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Question
Explain the following term with a suitable example:
Interstitials
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Solution
- When certain constituent particles, such as atoms or molecules, occupy interstitial positions, we refer to a crystal as having an interstitial defect.
- As shown in the figure, the presence of interstitial particles increases the substance’s density.
- Non-ionic solids exhibit interstitial flaws and vacancies.
- Ionic solids do not have simple vacancies or interstitial flaws as previously described because they must always maintain electrical neutrality.
- Rather, they display additional flaws referred to as Frenkel and Schottky faults.
- An example of interstitials is Carbon in Iron (Steel); Carbon atoms occupy interstitial sites in the iron lattice, making the metal stronger and harder.
RELATED QUESTIONS
Explain the following term with suitable examples:
Frenkel defect
Give reasons : In stoichiometric defects, NaCl exhibits Schottky defect and not Frenkel defect.
What type of defect is shown by NaCl in
stoichiometric defects, and
non-stoichiometric defects?
Ionic solids containing large differences in sizes of ions show ____________.
Defects in solids can be studied using
Frenkel defects are not found in alkali metal halides because ____________.
Assertion: No compound has both Schottky and Frenkel defects.
Reason: Both defects change the density of the solid.
Assertion: Due to Frenkel defect, there is no effect on the density of the crystalline solid.
Reason: In Frenkel defect, no cation or anion leaves the crystal.
Alkali halids do not show Frenkel defect because ____________.
Which of the following crystals does not exhibit Frenkel defect?
Silver halides generally show:
What is the effect of Frenkel defect on the density of ionic solids?
Which of the following statements are not true?
(i) Vacancy defect results in a decrease in the density of the substance.
(ii) Interstitial defects results in an increase in the density of the substance.
(iii) Impurity defect has no effect on the density of the substance.
(iv) Frankel defect results in an increase in the density of the substance.
Match the defects given in Column I with the statements in given Column II.
| Column I | Column II |
| (i) Simple vacancy defect | (a) shown by non-ionic solids and increases density of the solid. |
| (ii) Simple interstitial defect | (b) shown by ionic solids and decreases density of the solid. |
| (iii) Frenkel defect | (c) shown by non ionic solids and density of the solid decreases. |
| (iv) Schottky defect | (d) shown by ionic solids and density of the solid remains the same. |
Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion: In any ionic solid (MX) with Schottky defects, the number of positive and negative ions are same.
Reason: Equal number of cation and anion vacancies are present.
If NaCl is doped with 10–4 mole percent of SrCl2 the concentration of cation vacancies will be
Given below are two statements:
Statements I: Frenkel defects are vacancy as well as interstitial defects.
Statements II: Frenkel defect leads of colour in ionic solids due to the presence of F-centers.
Choose the most appropriate answer for the statements from the options given below:
The incorrect statement about the imperfections in solids is ______.
