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Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State [Latest edition]

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Chapters

Physical Chemistry

▶ 1: Solid State

    2: Solutions

    3: Electrochemistry

    4: Chemical Kinetics

    5: Surface Chemistry

Inorganic Chemistry

    6: General Principles and Processes of Isolation of Elements

    7: p-Block Elements

    8: d-and ƒ-Block Elements

    9: Coordination Compounds

Organic Chemistry

    10: Haloalkanes and Haloarenes

   Chapter 11: Alcohols, Phenols and Ethers

   Chapter 12: Aldehydes, Ketones and Carboxylic Acids

   Chapter 13: Organic Compounds containing Nitrogen

   Chapter 14: Biomolecules

    15: Polymers

   Chapter 16: Chemistry in Everyday Life

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State - Shaalaa.com
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Solutions for Chapter 1: Solid State

Below listed, you can find solutions for Chapter 1 of CISCE Nootan for Chemistry Part 1 and 2 [English] Class 12 ISC.


REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSINTEGER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNUMERICAL PROBLEMS'NCERT TEXT-BOOK' ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
REVIEW EXERCISES [Pages 21 - 37]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State REVIEW EXERCISES [Pages 21 - 37]

1.1 (i)Page 21

What do you understand by unit cell?

1.1 (ii)Page 21

What parameters are used to describe a unit cell?

1.2Page 21

Which crystal system can possess all the four types of unit cell?

1.3Page 21

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

1.4Page 21

Calculate the number of atoms in a cubic based unit cell having one atom at each corner and two atoms on each diagonal.

1.5Page 21

A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?

1.6 (a)Page 21

How many atoms of an element are there in one unit cell of simple cubic?

1.6 (b)Page 21

How many atoms of an element are there in one unit cell of body-centred cubic?

1.6 (c)Page 21

How many atoms constitute one unit cell of a face-centered cubic crystal?

1.7Page 21

The density of a face-centred cubic element (atomic mass = 60.2) is 6.25 g cm−1. Calculate the length of the edge of the unit cell.

1.8Page 21

Crystalline CsBr has a bcc structure. Calculate the unit cell edge length if the density of CsBr crystal is 4.24 g cm−3. (Atomic masses: Cs = 133; Br =  80)

1.9Page 21

An element has bcc structure with a cell edge of 288 pm. The density of the element is 7.2 g cm−3. How many atoms are present in 208 g of the element?

1.10Page 21

The density of KBr is 2.75 g cm−3. The length of the edge of the unit cell is 654 pm. Show that KBr has a face-centred cubic structure (NA = 6.022 × 1023 mol−1, Atomic masses : K = 39, Br = 80).

1.11Page 22

A solid is made up of two elements P and Q. Atoms Q are in hcp arrangement while atoms P occupy all the tetrahedral sites. What is the formula of the compound?

1.12Page 22

In an oxide of aluminium, oxide ions are arranged in ccp arranged and the aluminium ions occupy two third of the octahedral voids. What is the formula of the compound?

1.13Page 22

In a solid, oxide ions are arranged in hcp. One third of octahedral voids are occupied by the cations A and one sixth of the tetrahedral voids are occupied by the cations B. What is the formula of the compound?

1.14Page 22

In a closed packed structure of mixed oxides, the oxide ions are arranged in hcp array. One eighth of tetrahedral voids are occupied by divalent cations (A) while one half of octahedral voids are occupied by trivalent cations (B). What is the formula of the compound?

1.15Page 26

Why are molecular solids soft and possess low melting and boiling points?

1.16Page 26

What are the constituent particles in ionic solids and how are they held together?

1.17Page 26

Sort out the molecular, ionic and covalent solids from the following:

Naphthalene, ZnS, graphite, ice, Agl, silicon carbide.

1.18Page 26

What is the significance of radius ratio in deciding the structural arrangement in an ionic solid?

1.19Page 26

What is the coordination number of NaCl crystal structure?

1.20Page 26

Why are the properties of diamond very different from those of graphite although both are the different forms of the same substance?

1.21 (i)Page 26

Explain the lubricating property of graphite on the basis of its structure.

1.21 (ii)Page 26

Describe the structure of graphite with the help of a labelled diagram.

1.22Page 26

Discuss the crystal structure of copper metal.

1.23Page 26

Why do metals possess lustre and conduct electric current?

1.24 (i)Page 26

Write a short note on isomorphism.

1.24 (ii)Page 26

Write a short note on isopolymorphism.

1.25Page 31

Define point defects in solids.

1.26Page 31

What is Schottky defect in a solid?

1.27Page 31

What is the effect of the presence of Schottky defects on the density of a crystal?

1.28Page 31

What are F-centres?

1.29Page 31

Pure silicon does not conduct electricity. How can it be made a conductor of electricity? Explain with examples.

1.30Page 31

AgCl is doped with 10−2 mol% of CdCl2. Find the concentration of cation vacancies.

1.31Page 31

What other element may be added to silicon to make electrons available for conduction of an electric current?

1.32Page 31

What is the non-stoichiometry defect in crystals?

1.33Page 32

Why does Frenkel defect not change the density of AgCl crystals?

1.34Page 32

State the difference between Schottky and Frenkel defects. Which of these two changes the density of the solid?

1.35Page 32

Name a salt that can be added to AgCl so as to produce cation vacancies.

1.36Page 32

Which point defect lowers the density of a crystal?

1.37Page 32

Name a salt that can be added to AgCl so as to produce cation vacancies.

1.38Page 32

What makes alkali metal halides sometimes coloured, which are otherwise colourless?

1.39Page 32

Why does table salt, NaCl, sometimes appear yellow in colour?

1.40 (i)Page 32

What is a semiconductor?

1.40 (ii)Page 32

Describe the two main types of semiconductors and contrast their conduction mechanism.

1.41Page 32

What type of crystal defect is produced when sodium chloride is doped with MgCl2?

1.42 (i)Page 37

Name the electrical property possessed by the following oxide:

TiO

1.42 (ii)Page 37

Name the electrical property possessed by the following oxide:

Ti2O3

1.42 (iii)Page 37

Name the electrical property possessed by the following oxide:

TiO2

1.42 (iv)Page 37

Name the electrical property possessed by the following oxide:

CrO2

1.42 (v)Page 37

Name the electrical property possessed by the following oxide: 

Cr2O3

1.43Page 37

Sort out the diamagnetic, paramagnetic and ferromagnetic substances among the following:

O2, Fe, TiO2, Cu2+, Fe3+, Ni, CrO2, C6H6, NaCl.

1.44 (i)Page 37

What are paramagnetic substances?

1.44 (ii)Page 37

What are ferromagnetic substances?

1.44 (iii)Page 37

Account for the paramagnetic character of transition metal compounds.

1.44 (iv)Page 37

How does the paramagnetic character of the bivalent ions of first transition metal series vary from titanium (Z = 22) to copper (Z = 29)?

1.45 (i)Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Semiconductor

1.45 (ii)Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Metallic conductor

1.45 (iii)Page 37

How does the electrical resistivity of the following class of material vary with temperature?

Superconductor

1.46Page 37

Name any two superconducting materials which show superconductivity above 100 K.

1.47Page 37

Compare dia, para and ferromagnetism.

1.48Page 37

Explain the dielectric properties of solids.

1.49Page 37

Distinguish between crystalline solid and amorphous solid.

1.50Page 37

How would you convert a crystalline solid into an amorphous solid?

1.51Page 37

What is the difference between ferromagnetic and ferrimagnetic substances?

1.52Page 37

What is the utility of piezoelectric crystals?

1.53Page 37

What happens when ferrimagnetic Fe3O4 is heated at 850 K and why?

1.54 (i)Page 37

What are amorphous solids?

1.54 (ii)Page 37

Discuss the properties of amorphous solids.

1.54 (iii)Page 37

Discuss the uses of amorphous solids.

VERY SHORT ANSWER TYPE QUESTIONS [Pages 42 - 43]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State VERY SHORT ANSWER TYPE QUESTIONS [Pages 42 - 43]

1.Page 42

What type of solids do possess a long range order?

2.Page 42

Name different types of crystalline solids.

3. (i)Page 42

Define the term space lattice.

3. (ii)Page 42

Define lattice points.

4.Page 42

What do you understand by unit cell?

5.Page 42

How many atoms of an element are there in one unit cell of simple cubic?

6.Page 42

What do you understand by a face-centred unit cell?

7.Page 42

What is a body-centred cubic system?

8.Page 42

How many atoms constitute one unit cell of a face-centered cubic crystal?

9.Page 42

What is the percentage of the occupied space in a simple cubic unit cell?

10.Page 42

What is the name of the unit cell in which the atoms are present at the corners of all 12 edges of a cube in a unit cell?

11.Page 42

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

12.Page 42

What is the edge length of a face-centred cubic unit cell if the radius of the atom is r?

13.Page 42

What is the coordination number in a two dimensional hexagonal close packing?

14.Page 42

What is a void?

15. (i)Page 42

What is the coordination number of atoms in a cubic close-packed structure?

15. (ii)Page 42

What is the coordination number in a close-packed structure (hcp)?

16.Page 42

What is the coordination number of atoms in a bcc structure?

17.Page 42

Define a tetrahedral void.

18. (i)Page 42

If a close-packed structure contains n particles, what would be the number of tetrahedral voids in the structure?

18. (ii)Page 42

If a close-packed structure contains n particles, what would be the number of octahedral voids in the structure?

19.Page 42

If the radius of a particle is R, what would be the radius of a tetrahedral void present in the close-packed structure of the given particles?

20.Page 42

What is the ratio of the radius of an octahedral void to that of the constituent particle?

21.Page 42

In an ionic crystal, the radius ratio is greater than 0.732. What is the coordination number of the crystal?

22.Page 42

In the crystal of zinc sulphide, zinc occupies tetrahedral voids. What is the coordination number of zinc?

23.Page 42

What type of close-packing is possessed by a crystal of NaCl?

24. (i)Page 42

Name the ions forming the close-packed structure in NaCl crystals.

24. (ii)Page 42

Name the ions present in voids in NaCl crystals.

25.Page 42

What is Schottky defect in a solid?

26.Page 42

What do you understand by the fact that CaF2 has 8 : 4 coordination?

27.Page 42

What are electronic imperfections in crystals?

28.Page 42

What type of ionic compounds show Schottky defects?

29.Page 42

Write the effect on density of a substance in the Frenkel defect?

30.Page 42

What are F-centres?

31.Page 42

What do you understand by doping of a crystal?

32.Page 42

What is a semiconductor?

33.Page 42

How do paramagnetic substances behave in the absence of a magnetic field?

34.Page 42

What happens when ferrimagnetic Fe3O4 is heated at 850 K and why?

35.Page 42

What is pyroelectricity?

36.Page 42

What is piezoelectricity?

37.Page 42

What happens when an electric field is applied to a piezoelectric crystal?

38.Page 42

What do you understand by superconductivity?

39.Page 42

What happens when amorphous solids are subjected to annealing?

40.Page 42

What type of order is present in amorphous solids?

41.Page 42

Give reason for the following:

Ionic compounds do not conduct electricity in solid state.

42.Page 42

What is the effect of increasing temperature on the conductivity of a semiconductor?

43.Page 42

How does amorphous silica differ from quartz?

44.Page 42

What is a void?

45.Page 42

Compare dia, para and ferromagnetism.

46.Page 42

In a close packing of spheres, what is the value of radius ratio (radius of an octahedral void/radius of sphere)?

47. (i)Page 42

How can you convert NaCl structure into CsCl structure?

47. (ii)Page 42

How can you convert CsCl structure into NaCl structure?

48.Page 42

What causes the conduction of electricity by semiconductors?

49.Page 42

What type of crystals exhibit piezoelectricity?

50.Page 42

Agl crystallises in cubic close-packed ZnS structure. What fraction of tetrahedral sites are occupied by Ag+ ions?

51.Page 43

Classify each of the following solids as ionic, metallic, molecular, covalent or amorphous. 

  1. P4O10
  2. Graphite
  3. Brass
  4. (NH4)3PO4
  5. SiC
  6. Rb
  7. I2
  8. LiBr
  9. P4
  10. Si
  11. Plastic
52.Page 43

Classify each of the following as being either a p-type or a n-type semiconductor:

  1. Ge doped with In 
  2. B doped with Si
SHORT ANSWER TYPE QUESTIONS [Pages 43 - 44]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State SHORT ANSWER TYPE QUESTIONS [Pages 43 - 44]

1.Page 43

What are the main characteristics of crystalline solids?

2. (i)Page 43

What do you understand by space lattice?

2. (ii)Page 43

What do you understand by unit cell?

3. (i)Page 43

What do you understand by unit cell?

3. (ii)Page 43

What parameters are used to describe a unit cell?

4. (i)Page 43

What is a primitive unit cell?

4. (ii)Page 43

Name the different types of primitive unit cells.

5.Page 43

How many types of unit cells are present in different types of crystals? Explain with appropriate figures.

6.Page 43

Describe the various types of cubic systems.

7.Page 43

Explain why uncharged atoms or molecules never crystallise in a simple cubic structure.

8. (i)Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the corner?

8. (ii)Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the centre of a face?

8. (iii)Page 43

In a cubic unit cell, what is the contribution to the unit cell of the particle present at the body centre?

9. (i)Page 43

How many atoms of an element are there in one unit cell of simple cubic?

9. (ii)Page 43

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

9. (iii)Page 43

Find the number of atoms in the fcc unit cell.

10.Page 43

What is the percentage of the occupied space in a simple cubic unit cell?

11.Page 43

Show that the face diagonal of a cube is equal to `sqrt2  a`, where a is the edge length.

12.Page 43

Show that the packing fraction in a face-centred cubic unit cell is 0.74.

13.Page 43

In a face-centred cubic arrangement of atoms A and B, A are present at the corners and B at the face-centres. If A atoms are missing from 4 corners in each unit cell, what is the simplest formula of the compound?

14.Page 43

An element crystallises separately both in hcp and ccp structures. Will the two structures have the same density? If yes, why?

15.Page 43

Explain why the hexagonal close packing is more efficient than square close packing when considered in a plane?

16.Page 43

Distinguish between hexagonal close packing and cubic close packing.

17. (i)Page 43

What is meant by the term ‘coordination number’?

17. (ii) (a)Page 43

Mention the coordination number of each sphere in a hexagonal close-packed structure.

17. (ii) (b)Page 43

Mention the coordination number of each sphere in a body-centred close-packed structure.

18. (i)Page 43

What do you understand by voids in close-packed structures?

18. (ii)Page 43

Define a tetrahedral void.

18. (iii)Page 43

Define octahedral void.

19.Page 43

Show that the radius of a tetrahedral void is 0.225 times the radius of the sphere forming a close-packed structure.

20.Page 43

Show that a particle of radius less than 0.441 times the radius of the constituent particle can only be placed in an octahedral void without disturbing the crystal lattice.

21. (i)Page 44

What do you understand by radius ratio?

21. (ii)Page 44

What is the ideal radius ratio for octahedral arrangement?

22.Page 44

An ionic solid possesses a body-centred close-packed structure. What is the ideal radius ratio and coordination number for the structure?

23.Page 44

How would you decide that a given hard and rigid solid possessing high melting and boiling points is ionic or covalent?

24.Page 44

What types of structures are possessed by ionic solids of the type AB? Explain with diagrams.

25. (i)Page 44

Explain the structure of NaCl.

25. (ii)Page 44

Find the number of ion pairs per unit cell in NaCl.

26. (i)Page 44

What is the effect of pressure on the structures of the ionic crystals of the type AB?

26. (ii)Page 44

What is the effect of temperature on the structures of the ionic crystals of the type AB?

27. (i)Page 44

What do you understand by imperfections in ionic crystals?

27. (ii)Page 44

Name the type of imperfections which generally occur in ionic crystals.

28.Page 44

Explain why does the presence of Frenkel defects not affect the density of a crystal.

29. (i)Page 44

How does the Schottky defect increase the conductivity of a crystal?

29. (ii)Page 44

How does the Frenkel defect increase the conductivity of a crystal?

30.Page 44

How does a crystal having metal excess defect maintain its electrical neutrality?

31.Page 44

Why does a crystal of KCl appear violet in colour in spite of the fact that both K+ and Cl ions are colourless?

32.Page 44

What are F-centres?

33. (i)Page 44

What do you mean by doping?

33. (ii)Page 44

Why does the impurity-doped silicon act as a semiconductor?

34. (i)Page 44

What is a semiconductor?

34. (ii)Page 44

What factors are responsible for the conduction of current by a semiconductor?

34. (iii)Page 44

Mention important applications of semiconductors.

35. (i)Page 44

What is ferromagnetism?

35. (ii)Page 44

How does ferromagnetism arise?

36.Page 44

Why do ferrimagnetic substances possess small net magnetic moments in spite of the presence of a large number of unpaired electrons?

37. (i)Page 44

What happens when a piezoelectric crystal is subjected to a mechanical stress?

37. (ii)Page 44

What happens when an electric field is applied to a piezoelectric crystal?

38. (i)Page 44

Why are the amorphous solids said to possess short range order?

38. (ii)Page 44

Discuss the properties of amorphous solids.

39.Page 44

What type of crystal defect is produced when sodium chloride is doped with MgCl2?

40. (i)Page 44

Explain the Schottky defect.

40. (ii)Page 44

What are the consequences of the Schottky defect in crystals?

40. (iii)Page 44

What are the consequences of Frenkel defects in crystals?

41.Page 44

If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.

42.Page 44

Stability of a crystal is reflected in the magnitude of its melting point. Comment.

LONG ANSWER TYPE QUESTIONS [Pages 44 - 45]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State LONG ANSWER TYPE QUESTIONS [Pages 44 - 45]

1. i.Page 44

How are the solids classified?

1. ii.Page 44

Compare the properties of crystalline and amorphous solids.

2.Page 44

Explain the characteristics of different types of crystalline solids.

3. (i)Page 44

Discuss the characteristics of various types of unit cells.

3. (ii)Page 44

How would you calculate the number of particles in a unit cell?

4. (i)Page 44

How many atoms of an element are there in one unit cell of simple cubic?

4. (ii)Page 44

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

4. (iii)Page 44

Find the number of atoms in the fcc unit cell.

5. (i)Page 44

Calculate the percentage efficiency of packing in the case of a body-centred cubic crystal.

5. (ii)Page 44

Calculate the percentage of the occupied space in a face-centred cubic unit cell.

6.Page 45

Show that the packing fraction in a simple cubic unit cell is 0.524 and the radius of the atom is equal to half of the edge length.

7.Page 45

The unit cell of the crystal of an element has Z atoms and the edge length equal to a. If the molecular mass of the element is M, calculate the density of the crystal.

8. (i)Page 45

Explain with a diagram the hcp mode of packing in crystals. 

8. (ii)Page 45

Explain with diagrams the ccp mode of packing in crystals.

8. (iii)Page 45

Distinguish between hexagonal close packing and cubic close packing.

9. (i)Page 45

What are the voids commonly found in close-packed structures?

9. (ii)Page 45

Show that the radius of a tetrahedral void is 0.225 times the radius of the sphere forming a close-packed structure.

9. (iii)Page 45

Calculate the radii of octahedral voids in terms of the radius of the spheres forming close-packed structures.

10. (i)Page 45

What do you understand by radius ratio?

10. (ii)Page 45

What is the significance of the radius ratio in determining the structural arrangement and coordination number of an ionic solid?

11.Page 45

Explain the structure of NaCl.

12.Page 45

Show that a unit cell of sodium chloride contains four Na+Cl units.

13. (i)Page 45

Explain the Schottky defect.

13. (ii)Page 45

Explain with a diagram the Frenkel defect.

13. (iii)Page 45

How do Schottky defects affect the properties of crystals?

13. (iv)Page 45

How do Frenkel defects affect the properties of crystals?

14.Page 45

Describe the various types of non-stoichiometric defects found in ionic crystals.

15. (i)Page 45

What do you understand by doping of a crystal?

15. (ii)Page 45

How are the impurity defects introduced into covalent solids?

15. (iii)Page 45

How are the impurity defects introduced into ionic solids?

15. (iv)Page 45

In what way is the electrical conductivity of a crystal affected by doping?

16.Page 45

Classify the solids on the basis of their electrical properties.

17.Page 45

Describe the various types of magnetic substances with the help of electron spin and explain their characteristics.

18. (i)Page 45

What is piezoelectricity?

18. (ii)Page 45

Why are the piezoelectric crystals used in record players?

19. (i)Page 45

Write a short note on pyroelectricity.

19. (ii)Page 45

Write a short note on ferroelectricity.

19. (iii)Page 45

Write a short note on antiferroelectricity.

20.Page 45

Explain why all ferroelectric crystals behave as piezoelectric crystals but the reverse is not true.

21.Page 45

Explain why there is no current in a metal although there are free electrons in motion.

22.Page 45

Explain why doping produces cation vacancies and not the anion vacancies.

23. (i)Page 45

What are amorphous solids?

23. (ii)Page 45

Discuss the properties of amorphous solids.

23. (iii)Page 45

Discuss the uses of amorphous solids.

24. (i)Page 45

How would you convert silica into a glassy substance? Explain the structure of the substance thus obtained.

24. (ii)Page 45

Why do the glass objects from ancient civilizations look milky instead of being transparent?

25. (a)Page 45

Explain the following with suitable examples:

Ferromagnetism

25. (b)Page 45

Explain the following with suitable examples:

Paramagnetism

25. (c)Page 45

Explain the following with suitable examples:

Ferrimagnetism

25. (d)Page 45

Explain the following with suitable examples:

Piezoelectric effect

25. (e) (i)Page 45

Explain the following with suitable examples:

12-16 group compounds

25. (e) (ii)Page 45

Explain the following with suitable examples:

13-15 group compounds

26. (a)Page 45

Explain the Schottky defect.

26. (b)Page 45

Explain with a diagram the Frenkel defect.

26. (c)Page 45

Explain the following term with a suitable example:

Interstitials

26. (d)Page 45

Explain the following term with a suitable example:

F-centres

27.Page 45

What makes a glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?

28. (i)Page 45

What is a semiconductor?

28. (ii)Page 45

Describe the two main types of semiconductors and mention their important applications.

29. (i)Page 45

How are the crystalline solids classified?

29. (ii)Page 45

Describe the important characteristics of crystalline solids.

30. (i)Page 45

What are molecular solids?

30. (ii)Page 45

Explain the characteristics of different types of crystalline solids.

30. (iii)Page 45

Discuss the crystal structure of dry ice.

31. (i)Page 45

Give any three characteristics of ionic crystals.

31. (ii)Page 45

Explain the structure of NaCl.

32. (i)Page 45

What is meant by covalent solids?

32. (ii)Page 45

Discuss the structures of diamond. How would you explain the properties of these substances on the basis of their structures?

32. (iii)Page 45

Describe the structure of graphite with the help of a labelled diagram.

33. (i)Page 45

What are metallic solids?

33. (ii)Page 45

What are the characteristics of metallic solids?

33. (iii)Page 45

Describe the important features of metallic bonding.

33. (iv)Page 45

Discuss the crystal structure of copper metal.

INTEGER TYPE QUESTIONS [Page 45]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State INTEGER TYPE QUESTIONS [Page 45]

1.Page 45

The distance between Na+ and Cl ions in solid NaCl of density 43.1 g cm−3 is ______ × 10 −10 m (Nearest integer).

(Given: NA = 6.02 × 1023 mol−1)

2.Page 45

Atoms of element X form hcp lattice and those of element Y occupy `2/3` of its tetrahedral voids. The percentage of element X in the lattice is ______ (Nearest integer).

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 46 - 47]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 46 - 47]

Choose the correct option in the following questions.

1.Page 46

Which one is not the property of a crystalline solid?

  • Isotropic

  • Sharp melting point

  • A definite and regular geometry

  • High intermolecular forces

2.Page 46

Tetragonal crystal system has the following unit cell dimensions:

  • a = b = c, α = β = γ = 90°

  • a = b ≠ c, α = β = γ = 90°

  • a ≠ b ≠ c, α = β = γ = 90°

  • a = b ≠ c, α = β = γ = 90°, γ = 120°

3.Page 46

The coordination number of each sphere in hcp arrangement is ______.

  • 8

  • 12

  • 6

  • 4

4.Page 46

The number of atoms contained in one face-centred cubic unit cell of a monoatomic substance is ______.

  • 1

  • 2

  • 4

  • 3

5.Page 46

How many chloride ions are surrounding sodium ions in sodium chloride crystal?

  • 4

  • 8

  • 6

  • 12

  • 3

6.Page 46

For an ionic crystal of general formula AX and coordination number 6, the value of radius ratio will be ______.

  • greater than 0.73

  • in between 0.73 and 0.41

  • in between 0.41 and 0.22

  • less than 0.22

7.Page 46

Potassium crystallises in bcc lattice, the coordination number of potassium in potassium metal is ______.

  • 12

  • 4

  • 6

  • 8

8.Page 46

Coordination number of Cu is ______.

  • 4

  • 6

  • 8

  • 12

9.Page 46

An ionic compound is made up of P cations and Q anions. If P are present at alternate corners and Q is present on the body of the diagonal, then the formula of the ionic compound will be ______.

  • PQ

  • PQ2

  • P2Q

  • P4Q

10.Page 46

In a crystal, the atoms are located at the position of ______.

  • maximum P.E.

  • minimum P.E.

  • zero P.E.

  • infinite P.E.

11.Page 46

An element A (atomic mass 60) has simple cubic lattice of edge 100 pm. The density of crystal (N0 = 6 × 1023) is ______.

  • 600 g cm−3

  • 1 × 104 g cm−3

  • 6 × 10−2 g cm−3

  • 1 × 102 g cm−3

12.Page 46

The intermetallic compound LiAg crystallises in cubic lattice in which both lithium and silver have coordination number of eight. The crystal class is ______.

  • simple cubic

  • body-centred cubic

  • face-centred cubic

  • none of these

13.Page 46

A solid has a structure in which W atoms are located at the corners of a cubic lattice, O atoms at the centre of edges and Na atoms at the centre of the cube. The formula of the compound is ______.

  • NaWO2

  • NaWO3

  • Na2WO3

  • NaWO4

14.Page 46

For tetrahedral coordination, the radius ratio (r+/r) should be ______.

  • 0.155−0.225

  • 0.225−0.414

  • 0.444−0.732

  • 0.732−1

15.Page 46

If edge of a bcc crystal of an element is a cm, M is the atomic mass and N0 the Avogadro’s number, the density of the crystal is ______.

  • `(4M)/(N_0a^3)`

  • `(2N_0)/(Ma^3)`

  • `(2M)/(N_0a^3)`

  • `(Ma^3)/(2N_0)`

16Page 46

In a compound AB2O4, oxide ions are arranged in ccp and cations A are present in octahedral voids. Cations B are equally distributed between octahedral and tetrahedral voids. The fraction of the octahedral voids occupied is ______.

  • `1/2`

  • `1/4`

  • `1/8`

  • `1/6`

17.Page 46

Potassium has a bcc structure with nearest neighbour distance of 4.52 Å. Its atomic weight is 39. Its density will be ______.

  • 454 kg m−3

  • 804 kg m−3

  • 852 kg m−3

  • 908 kg m−3

18.Page 4

A compound formed by atoms X and Y crystallises in the cubic structure. The atoms X are present at the corners of a cube while atoms Y are at the face-centres. The formula of the compound is ______.

  • XY

  • X2Y

  • X3Y

  • XY3

19.Page 46

In a face-centred cubic system, the distance d between the nearest neighbours is given by ______.

  • d = a

  • `d = sqrt 2a`

  • `d = (sqrt 3a)/2`

  • `d = a/sqrt2`

20.Page 46

An element crystallises in body-centred cubic structure. If the edge length of the cubic unit cell is 400 pm, the interatomic distance in the crystal is ______.

  • 346.4 pm

  • 282.8 pm

  • 400 pm

  • 200 pm

21.Page 46

A face-centred cubic element (atomic mass = 60) has a cell edge of 400 pm. What is its density?

  • 0.623 g cm−3

  • 6.23 g cm−3

  • 62.3 g cm−3

  • 0.0623 g cm−3

22.Page 46

An element occurs in bcc structure. Its density is 8.0 g cm−3. If the cell edge is 250 pm, the atomic mass of the element is ______.

  • 26.4 g mol−1

  • 37.6 g mol−1

  • 54.5 g mol−1

  • 86.1 g mol−1

23.Page 46

Which of the following statements is not true?

  • The radius of a tetrahedral void is 0.225 times the radius of the particle.

  • The radius of an octahedral void is 0.732 times the radius of the particle.

  • The space occupied in bcc arrangement is 68%.

  • The number of tetrahedral voids in a close-packed structure is double that of the number of constituent particles.

24.Page 46

Gold crystallises in a ccp lattice. How many nearest neighbours does a gold atom possess?

  • 6

  • 8

  • 10

  • 12

25.Page 46

Which of the following statements is not true for rock salt (NaCl) structure?

  • The structure is of fcc type.

  • Cl ions are present at the corners and face-centres of a cube.

  • Na+ ions are present in alternate tetrahedral voids.

  • The structure has 6 : 6 coordination.

26.Page 46

Which of the following substances is ferromagnetic?

  • Fe

  • Ni

  • MnO

  • Fe3O4

27.Page 46

The point defect which lowers the density of a crystal is ______.

  • Schottky defect

  • Frenkel defect

  • Schottky defect and Frenkel defect

  • None of these

28.Page 46

The presence of F-centres in a crystal makes it ______.

  • conducting

  • colourless

  • non-conducting

  • coloured

29.Page 46

When a group 13 element is added in small amounts to Ge, the material obtained is ______.

  • an insulator

  • an n-type semiconductor

  • a p-type semiconductor

  • a super conductor

30.Page 46

Which of the following sets of magnetic moments represents an antiferromagnetic substance?

  • ↑↑↑↑↑↑

  • ↑↓↑↓↑↓

  • ↑↑↓↑↑↓

  • ↑↑↓↓↑

31.Page 46

Which of the following statements is not true?

  • Piezoelectric crystals produce electricity when subjected to a mechanical stress.

  • The electric current produced on heating certain polar crystals is called ferroelectricity.

  • PbZrO3 is an antiferroelectric substance.

  • Piezoelectric crystals are used as pickups in record players.

32.Page 46

In a solid lattice, the cation has left a lattice site and is located at an interstitial position. The lattice defect is ______.

  • Frenkel defect

  • Schottky defect

  • Non-stoichiometric defect

  • Valence defect

33.Page 46

CsBr contains bcc structure. The length of its one side is 4.3 Å. The minimum distance between Cs+ and Br ions will be ______.

  • 0.897 Å

  • 3.72 Å

  • 1.794 Å

  • none of these

34.Page 46

Germanium is an example of ______.

  • an intrinsic semiconductor

  • an extrinsic semiconductor

  • an insulator

  • an n-type semiconductor

35.Page 46

Which type of semiconductor is obtained on mixing arsenic into silicon?

  • n-type

  • p-type

  • p-n type

  • n-p type

36.Page 46

How many unit cells are present in a cube-shaped ideal crystal of NaCl of mass 1.00 g? [Atomic masses: Na = 23, Cl = 35.5]

  • 5.14 × 1021 unit cells

  • 1.28 × 1021 unit cells

  • 1.71 × 1021 unit cells

  • 2.57 × 1021 unit cells

37.Page 46

What type of crystal defect is indicated in the diagram below?

  • Frenkel defect

  • Schottky defect

  • Interstitial defect

  • Frenkel and Schottky defects

38.Page 46

An ionic compound has a unit cell consisting of A ions at the corners of a cube and B ions on the centres of the faces of the cube. The empirical formula for this compound would be ______.

  • A3B

  • AB3

  • A2B

  • AB

39.Page 46

Total volume of atoms present in a face-centred cubic unit cell of a metal (r is atomic radius) is ______.

  • `20/3  pi r^3`

  • `24/3  pi r^3`

  • `12/3  pi r^3`

  • `16/3  pi r^3`

40.Page 46

In a compound, atoms of element Y form ccp lattice and those of element X occupy `2/3`rd of tetrahedral voids. The formula of the compound will be ______.

  • X4Y3

  • X2Y3

  • X2Y

  • X3Y4

41.Page 46

AB crystallises in a body-centred cubic lattice with edge length ‘a’ equal to 387 pm. The distance between two oppositively charged ions in the lattice is ______.

  • 335 pm

  • 250 pm

  • 200 pm

  • 300 pm

42.Page 46

A metal crystallises with a face-centred cubic lattice. The edge of the unit cell is 408 pm. The diameter of the metal atom is ______.

  • 288 pm

  • 408 pm

  • 144 pm

  • 204 pm

43.Page 46

The number of octahedral void(s) per atom present in a cubic close-packed structure is ______.

  • 1

  • 3

  • 2

  • 4

44.Page 47

If ‘a’ is the length of the side of the cube, the distance between the body-centered atom and one corner atom in the cube will be ______.

  • `(2/sqrt 3) a`

  • `(4/sqrt 3) a`

  • `(sqrt 3/4) a`

  • `(sqrt 3/2) a`

45.Page 47

Sodium metal crystallises in a body-centred cubic lattice with a unit cell edge of 4.29 Å. The radius of the sodium atom is approximately ______.

  • 5.72 Å

  • 0.93 Å

  • 1.86 Å

  • 3.22 Å

46.Page 47

If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are ______.

  • `1/2, 1/8`

  • `1, 1/4`

  • `1/2, 1/2`

  • `1/4, 1/8`

47.Page 47

Lithium has a bcc structure. Its density is 530 kg m−3 and its atomic mass is 6.94 g mol−1. Calculate the edge length of a unit cell of lithium metal. (NA = 6.02 × 1023 mol−1)

  • 154 pm

  • 352 pm

  • 527 pm

  • 264 pm

48.Page 47

The ionic radii of A+ and B are 0.98 × 10−10 m and 1.81 × 10−10 m. The coordination number of each ion in AB is ______.

  • 8

  • 2

  • 6

  • 4

49.Page 47

Which is the incorrect statement?

  • FeO0.98 has non stoichiometric metal deficiency defect.

  • Density decreases in case of crystals with Schottky’s defect.

  • NaCl (s) is insulator, silicon is semiconductor, silver is conductor, quartz is piezoelectric crystal.

  • Frenkel defect is favoured in those ionic compounds in which sizes of cations and anions are almost equal.

50.Page 47

A metal crystallises in a face-centred cubic structure. If the edge length of its unit cell is ‘a’, the closest approach between two atoms in metallic crystal will be ______.

  • `sqrt 2 a`

  • `a/sqrt 2`

  • 2a

  • `2 sqrt 2 a`

51.Page 47

Which type of ‘defect’ has the presence of cations in the interstitial sites?

  • Schottky defect

  • Vacancy defect 

  • Frenkel defect

  • Metal deficiency defect

52.Page 47

Iron exhibits bcc structure at room temperature. Above 900°C, it transforms to fcc structure. The ratio of density of iron at room temperature to that at 900°C (assuming molar mass and atomic radii of iron remains constant with temperature) is ______.

  • `(3 sqrt 3)/(4 sqrt 2)`

  • `(4 sqrt 3)/(3 sqrt 2)`

  • `sqrt 3/sqrt 2`

  • `1/2`

53.Page 47

An element has a face-centred cubic (fcc) structure with a cell edge of a. The distance between the centres of two nearest tetrahedral voids in the lattice is ______.

  • a

  • `3/2  a`

  • `a/2`

  • `sqrt 2  a`

54.Page 47

A compound is formed by cation C and anion A. The anions form hexagonal close-packed (hcp) lattice and the cations occupy 75% of octahedral voids. The formula of the compound is ______.

  • C2A3

  • C3A2

  • C3A4

  • C4A3

55.Page 47

An element has a body centered cubic (bcc) structure with a cell edge of 288 pm. The atomic radius is ______.

  • `sqrt 3/4 xx 288  "pm"`

  • `sqrt 2/4 xx 288  "pm"`

  • `4/sqrt3 xx 288  "pm"`

  • `4/sqrt 2 xx 288  "pm"`

56.Page 47

A diatomic molecule X2 has a body-centered cubic (bcc) structure with a cell edge of 300 pm. The density of the molecule is 6.47 g cm−3. The number of molecules present in 200 g of X2 is ______.

  • 4 NA

  • 2 NA

  • 40 NA

  • 8 NA

57.Page 47

The right option for the number of tetrahedral and octahedral voids in the hexagonal primitive unit cell is ______.

  • 6, 12

  • 2, 1

  • 12, 6

  • 8, 4

58.Page 47

The correct option for the number of body-centered unit cells in all 14 types of Bravais lattice unit cells is ______.

  • 3

  • 7

  • 5

  • 2

59.Page 47

In a binary compound, atoms of element A form a hcp structure and those of element M occupy `2/3` of the tetrahedral voids of 3 the hcp structure. The formula of the binary compound is ______.

  • M2A3

  • M4A3

  • M4A

  • MA4

60.Page 47

For the given close packed structure of a salt made of cation X and anion Y shown below (ions of only one face are shown for clarity), the packing fraction is approximately:

  • 0.74

  • 0.63

  • 0.52

  • 0.48

61.Page 47

Copper crystallises in fcc unit cell with cell edge length of 3.608 × 10−8 cm. The density of copper is 8.92 g cm−3. Calculate the atomic mass of copper.

  • 31.55 u

  • 60 u

  • 65 u

  • 63.1 u

62.Page 47

Choose the correct statement:

  • Diamond is covalent and graphite is ionic.

  • Diamond is sp3 hybridised and graphite is sp2 hybridised.

  • Both diamond and graphite are used as dry lubricants.

  • Diamond and graphite have two dimensional network.

63.Page 47

The incorrect statement about the imperfections in solids is ______.

  • Schottky defect decreases the density of the substance.

  • Interstitial defect increases the density of the substance.

  • Frenkel defect does not alter the density of the substance. 

  • Vacancy defect increases the density of the substance.

64.Page 47

Atom X occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to ______.

  • 25

  • 35

  • 55

  • 75

FILL IN THE BLANKS TYPE QUESTIONS [Pages 49 - 50]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State FILL IN THE BLANKS TYPE QUESTIONS [Pages 49 - 50]

1.Page 49

If a molten crystalline solid is cooled, the original ______ reappears again.

2.Page 49

Amorphous solids are regarded as ______ liquids.

3.Page 49

The smallest three dimensional group of lattice points, which when repeated in three dimensions in space gives the whole lattice of the crystal, is called ______.

4.Page 50

The unit cell in which one constituent particle is present at the centre in addition to the particles at its corners is called ______ unit cell.

5.Page 50

The unit cell of a body-centred cubic system contains ______ atoms.

6.Page 50

Both ccp and hcp are ______ packings and occupy about ______% of the available space.

7.Page 50

The number of nearest neighbours with which a given particle is in direct contact in a crystal is called the ______.

8.Page 50

In a close-packed structure, the number of tetrahedral voids is ______ the number of constituent particles because every void has ______ particles and there are ______ voids around each particle.

9.Page 50

A cation would exactly fit into an octahedral void in the lattice formed by anions if `r_+/r_-` is exactly equal to ______.

10.Page 50

In the sodium chloride structure, each Na+ ion is surrounded by six Cl ions nearest neighbours and ______ Na+ ions next nearest neighbours.

11.Page 50

If the radius ratio `(r_+/r_-)` is in the range 0.414 − 0.732, the compound AB is likely to have ______ structure.

12.Page 50

The percentages of unoccupied spaces in bcc and fcc arrangements are ______ and ______ respectively.

ASSERTION-REASON TYPE QUESTIONS [Page 50]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State ASSERTION-REASON TYPE QUESTIONS [Page 50]

The questions given below consist of an Assertion and a Reason. You have to choose the correct answer (a), (b), (c) or (d) according to the following clue:

1.Page 50

Assertion: The presence of Frenkel defect in a crystal lowers its density.

Reason: Frenkel defect involves the creation of a hole in the lattice of a crystal due to migration of a cation from its lattice site to an interstitial site.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

2.Page 50

Assertion: Silicon forms covalent crystals.

Reason: Its lattice consists of silicon atoms bonded together by covalent bonds in a three dimensional network.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

3.Page 50

Assertion: The unit cell of a face-centred cubic system contains 4 atoms.

Reason: The unit cell of a face-centred cubic system consists of atoms at face centres in addition to atoms at the corners.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

4.Page 50

Assertion: In rock salt structure, Cl ions form a close-packed lattice and Na+ ions occupy the octahedral voids.

Reason: Sodium chloride possesses a face-centred cubic arrangement.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

5.Page 50

Assertion: KCl crystals appear violet in colour.

Reason: The violet colour is due to electrons trapped in anion vacancies.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

6.Page 50

Assertion: In a particular point defect, an ionic solid is electrically neutral, even if few of its cations are missing from its unit cells.

Reason: In an ionic solid, Frenkel defect arises due to dislocation of cation from its lattice site to interstitial site maintaining overall electrical neutrality.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

NUMERICAL PROBLEMS [Pages 50 - 51]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State NUMERICAL PROBLEMS [Pages 50 - 51]

1.Page 50

A unit cell of sodium chloride has four formula units. The edge length of the unit cell is 0.564 nm. What is the density of sodium chloride?

2.Page 50

Chromium metal crystallises with a body-centred cubic lattice. The length of the unit cell edge is found to be 287 pm. Calculate the atomic radius. What would be the density of chromium in g cm−3?

3.Page 51

Iron occurs as body-centred as well as face-centred cubic systems. If the effective radius of an atom of iron is 124 pm, calculate the density of iron in both the structures.

4.Page 51

Molybdenum forms body-centred cubic crystals and at 20°C the density is 10.3 g/cm3. Calculate the distance between the centres of the nearest molybdenum atoms.

5.Page 51

In the cubic crystal of CsCl (d = 3.97 g/cm3), the eight corners are occupied by Cl with a Cs+ at the centre and vice-versa. Calculate the distance between the neighbouring Cs+ and Cl ions. What is the radius ratio of the two ions? (At. masses: Cs = 132.91, Cl = 35.45)

6.Page 51

A compound formed by atoms A and B crystallises in the cubic structures. The atoms A occupy the corners while atoms Y the face-centres of the cube. Find the formula of the compound. If the side length is 5 Å, calculate the density of the solid. (Atomic masses: A = 60, B = 90.)

7.Page 51

A solid AB crystallises as a body-centred cubic lattice with the unit cell edge length equal to 384 pm. Calculate

  1. the distance between the oppositely charged ions in the lattice, and
  2. the radius of A+ ion if that of B is 180 pm.
8.Page 51

The density of crystalline sodium chloride is 2.165 g cm−3. What is the edge length of the cubic unit cell? What would be the dimension of a cube containing one mole of NaCl?

'NCERT TEXT-BOOK' Exercises [Pages 52 - 55]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State 'NCERT TEXT-BOOK' Exercises [Pages 52 - 55]

1.1 (i)Page 52

Define the term ‘amorphous’.

1.1 (ii)Page 52

Give a few examples of amorphous solids.

1.2Page 52

What makes a glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?

1.3Page 52

Classify each of the following solids as ionic, metallic, molecular, network (covalent) or amorphous.

  1. Tetra phosphorus decoxide (P4O10)
  2. Ammonium phosphate (NH4)3PO4
  3. SiC
  4. I2
  5. P4
  6. Plastic
  7. Graphite
  8. Brass
  9. Rb
  10. LiBr
  11. Si
1.4 (i)Page 53

What is meant by the term ‘coordination number’?

1.4 (ii) (a)Page 53

What is the coordination number of atoms in a cubic close-packed structure?

1.4 (ii) (b)Page 53

What is the coordination number of atoms in a bcc structure?

1.5Page 53

How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.

1.6Page 53

‘Stability of a crystal is reflected in the magnitude of its melting points.’ Comment. Collect melting points of solid water, ethyl alcohol, diethyl ether and methane from a data book. What can you say about the intermolecular forces between these molecules?

1.7 (i)Page 53

Distinguish between hexagonal close packing and cubic close packing.

1.7 (ii)Page 53

How will you distinguish between the following pair of terms?

Crystal lattice and unit cell

1.7 (iii)Page 53

How will you distinguish between the following pair of terms?

Tetrahedral and octahedral voids

1.8 (i)Page 53

How many lattice points are there in one unit cell of the following lattice?

Face-centred cubic

1.8 (ii)Page 53

How many lattice points are there in one unit cell of the following lattice?

Face-centred tetragonal

1.8 (iii)Page 53

How many lattice points are there in one unit cell of the following lattice?

Body-centred

1.9 (i) (a)Page 53

Explain the basis of similarities between metallic and ionic crystals.

1.9 (i) (b)Page 53

Explain the basis of differences between metallic and ionic crystals.

1.9 (ii)Page 53

Explain ionic solids are hard and brittle.

1.10 (i)Page 53

What is the percentage of the occupied space in a simple cubic unit cell?

1.10 (ii)Page 53

Calculate the percentage efficiency of packing in the case of a body-centred cubic crystal.

1.10 (iii)Page 53

Calculate the percentage of the occupied space in a face-centred cubic unit cell.

1.11Page 53

Silver crystallises in fcc lattice. If edge length of the cell is 4.07 × 10−8 cm and density is 10.5 g cm−3, calculate the atomic mass of silver.

1.12Page 53

A cubic solid is made of two elements P and Q. Atoms of Q are at the corners of the cube and P at the body-centre. What is the formula of the compound? What are the coordination numbers of P and Q?

1.13Page 54

Niobium crystallises in body-centred cubic structure. If density is 8.55 g cm−3, calculate atomic radius of niobium using its atomic mass 93 u.

1.14Page 54

If the radius of the octahedral void is r and the radius of the atoms in close packing is R, derive the relation between r and R.

1.15Page 54

Copper crystallises into a fcc lattice with edge length 3.61 × 10−8 cm. Show that the calculated density is in agreement with its measured value of 8.92 g cm−3.

1.16Page 54

Analysis shows that nickel oxide has the formula Ni0.98O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?

1.17 (i)Page 54

What is a semiconductor?

1.17 (ii)Page 54

Describe the two main types of semiconductors and contrast their conduction mechanism.

1.18Page 54

Non-stoichiometric cuprous oxide, Cu2O can be prepared in laboratory. In this oxide, copper to oxygen ratio is slightly less than 2 : 1. Can you account for the fact that this substance is a p-type semiconductor?

1.19Page 54

Ferric oxide crystallises in a hexagonal close-packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.

1.20Page 54

Classify each of the following as being either a p-type or a n-type semiconductor:

  1. Ge doped with In 
  2. B doped with Si
1.21Page 54

Gold (atomic radius = 0.144 nm) crystallises in a face-centred unit cell. What is the length of a side of the cell?

1.22 (i)Page 54

In terms of band theory, what is the difference between a conductor and an insulator?

1.22 (ii)Page 54

In terms of band theory, what is the difference between a conductor and a semiconductor?

1.23 (i)Page 55

Explain the Schottky defect.

1.23 (ii)Page 55

Explain the following term with suitable examples: 

Frenkel defect

1.23 (iii)Page 55

Explain the following term with a suitable example:

Interstitials

1.23 (iv)Page 55

Explain the following term with a suitable example:

F-centres

1.24Page 55

Aluminium crystallises in a cubic close-packed structure. Its metallic radius is 125 pm.

  1. What is the length of the side of the unit cell?
  2. How many unit cells are there in 1.00 cm3 of aluminium?
1.25Page 55

If NaCl is doped with 10−3 mol % of SrCl2, what is the concentration of cation vacancies?

1.26 (i)Page 55

Explain the following with suitable examples:

Ferromagnetism

1.26 (ii)Page 55

Explain the following with suitable examples:

Paramagnetism

1.26 (iii)Page 55

Explain the following with suitable examples:

Ferrimagnetism

1.26 (iv)Page 55

Explain the following with suitable examples: 

Antiferromagnetism

1.26 (v) (a)Page 55

Explain the following with suitable examples:

12-16 group compounds

1.26 (v) (b)Page 55

Explain the following with suitable examples:

13-15 group compounds

QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 55 - 57]

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC 1 Solid State QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 55 - 57]

1. (i)Page 55

Distinguish between crystalline solid and amorphous solid.

1. (ii) (a)Page 55

State the element present at the lattice sites in diamond.

1. (ii) (b)Page 55

The number of nearest neighbours for each atom in diamond.

1. (ii) (c)Page 55

The type of unit cell of diamond.

2. (i)Page 55

For sodium chloride crystal, state the type of unit cell.

2. (ii)Page 55

For sodium chloride crystal, state the nature of the forces holding the particles together.

2. (iii)Page 55

For sodium chloride crystal, state the number of nearest neighbours around each sodium ion.

2. (iv)Page 55

For sodium chloride crystal, state the geometry of the sodium ions which are arranged around a chloride ion.

3. (i)Page 55

Diamond is hard and a bad conductor of electricity, while graphite is soft and a good conductor of electricity. Explain.

3. (ii)Page 55

What is the state of hybridisation of carbon in diamond?

3. (iii)Page 55

What is the state of hybridisation of carbon in graphite?

4.Page 55

Describe the unit cell of sodium chloride with a neat diagram stating:

  1. Type of bonding
  2. Type of unit cell
  3. Number of nearest neighbours around sodium and chloride.

Fill in the blanks.

5.Page 55

Crystals of ______ and ______ have face-centred cubic lattices.

6. (i)Page 55

Give any three characteristics of ionic crystals.

6. (ii)Page 55

State the main characteristics of a network type of crystal citing a suitable example.

7. (a)Page 55

Name the crystal structure of the copper metal.

7. (b)Page 55

What is the coordination number of copper in its crystalline state?

8. (a)Page 55

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

8. (b)Page 55

What is the coordination number of sodium and chloride ions in sodium chloride crystals?

9. (i)Page 55

State the element present at the lattice sites in diamond.

9. (ii)Page 55

The number of nearest neighbours for each atom in diamond.

9. (iii)Page 55

The type of unit cell of diamond.

9. (iv)Page 55

What is the state of hybridisation of carbon in diamond?

10. (i)Page 55

What is the number of atoms in a body-centred cubic (bcc) unit cell of an element?

10. (ii)Page 55

Give reasons: 

Graphite is used as a lubricant.

11. (a) (i)Page 55

Define piezoelectricity.

11. (a) (ii)Page 55

Give one use of piezoelectric crystals.

11. (b) (i)Page 55

What is a semiconductor?

11. (b) (ii)Page 55

What is the effect of increasing temperature on the conductivity of a semiconductor?

11. (c)Page 55

A compound AB has a simple cubic structure and has a molecular mass of 99. Its density is 3.4 g cm−3. What will be the edge length of the unit cell?

12. (a)Page 56

What are F-centres?

12. (b)Page 56

Why are crystals having F-centres paramagnetic?

13. (a)Page 56

What is the state of hybridisation of carbon in diamond?

13. (b)Page 56

For a crystal of diamond, state the coordination number of each carbon atom.

13. (c)Page 56

State the element present at the lattice sites in diamond.

13. (d)Page 56

For a crystal of diamond, state the number of carbon atoms present per unit cell.

14.Page 56

An ionic compound is made up of A cations and B anions. If A cations are present at the alternate corners and B anion is present on the body of the diagonal, what is the formula of the ionic compound?

15.Page 56

Define the Frenkel defect in a solid crystal.

16.Page 56

Explain giving reasons, why ionic solids conduct electricity in the molten state, but not in solid-state?

17.Page 56

In a crystal of diamond:

  1. How many carbon atoms are present per unit cell?
  2. What type of lattice does diamond crystallise in?
  3. How many carbon atoms surround each carbon atom?
  4. How are they arranged?
18.Page 56

Name the crystal structure of the copper metal.

19.Page 56

Chromium metal crystallises with a body centred cubic lattice. The edge length of the unit cell is found to be 287 pm. Calculate the atomic radius. What would be the density of chromium in g/cm3? (atomic mass of Cr = 52.99)

20.Page 56

Why does sodium chloride on heating with sodium vapours acquire yellow colour?

21. (a)Page 56

For a crystal of sodium chloride, state the type of lattice in which it crystallises.

21. (b)Page 56

What is the coordination number of sodium and chloride ions in sodium chloride crystals?

21. (c)Page 56

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

21. (d)Page 56

For a crystal of sodium chloride, state the structural arrangement of the sodium chloride crystal.

22.Page 56

The edge length of the unit cell of a body-centred cubic (bcc) crystal is 352 pm. Calculate the radius of the atom.

23.Page 56

Graphite is anisotropic with respect to the conduction of electric current. Explain.

24. (a) (i)Page 56

How many lattice points are there in one unit cell of the following lattice?

Body-centred

24. (a) (ii)Page 56

How many atoms constitute one unit cell of a face-centered cubic crystal?

24. (b)Page 56

A compound AB has a simple cubic structure and has a molecular mass of 99. Its density is 3.4 g cm−3. What will be the edge length of the unit cell?

25.Page 56

In a face-centred cubic lattice, atom (A) occupies the corner positions and atom (B) occupies the face centre positions. If one atom of (B) is missing from one of the face-centred points, the formula of the compound is ______.

  • A2B5

  • A2B3

  • AB2

  • A2B

26.Page 56

How many sodium ions and chloride ions are present in a unit cell of sodium chloride crystal?

27.Page 56

Frenkel defect does not change the density of the ionic crystal whereas Schottky defect lowers the density of ionic crystal. Give a reason.

28.Page 56

Lead sulphide has a face-centred cubic crystal structure. If the edge length of the unit cell of lead sulphide is 495 pm, calculate the density of the crystal. 
(Atomic weight of Pb = 207, S = 32)

29.Page 56

Examine the defective crystal given below and answer the question that follows: 

A+ B A+ B A+
B   B A+ B
A+ B A+   A+
B A+ B A+ B

State if the above defect is stoichiometric or non-stoichiometric. How does this defect affect the density of the crystal? Also, write the term used for this type of defect.

30.Page 56

An element occurs in a body-centred cubic structure. Its density is 8.0 g/cm3. If the cell edge is 250 pm, calculate the atomic mass of an atom of this element. (NA = 6.023 × 1023)

31.Page 56

The packing efficiency of simple cubic structure, body centred cubic structure and face-centred cubic structure respectively is ______.

  • 52.4%, 74%, 68%

  • 74%, 68%, 52.4%

  • 52.4%, 68%, 74%

  • 68%, 74%, 52.4%

32.Page 56

An element has atomic mass 93 g mol−1 and density 11.5 g cm–3. If the edge length of its unit cell is 300 pm, identify the type of unit cell. (NA = 6.023 × 1023 mol−1)

33.Page 56

Calculate the radius of copper atom. The atomic weight of copper is 63.55 g mol−1. It crystallises in face-centred cubic lattice and has density of 8.93 g cm−3 at 298 K.

(NA = 6.023 × 1023 mol−1)

34.Page 56

An alloy of gold (Au) and cadmium (Cd) crystallises with a cubic structure in which gold atoms occupy the corners and cadmium atoms fit into the face centres. What is the formula of this alloy?

Select and write the correct alternative from the choices given below

35. (i)Page 56

How many chloride ions are surrounding sodium ions in sodium chloride crystal?

  • 4

  • 8

  • 6

  • 12

  • 3

35. (ii)Page 57

The ratio of number of atoms present in a simple cubic, body-centred cubic and face-centred cubic structure are, respectively ______.

  • 8 : 1 : 6

  • 1 : 2 : 4

  • 4 : 2 : 1

  • 4 : 2 : 3

35. (iii)Page 57

A solid has a structure in which ‘Y’ atoms are located at the corners of a cubic lattice, ‘O’ atoms at the centre of edges and ‘K’ atoms at the centre of the cube. What is the formula of the compound?

  • KYO2

  • KYO3

  • K2YO3

  • K4YO3

35. (iv)Page 57

The appearance of colour in solid alkali metal halides is generally due to ______.

  • Schottky defect

  • Frenkel defect

  • Interstitial positions

  • F-centre

35. (v) 1.Page 57

An element ‘X’ having atomic mass 60 has density 6.23 g cm−3. The edge length of its unit cubic cell is 400 pm. (NA = 6.02 × 1023 mol−1).

What is the type of unit cell known as?

  • Body centred cubic

  • Face centred cubic

  • Simple cubic

  • Side centred cubic

35. (v) 2.Page 57

An element ‘X’ having atomic mass 60 has density 6.23 g cm−3. The edge length of its unit cubic cell is 400 pm. (NA = 6.02 × 1023 mol−1).

What is the radius of an atom of this element?

  • 210.5 pm

  • 344.4 pm

  • 141.4 pm

  • 115.3 pm

35. (vi) 1.Page 57

The radius of silver atom is 143.5 pm and it crystallises in face centred cubic arrangement. (Atomic mass of Ag = 107.47, NA = 6.023 × 1023)

What is the edge length of the unit cell?

  • 405.8 pm

  • 40.6 pm

  • 331.4 pm

  • 287 pm

35. (vi) 2.Page 57

The radius of silver atom is 143.5 pm and it crystallises in face centred cubic arrangement. (Atomic mass of Ag = 107.47, NA = 6.023 × 1023)

What is the density of silver metal?

  • 5.36 g/cm3

  • 8.60 g/cm3

  • 10.72 g/cm3

  • 7.07 g/cm3

35. (vii) 1.Page 57

Niobium crystallises in body centred cubic structure. Its density is 8.55 g cm−3 and its atomic mass is 93 g mol−1. (NA = 6.023 × 1023)

What is the edge length of niobium?

  • 314.50 pm

  • 330.56 pm

  • 340.43 pm

  • 346.30 pm

35. (vii) 2.Page 57

Niobium crystallises in body centred cubic structure. Its density is 8.55 g cm−3 and its atomic mass is 93 g mol−1. (NA = 6.023 × 1023)

What is the atomic radius of niobium?

  • 136 pm

  • 140 pm

  • 143 pm

  • 149 pm

Solutions for 1: Solid State

REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSINTEGER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNUMERICAL PROBLEMS'NCERT TEXT-BOOK' ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State - Shaalaa.com

Nootan solutions for Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 - Solid State

Shaalaa.com has the CISCE Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE solutions in a manner that help students grasp basic concepts better and faster. The detailed, step-by-step solutions will help you understand the concepts better and clarify any confusion. Nootan solutions for Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE 1 (Solid State) include all questions with answers and detailed explanations. This will clear students' doubts about questions and improve their application skills while preparing for board exams.

Further, we at Shaalaa.com provide such solutions so students can prepare for written exams. Nootan textbook solutions can be a core help for self-study and provide excellent self-help guidance for students.

Concepts covered in Chemistry Part 1 and 2 [English] Class 12 ISC chapter 1 Solid State are Introduction to Solid State, Classification of Solids, Classification of Crystalline Solids, Space Lattice, Definition of Unit Cell, Different Types of Cubic Systems, Number of Particles Per Unit Cell in Different Cubic Systems, Calculation of the Space Occupied (Packing Fraction) in the Unit Cells of Different Types of Cubic Systems, Calculation of Density of a Crystal, Close-packed Structures, Packing of Constituent Particles in Crystals, Voids in Close-Packed Structures, Dimensions of Voids, Location of Tetrahedral Voids, Location of Octahedral Voids, Radius Ratio Rules, Number of Voids Filled and the Formula of the Compound, Types of Crystalline Solids: Molecular Solids, Types of Crystalline Solids: Ionic Solids, Types of Crystalline Solids: Covalent Solids {Atomic or Network Solids), Types of Crystalline Solids: Metallic Solids, Imperfections (Defects) in Solids, Imperfections (Defects) in Solids: Electronic Imperfections, Imperfections (Defects) in Solids: Atomic Imperfections, Imperfections (Defects) Caused by Impurities, Properties of Solids: Electrical Properties, Properties of Solids: Magnetic Properties, Properties of Solids: Dielectric Properties, Amorphous Solids.

Using Nootan Chemistry Part 1 and 2 [English] Class 12 ISC solutions Solid State exercise by students is an easy way to prepare for the exams, as they involve solutions arranged chapter-wise and also page-wise. The questions involved in Nootan Solutions are essential questions that can be asked in the final exam. Maximum CISCE Chemistry Part 1 and 2 [English] Class 12 ISC students prefer Nootan Textbook Solutions to score more in exams.

Get the free view of Chapter 1, Solid State Chemistry Part 1 and 2 [English] Class 12 ISC additional questions for Mathematics Chemistry Part 1 and 2 [English] Class 12 ISC CISCE, and you can use Shaalaa.com to keep it handy for your exam preparation.

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