is obtained on mixing arsenic into silicon?

  • n-type

  • p-type

  • p-n type

  • n-p type

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 36. | Page 46

How many unit cells are present in a cube-shaped ideal crystal of NaCl of mass 1.00 g? [Atomic masses: Na = 23, Cl = 35.5]

  • 5.14 × 1021 unit cells

  • 1.28 × 1021 unit cells

  • 1.71 × 1021 unit cells

  • 2.57 × 1021 unit cells

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 37. | Page 46

What type of crystal defect is indicated in the diagram below?

  • Frenkel defect

  • Schottky defect

  • Interstitial defect

  • Frenkel and Schottky defects

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 38. | Page 46

An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the centres of the faces of the cube. The empirical formula for this compound would be ______.

  • A3B

  • AB3

  • A2B

  • AB

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 39. | Page 46

Total volume of atoms present in a face-centred cubic unit cell of a metal (r is atomic radius) is ______.

  • `20/3  pi r^3`

  • `24/3  pi r^3`

  • `12/3  pi r^3`

  • `16/3  pi r^3`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 40. | Page 46

In a compound, atoms of element Y form ccp lattice and those of element X occupy `2/3`rd of tetrahedral voids. The formula of the compound will be ______.

  • X4Y3

  • X2Y3

  • X2Y

  • X3Y4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 41. | Page 46

AB crystallises in a body-centred cubic lattice with edge length ‘a’ equal to 387 pm. The distance between two oppositively charged ions in the lattice is ______.

  • 335 pm

  • 250 pm

  • 200 pm

  • 300 pm

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 42. | Page 46

A metal crystallises with a face-centred cubic lattice. The edge of the unit cell is 408 pm. The diameter of the metal atom is ______.

  • 288 pm

  • 408 pm

  • 144 pm

  • 204 pm

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 43. | Page 46

The number of octahedral void(s) per atom present in a cubic close-packed structure is ______.

  • 1

  • 3

  • 2

  • 4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 44. | Page 47

If ‘a’ is the length of the side of the cube, the distance between the body-centered atom and one corner atom in the cube will be ______.

  • `(2/sqrt 3) a`

  • `(4/sqrt 3) a`

  • `(sqrt 3/4) a`

  • `(sqrt 3/2) a`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 45. | Page 47

Sodium metal crystallises in a body-centred cubic lattice with a unit cell edge of 4.29 Å. The radius of the sodium atom is approximately ______.

  • 5.72 Å

  • 0.93 Å

  • 1.86 Å

  • 3.22 Å

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 46. | Page 47

If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are ______.

  • `1/2, 1/8`

  • `1, 1/4`

  • `1/2, 1/2`

  • `1/4, 1/8`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 47. | Page 47

Lithium has a bcc structure. Its density is 530 kg m−3 and its atomic mass is 6.94 g mol−1. Calculate the edge length of a unit cell of lithium metal. (NA = 6.02 × 1023 mol−1)

  • 154 pm

  • 352 pm

  • 527 pm

  • 264 pm

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 48. | Page 47

The ionic radii of A+ and B are 0.98 × 10−10 m and 1.81 × 10−10 m. The coordination number of each ion in AB is ______.

  • 8

  • 2

  • 6

  • 4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 49. | Page 47

Which is the incorrect statement?

  • FeO0.98 has non stoichiometric metal deficiency defect.

  • Density decreases in case of crystals with Schottky’s defect.

  • NaCl (s) is insulator, silicon is semiconductor, silver is conductor, quartz is piezoelectric crystal.

  • Frenkel defect is favoured in those ionic compounds in which sizes of cations and anions are almost equal.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 50. | Page 47

A metal crystallises in a face-centred cubic structure. If the edge length of its unit cell is ‘a’, the closest approach between two atoms in metallic crystal will be ______.

  • `sqrt 2 a`

  • `a/sqrt 2`

  • 2a

  • `2 sqrt 2 a`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 51. | Page 47

Which type of ‘defect’ has the presence of cations in the interstitial sites?

  • Schottky defect

  • Vacancy defect 

  • Frenkel defect

  • Metal deficiency defect

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 52. | Page 47

Iron exhibits bcc structure at room temperature. Above 900°C, it transforms to fcc structure. The ratio of density of iron at room temperature to that at 900°C (assuming molar mass and atomic radii of iron remains constant with temperature) is ______.

  • `(3 sqrt 3)/(4 sqrt 2)`

  • `(4 sqrt 3)/(3 sqrt 2)`

  • `sqrt 3/sqrt 2`

  • `1/2`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 53. | Page 47

An element has a face-centred cubic (fcc) structure with a cell edge of a. The distance between the centres of two nearest tetrahedral voids in the lattice is ______.

  • a

  • `3/2  a`

  • `a/2`

  • `sqrt 2  a`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 54. | Page 47

A compound is formed by cation C and anion A. The anions form hexagonal close-packed (hcp) lattice and the cations occupy 75% of octahedral voids. The formula of the compound is ______.

  • C2A3

  • C3A2

  • C3A4

  • C4A3

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 55. | Page 47

An element has a body centered cubic (bcc) structure with a cell edge of 288 pm. The atomic radius is ______.

  • `sqrt 3/4 xx 288  "pm"`

  • `sqrt 2/4 xx 288  "pm"`

  • `4/sqrt3 xx 288  "pm"`

  • `4/sqrt 2 xx 288  "pm"`

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 56. | Page 47

A diatomic molecule X2 has a body-centered cubic (bcc) structure with a cell edge of 300 pm. The density of the molecule is 6.47 g cm−3. The number of molecules present in 200 g of X2 is ______.

  • 4 NA

  • 2 NA

  • 40 NA

  • 8 NA

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 57. | Page 47

The right option for the number of tetrahedral and octahedral voids in the hexagonal primitive unit cell is ______.

  • 6, 12

  • 2, 1

  • 12, 6

  • 8, 4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 58. | Page 47

The correct option for the number of body-centered unit cells in all 14 types of Bravais lattice unit cells is ______.

  • 3

  • 7

  • 5

  • 2

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 59. | Page 47

In a binary compound, atoms of element A form a hcp structure and those of element M occupy `2/3` of the tetrahedral voids of 3 the hcp structure. The formula of the binary compound is ______.

  • M2A3

  • M4A3

  • M4A

  • MA4

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 60. | Page 47

For the given close packed structure of a salt made of cation X and anion Y shown below (ions of only one face are shown for clarity), the packing fraction is approximately:

  • 0.74

  • 0.63

  • 0.52

  • 0.48

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 61. | Page 47

Copper crystallises in fcc unit cell with cell edge length of 3.608 × 10−8 cm. The density of copper is 8.92 g cm−3. Calculate the atomic mass of copper.

  • 31.55 u

  • 60 u

  • 65 u

  • 63.1 u

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 62. | Page 47

Choose the correct statement:

  • Diamond is covalent and graphite is ionic.

  • Diamond is sp3 hybridised and graphite is sp2 hybridised.

  • Both diamond and graphite are used as dry lubricants.

  • Diamond and graphite have two dimensional network.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 63. | Page 47

The incorrect statement about the imperfections in solids is ______.

  • Schottky defect decreases the density of the substance.

  • Interstitial defect increases the density of the substance.

  • Frenkel defect does not alter the density of the substance. 

  • Vacancy defect increases the density of the substance.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS | Q 64. | Page 47

Atom X occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to ______.

  • 25

  • 35

  • 55

  • 75

FILL IN THE BLANKS TYPE QUESTIONS [Pages 49 - 50]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State FILL IN THE BLANKS TYPE QUESTIONS [Pages 49 - 50]

FILL IN THE BLANKS TYPE QUESTIONS | Q 1. | Page 49

If a molten crystalline solid is cooled, the original ______ reappears again.

FILL IN THE BLANKS TYPE QUESTIONS | Q 2. | Page 49

Amorphous solids are regarded as ______ liquids.

FILL IN THE BLANKS TYPE QUESTIONS | Q 3. | Page 49

The smallest three dimensional group of lattice points, which when repeated in three dimensions in space gives the whole lattice of the crystal, is called ______.

FILL IN THE BLANKS TYPE QUESTIONS | Q 4. | Page 50

The unit cell in which one constituent particle is present at the centre in addition to the particles at its corners is called ______ unit cell.

FILL IN THE BLANKS TYPE QUESTIONS | Q 5. | Page 50

The unit cell of a body-centred cubic system contains ______ atoms.

FILL IN THE BLANKS TYPE QUESTIONS | Q 6. | Page 50

Both ccp and hcp are ______ packings and occupy about ______% of the available space.

FILL IN THE BLANKS TYPE QUESTIONS | Q 7. | Page 50

The number of nearest neighbours with which a given particle is in direct contact in a crystal is called the ______.

FILL IN THE BLANKS TYPE QUESTIONS | Q 8. | Page 50

In a close-packed structure, the number of tetrahedral voids is ______ the number of constituent particles because every void has ______ particles and there are ______ voids around each particle.

FILL IN THE BLANKS TYPE QUESTIONS | Q 9. | Page 50

A cation would exactly fit into an octahedral void in the lattice formed by anions if `r_+/r_-` is exactly equal to ______.

FILL IN THE BLANKS TYPE QUESTIONS | Q 10. | Page 50

In the sodium chloride structure, each Na+ ion is surrounded by six Cl ions nearest neighbours and ______ Na+ ions next nearest neighbours.

FILL IN THE BLANKS TYPE QUESTIONS | Q 11. | Page 50

If the radius ratio `(r_+/r_-)` is in the range 0.414 − 0.732, the compound AB is likely to have ______ structure.

FILL IN THE BLANKS TYPE QUESTIONS | Q 12. | Page 50

The percentages of unoccupied spaces in bcc and fcc arrangements are ______ and ______ respectively.

ASSERTION-REASON TYPE QUESTIONS [Page 50]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State ASSERTION-REASON TYPE QUESTIONS [Page 50]

The questions given below consist of an Assertion and a Reason. You have to choose the correct answer (a), (b), (c) or (d) according to the following clue:

ASSERTION-REASON TYPE QUESTIONS | Q 1. | Page 50

Assertion: The presence of Frenkel defect in a crystal lowers its density.

Reason: Frenkel defect involves the creation of a hole in the lattice of a crystal due to migration of a cation from its lattice site to an interstitial site.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

ASSERTION-REASON TYPE QUESTIONS | Q 2. | Page 50

Assertion: Silicon forms covalent crystals.

Reason: Its lattice consists of silicon atoms bonded together by covalent bonds in a three dimensional network.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

ASSERTION-REASON TYPE QUESTIONS | Q 3. | Page 50

Assertion: The unit cell of a face-centred cubic system contains 4 atoms.

Reason: The unit cell of a face-centred cubic system consists of atoms at face centres in addition to atoms at the corners.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

ASSERTION-REASON TYPE QUESTIONS | Q 4. | Page 50

Assertion: In rock salt structure, Cl ions form a close-packed lattice and Na+ ions occupy the octahedral voids.

Reason: Sodium chloride possesses a face-centred cubic arrangement.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

ASSERTION-REASON TYPE QUESTIONS | Q 5. | Page 50

Assertion: KCl crystals appear violet in colour.

Reason: The violet colour is due to electrons trapped in anion vacancies.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

ASSERTION-REASON TYPE QUESTIONS | Q 6. | Page 50

Assertion: In a particular point defect, an ionic solid is electrically neutral, even if few of its cations are missing from its unit cells.

Reason: In an ionic solid, Frenkel defect arises due to dislocation of cation from its lattice site to interstitial site maintaining overall electrical neutrality.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

NUMERICAL PROBLEMS [Pages 50 - 51]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State NUMERICAL PROBLEMS [Pages 50 - 51]

NUMERICAL PROBLEMS | Q 1. | Page 50

A unit cell of sodium chloride has four formula units. The edge length of the unit cell is 0.564 nm. What is the density of sodium chloride?

NUMERICAL PROBLEMS | Q 2. | Page 50

Chromium metal crystallises with a body-centred cubic lattice. The length of the unit cell edge is found to be 287 pm. Calculate the atomic radius. What would be the density of chromium in g cm−3?

NUMERICAL PROBLEMS | Q 3. | Page 51

Iron occurs as body-centred as well as face-centred cubic systems. If the effective radius of an atom of iron is 124 pm, calculate the density of iron in both the structures.

NUMERICAL PROBLEMS | Q 4. | Page 51

Molybdenum forms body-centred cubic crystals and at 20°C the density is 10.3 g/cm3. Calculate the distance between the centres of the nearest molybdenum atoms.

NUMERICAL PROBLEMS | Q 5. | Page 51

In the cubic crystal of CsCl (d = 3.97 g/cm3), the eight corners are occupied by Cl with a Cs+ at the centre and vice-versa. Calculate the distance between the neighbouring Cs+ and Cl ions. What is the radius ratio of the two ions? (At. masses: Cs = 132.91, Cl = 35.45)

NUMERICAL PROBLEMS | Q 6. | Page 51

A compound formed by atoms A and B crystallises in the cubic structures. The atoms A occupy the corners while atoms Y the face-centres of the cube. Find the formula of the compound. If the side length is 5 Å, calculate the density of the solid. (Atomic masses: A = 60, B = 90.)

NUMERICAL PROBLEMS | Q 7. | Page 51

A solid AB crystallises as a body-centred cubic lattice with the unit cell edge length equal to 384 pm. Calculate

  1. the distance between the oppositely charged ions in the lattice, and
  2. the radius of A+ ion if that of B is 180 pm.
NUMERICAL PROBLEMS | Q 8. | Page 51

The density of crystalline sodium chloride is 2.165 g cm−3. What is the edge length of the cubic unit cell? What would be the dimension of a cube containing one mole of NaCl?

'NCERT TEXT-BOOK' Exercises [Pages 52 - 55]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State 'NCERT TEXT-BOOK' Exercises [Pages 52 - 55]

'NCERT TEXT-BOOK' Exercises | Q 1.1 (i) | Page 52

Define the term ‘amorphous’.

'NCERT TEXT-BOOK' Exercises | Q 1.1 (ii) | Page 52

Give a few examples of amorphous solids.

'NCERT TEXT-BOOK' Exercises | Q 1.2 | Page 52

What makes a glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?

'NCERT TEXT-BOOK' Exercises | Q 1.3 | Page 52

Classify each of the following solids as ionic, metallic, molecular, network (covalent) or amorphous.

  1. Tetra phosphorus decoxide (P4O10)
  2. Ammonium phosphate (NH4)3PO4
  3. SiC
  4. I2
  5. P4
  6. Plastic
  7. Graphite
  8. Brass
  9. Rb
  10. LiBr
  11. Si
'NCERT TEXT-BOOK' Exercises | Q 1.4 (i) | Page 53

What is meant by the term ‘coordination number’?

'NCERT TEXT-BOOK' Exercises | Q 1.4 (ii) (a) | Page 53

What is the coordination number of atoms in a cubic close-packed structure?

'NCERT TEXT-BOOK' Exercises | Q 1.4 (ii) (b) | Page 53

What is the coordination number of atoms in a bcc structure?

'NCERT TEXT-BOOK' Exercises | Q 1.5 | Page 53

How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.

'NCERT TEXT-BOOK' Exercises | Q 1.6 | Page 53

‘Stability of a crystal is reflected in the magnitude of its melting points.’ Comment. Collect melting points of solid water, ethyl alcohol, diethyl ether and methane from a data book. What can you say about the intermolecular forces between these molecules?

'NCERT TEXT-BOOK' Exercises | Q 1.7 (i) | Page 53

Distinguish between hexagonal close packing and cubic close packing.

'NCERT TEXT-BOOK' Exercises | Q 1.7 (ii) | Page 53

How will you distinguish between the following pair of terms?

Crystal lattice and unit cell

'NCERT TEXT-BOOK' Exercises | Q 1.7 (iii) | Page 53

How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids

'NCERT TEXT-BOOK' Exercises | Q 1.8 (i) | Page 53

How many lattice points are there in one unit cell of the following lattice?

Face-centred cubic

'NCERT TEXT-BOOK' Exercises | Q 1.8 (ii) | Page 53

How many lattice points are there in one unit cell of the following lattice?

Face-centred tetragonal

'NCERT TEXT-BOOK' Exercises | Q 1.8 (iii) | Page 53

How many lattice points are there in one unit cell of the following lattice?

Body-centred

'NCERT TEXT-BOOK' Exercises | Q 1.9 (i) (a) | Page 53

Explain the basis of similarities between metallic and ionic crystals.

'NCERT TEXT-BOOK' Exercises | Q 1.9 (i) (b) | Page 53

Explain the basis of differences between metallic and ionic crystals.

'NCERT TEXT-BOOK' Exercises | Q 1.9 (ii) | Page 53

Explain ionic solids are hard and brittle.

'NCERT TEXT-BOOK' Exercises | Q 1.10 (i) | Page 53

What is the percentage of the occupied space in a simple cubic unit cell?

'NCERT TEXT-BOOK' Exercises | Q 1.10 (ii) | Page 53

Calculate the percentage efficiency of packing in the case of a body-centred cubic crystal.

'NCERT TEXT-BOOK' Exercises | Q 1.10 (iii) | Page 53

Calculate the percentage of the occupied space in a face-centred cubic unit cell.

'NCERT TEXT-BOOK' Exercises | Q 1.11 | Page 53

Silver crystallises in fcc lattice. If edge length of the cell is 4.07 × 10−8 cm and density is 10.5 g cm−3, calculate the atomic mass of silver.

'NCERT TEXT-BOOK' Exercises | Q 1.12 | Page 53

A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?

'NCERT TEXT-BOOK' Exercises | Q 1.13 | Page 54

Niobium crystallises in body-centred cubic structure. If density is 8.55 g cm−3, calculate atomic radius of niobium using its atomic mass 93 u.

'NCERT TEXT-BOOK' Exercises | Q 1.14 | Page 54

If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.

'NCERT TEXT-BOOK' Exercises | Q 1.15 | Page 54

Copper crystallises into a fcc lattice with edge length 3.61 × 10−8 cm. Show that the calculated density is in agreement with its measured value of 8.92 g cm−3.

'NCERT TEXT-BOOK' Exercises | Q 1.16 | Page 54

Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?

'NCERT TEXT-BOOK' Exercises | Q 1.17 (i) | Page 54

What is a semiconductor?

'NCERT TEXT-BOOK' Exercises | Q 1.17 (ii) | Page 54

Describe the two main types of semiconductors and contrast their conduction mechanism.

'NCERT TEXT-BOOK' Exercises | Q 1.18 | Page 54

Non-stoichiometric cuprous oxide, Cu2O can be prepared in laboratory. In this oxide, copper to oxygen ratio is slightly less than 2 : 1. Can you account for the fact that this substance is a p-type semiconductor?

'NCERT TEXT-BOOK' Exercises | Q 1.19 | Page 54

Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.

'NCERT TEXT-BOOK' Exercises | Q 1.20 | Page 54

Classify each of the following as being either a p-type or a n-type semiconductor:

  1. Ge doped with In 
  2. B doped with Si
'NCERT TEXT-BOOK' Exercises | Q 1.21 | Page 54

Gold (atomic radius = 0.144 nm) crystallises in a face-centred unit cell. What is the length of a side of the cell?

'NCERT TEXT-BOOK' Exercises | Q 1.22 (i) | Page 54

In terms of band theory, what is the difference between a conductor and an insulator?

'NCERT TEXT-BOOK' Exercises | Q 1.22 (ii) | Page 54

In terms of band theory, what is the difference between a conductor and a semiconductor?

'NCERT TEXT-BOOK' Exercises | Q 1.23 (i) | Page 55

Explain the Schottky defect.

'NCERT TEXT-BOOK' Exercises | Q 1.23 (ii) | Page 55

Explain the following term with suitable examples: 

Frenkel defect

'NCERT TEXT-BOOK' Exercises | Q 1.23 (iii) | Page 55

Explain the following term with a suitable example:

Interstitials

'NCERT TEXT-BOOK' Exercises | Q 1.23 (iv) | Page 55

Explain the following term with a suitable example:

F-centres

'NCERT TEXT-BOOK' Exercises | Q 1.24 | Page 55

Aluminium crystallises in a cubic close-packed structure. Its metallic radius is 125 pm.

  1. What is the length of the side of the unit cell?
  2. How many unit cells are there in 1.00 cm3 of aluminium?
'NCERT TEXT-BOOK' Exercises | Q 1.25 | Page 55

If NaCl is doped with 10−3 mol % of SrCl2, what is the concentration of cation vacancies?

'NCERT TEXT-BOOK' Exercises | Q 1.26 (i) | Page 55

Explain the following with suitable examples:

Ferromagnetism

'NCERT TEXT-BOOK' Exercises | Q 1.26 (ii) | Page 55

Explain the following with suitable examples:

Paramagnetism

'NCERT TEXT-BOOK' Exercises | Q 1.26 (iii) | Page 55

Explain the following with suitable examples:

Ferrimagnetism

'NCERT TEXT-BOOK' Exercises | Q 1.26 (iv) | Page 55

Explain the following with suitable examples: 

Antiferromagnetism

'NCERT TEXT-BOOK' Exercises | Q 1.26 (v) (a) | Page 55

Explain the following with suitable examples:

12-16 group compounds

'NCERT TEXT-BOOK' Exercises | Q 1.26 (v) (b) | Page 55

Explain the following with suitable examples:

13-15 group compounds

QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 55 - 57]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 55 - 57]

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 1. (i) | Page 55

Distinguish between crystalline solid and amorphous solid.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 1. (ii) (a) | Page 55

State the element present at the lattice sites in diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 1. (ii) (b) | Page 55

The number of nearest neighbours for each atom in diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 1. (ii) (c) | Page 55

The type of unit cell of diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 2. (i) | Page 55

For sodium chloride crystal, state the type of unit cell.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 2. (ii) | Page 55

For sodium chloride crystal, state the nature of the forces holding the particles together.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 2. (iii) | Page 55

For sodium chloride crystal, state the number of nearest neighbours around each sodium ion.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 2. (iv) | Page 55

For sodium chloride crystal, state the geometry of the sodium ions which are arranged around a chloride ion.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 3. (i) | Page 55

Diamond is hard and a bad conductor of electricity, while graphite is soft and a good conductor of electricity. Explain.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 3. (ii) | Page 55

What is the state of hybridisation of carbon in diamond?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 3. (iii) | Page 55

What is the state of hybridisation of carbon in graphite?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 4. | Page 55

Describe the unit cell of sodium chloride with a neat diagram stating:

  1. Type of bonding
  2. Type of unit cell
  3. Number of nearest neighbours around sodium and chloride.

Fill in the blanks.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 5. | Page 55

Crystals of ______ and ______ have face-centred cubic lattices.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 6. (i) | Page 55

Give any three characteristics of ionic crystals.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 6. (ii) | Page 55

State the main characteristics of a network type of crystal citing a suitable example.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 7. (a) | Page 55

Name the crystal structure of the copper metal.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 7. (b) | Page 55

What is the coordination number of copper in its crystalline state?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 8. (a) | Page 55

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 8. (b) | Page 55

What is the coordination number of sodium and chloride ions in sodium chloride crystals?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 9. (i) | Page 55

State the element present at the lattice sites in diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 9. (ii) | Page 55

The number of nearest neighbours for each atom in diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 9. (iii) | Page 55

The type of unit cell of diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 9. (iv) | Page 55

What is the state of hybridisation of carbon in diamond?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 10. (i) | Page 55

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 10. (ii) | Page 55

Give reasons: 

Graphite is used as a lubricant.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 11. (a) (i) | Page 55

Define piezoelectricity.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 11. (a) (ii) | Page 55

Give one use of piezoelectric crystals.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 11. (b) (i) | Page 55

What is a semiconductor?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 11. (b) (ii) | Page 55

What is the effect of increasing temperature on the conductivity of a semiconductor?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 11. (c) | Page 55

A compound AB has a simple cubic structure and has a molecular mass of 99. Its density is 3.4 g cm−3. What will be the edge length of the unit cell?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 12. (a) | Page 56

What are F-centres?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 12. (b) | Page 56

Why are crystals having F-centres paramagnetic?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 13. (a) | Page 56

What is the state of hybridisation of carbon in diamond?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 13. (b) | Page 56

For a crystal of diamond, state the coordination number of each carbon atom.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 13. (c) | Page 56

State the element present at the lattice sites in diamond.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 13. (d) | Page 56

For a crystal of diamond, state the number of carbon atoms present per unit cell.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 14. | Page 56

An ionic compound is made up of A cations and B anions. If A cations are present at the alternate corners and B anion is present on the body of the diagonal, what is the formula of the ionic compound?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 15. | Page 56

Define the Frenkel defect in a solid crystal.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 16. | Page 56

Explain giving reasons, why ionic solids conduct electricity in the molten state, but not in solid-state?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 17. | Page 56

In a crystal of diamond:

  1. How many carbon atoms are present per unit cell?
  2. What type of lattice does diamond crystallise in?
  3. How many carbon atoms surround each carbon atom?
  4. How are they arranged?
QUESTIONS FROM ISC EXAMINATION PAPERS | Q 18. | Page 56

Name the crystal structure of the copper metal.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 19. | Page 56

Chromium metal crystallises with a body centred cubic lattice. The edge length of the unit cell is found to be 287 pm. Calculate the atomic radius. What would be the density of chromium in g/cm3? (atomic mass of Cr = 52.99)

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 20. | Page 56

Why does sodium chloride on heating with sodium vapours acquire yellow colour?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 21. (a) | Page 56

For a crystal of sodium chloride, state the type of lattice in which it crystallises.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 21. (b) | Page 56

What is the coordination number of sodium and chloride ions in sodium chloride crystals?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 21. (c) | Page 56

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 21. (d) | Page 56

For a crystal of sodium chloride, state the structural arrangement of the sodium chloride crystal.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 22. | Page 56

The edge length of the unit cell of a body-centred cubic (bcc) crystal is 352 pm. Calculate the radius of the atom.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 23. | Page 56

Graphite is anisotropic with respect to the conduction of electric current. Explain.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 24. (a) (i) | Page 56

How many lattice points are there in one unit cell of the following lattice?

Body-centred

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 24. (a) (ii) | Page 56

How many atoms constitute one unit cell of a face-centered cubic crystal?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 24. (b) | Page 56

A compound AB has a simple cubic structure and has a molecular mass of 99. Its density is 3.4 g cm−3. What will be the edge length of the unit cell?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 25. | Page 56

In a face-centred cubic lattice, atom (A) occupies the corner positions and atom (B) occupies the face centre positions. If one atom of (B) is missing from one of the face-centred points, the formula of the compound is ______.

  • A2B5

  • A2B3

  • AB2

  • A2B

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 26. | Page 56

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 27. | Page 56

Frenkel defect does not change the density of the ionic crystal whereas Schottky defect lowers the density of ionic crystal. Give a reason.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 28. | Page 56

Lead sulphide has a face-centred cubic crystal structure. If the edge length of the unit cell of lead sulphide is 495 pm, calculate the density of the crystal. 
(Atomic weight of Pb = 207, S = 32)

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 29. | Page 56

Examine the defective crystal given below and answer the question that follows: 

A+ B A+ B A+
B   B A+ B
A+ B A+   A+
B A+ B A+ B

State if the above defect is stoichiometric or non-stoichiometric. How does this defect affect the density of the crystal? Also, write the term used for this type of defect.

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 30. | Page 56

An element occurs in a body-centred cubic structure. Its density is 8.0 g/cm3. If the cell edge is 250 pm, calculate the atomic mass of an atom of this element. (NA = 6.023 × 1023)

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 31. | Page 56

The packing efficiency of simple cubic structure, body centred cubic structure and face-centred cubic structure respectively is ______.

  • 52.4%, 74%, 68%

  • 74%, 68%, 52.4%

  • 52.4%, 68%, 74%

  • 68%, 74%, 52.4%

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 32. | Page 56

An element has atomic mass 93 g mol−1 and density 11.5 g cm–3. If the edge length of its unit cell is 300 pm, identify the type of unit cell. (NA = 6.023 × 1023 mol−1)

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 33. | Page 56

Calculate the radius of copper atom. The atomic weight of copper is 63.55 g mol−1. It crystallises in face-centred cubic lattice and has density of 8.93 g cm−3 at 298 K.

(NA = 6.023 × 1023 mol−1)

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 34. | Page 56

An alloy of gold (Au) and cadmium (Cd) crystallises with a cubic structure in which gold atoms occupy the corners and cadmium atoms fit into the face centres. What is the formula of this alloy?

Select and write the correct alternative from the choices given below

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (i) | Page 56

How many chloride ions are surrounding sodium ions in sodium chloride crystal?

  • 4

  • 8

  • 6

  • 12

  • 3

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (ii) | Page 57

The ratio of number of atoms present in a simple cubic, body-centred cubic and face-centred cubic structure are, respectively ______.

  • 8 : 1 : 6

  • 1 : 2 : 4

  • 4 : 2 : 1

  • 4 : 2 : 3

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (iii) | Page 57

A solid has a structure in which ‘Y’ atoms are located at the corners of a cubic lattice, ‘O’ atoms at the centre of edges and ‘K’ atoms at the centre of the cube. What is the formula of the compound?

  • KYO2

  • KYO3

  • K2YO3

  • K4YO3

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (iv) | Page 57

The appearance of colour in solid alkali metal halides is generally due to ______.

  • Schottky defect

  • Frenkel defect

  • Interstitial positions

  • F-centre

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (v) 1. | Page 57

An element ‘X’ having atomic mass 60 has density 6.23 g cm−3. The edge length of its unit cubic cell is 400 pm. (NA = 6.02 × 1023 mol−1).

What is the type of unit cell known as?

  • Body centred cubic

  • Face centred cubic

  • Simple cubic

  • Side centred cubic

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (v) 2. | Page 57

An element ‘X’ having atomic mass 60 has density 6.23 g cm−3. The edge length of its unit cubic cell is 400 pm. (NA = 6.02 × 1023 mol−1).

What is the radius of an atom of this element?

  • 210.5 pm

  • 344.4 pm

  • 141.4 pm

  • 115.3 pm

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (vi) 1. | Page 57

The radius of silver atom is 143.5 pm and it crystallises in face centred cubic arrangement. (Atomic mass of Ag = 107.47, NA = 6.023 × 1023)

What is the edge length of the unit cell?

  • 405.8 pm

  • 40.6 pm

  • 331.4 pm

  • 287 pm

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (vi) 2. | Page 57

The radius of silver atom is 143.5 pm and it crystallises in face centred cubic arrangement. (Atomic mass of Ag = 107.47, NA = 6.023 × 1023)

What is the density of silver metal?

  • 5.36 g/cm3

  • 8.60 g/cm3

  • 10.72 g/cm3

  • 7.07 g/cm3

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (vii) 1. | Page 57

Niobium crystallises in body centred cubic structure. Its density is 8.55 g cm−3 and its atomic mass is 93 g mol−1. (NA = 6.023 × 1023)

What is the edge length of niobium?

  • 314.50 pm

  • 330.56 pm

  • 340.43 pm

  • 346.30 pm

QUESTIONS FROM ISC EXAMINATION PAPERS | Q 35. (vii) 2. | Page 57

Niobium crystallises in body centred cubic structure. Its density is 8.55 g cm−3 and its atomic mass is 93 g mol−1. (NA = 6.023 × 1023)

What is the atomic radius of niobium?

  • 136 pm

  • 140 pm

  • 143 pm

  • 149 pm

Solutions for 1: Solid State

REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSINTEGER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNUMERICAL PROBLEMS'NCERT TEXT-BOOK' ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State - Shaalaa.com

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State

Shaalaa.com has the CISCE Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Nootan solutions for Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE 1 (Solid State) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

Further, we at Shaalaa.com provide such solutions so students can prepare for written exams. Nootan textbook solutions can be a core help for self-study and provide excellent self-help guidance for students.

Concepts covered in Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 Solid State are Introduction to Solid State, Classification of Solids, Classification of Crystalline Solids, Space Lattice, Definition of Unit Cell, Different Types of Cubic Systems, Number of Particles Per Unit Cell in Different Cubic Systems, Calculation of the Space Occupied (Packing Fraction) in the Unit Cells of Different Types of Cubic Systems, Calculation of Density of a Crystal, Close-packed Structures, Packing of Constituent Particles in Crystals, Voids in Close-Packed Structures, Dimensions of Voids, Location of Tetrahedral Voids, Location of Octahedral Voids, Radius Ratio Rules, Number of Voids Filled and the Formula of the Compound, Types of Crystalline Solids: Molecular Solids, Types of Crystalline Solids: Ionic Solids, Types of Crystalline Solids: Covalent Solids {Atomic or Network Solids), Types of Crystalline Solids: Metallic Solids, Imperfections (Defects) in Solids, Imperfections (Defects) in Solids: Electronic Imperfections, Imperfections (Defects) in Solids: Atomic Imperfections, Imperfections (Defects) Caused by Impurities, Properties of Solids: Electrical Properties, Properties of Solids: Magnetic Properties, Properties of Solids: Dielectric Properties, Amorphous Solids.

Using Nootan Chemistry Part 1 and 2 [English] Class 12 ISC solutions Solid State exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Nootan Solutions are essential questions that can be asked in the final exam. Maximum CISCE Chemistry Part 1 and 2 [English] Class 12 ISC students prefer Nootan Textbook Solutions to score more in exams.

Get the free view of Chapter 1, Solid State Chemistry Part 1 and 2 [English] Class 12 ISC additional questions for Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE, and you can use Shaalaa.com to keep it handy for your exam preparation.

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