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What factors are responsible for the conduction of current by a semiconductor? - Chemistry (Theory)

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Question

What factors are responsible for the conduction of current by a semiconductor?

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Solution

  1. Temperature: Increasing temperature provides energy to electrons, allowing them to jump from the valence band to the conduction band, increasing conductivity.
  2. Doping: Adding impurities (dopants) like phosphorus (n-type) or boron (p-type) introduces free charge carriers (electrons or holes), significantly boosting conductivity.
  3. Electric Field: Applying an external electric field accelerates free charge carriers, resulting in an electric current.
  4. Band Gap Energy: Semiconductors have a small band gap (typically 0.7 to 3 eV), which makes it easier for electrons to move to the conduction band.
  5. Photon Absorption (Photoexcitation): Exposure to light or other forms of electromagnetic radiation can provide energy for electrons to jump into the conduction band, creating current (photoelectric effect).
  6. Crystal Purity and Lattice Structure: The arrangement and purity of the crystal lattice affect the ease with which electrons can move, influencing conductivity.
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