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Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी chapter 6 - General Principles and Processes of Isolation of Elements [Latest edition]

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Chapters

Physical Chemistry

    1: Solid State

    2: Solutions

    3: Electrochemistry

    4: Chemical Kinetics

    5: Surface Chemistry

Inorganic Chemistry

▶ 6: General Principles and Processes of Isolation of Elements

    7: p-Block Elements

    8: d-and ƒ-Block Elements

    9: Coordination Compounds

Organic Chemistry

    10: Haloalkanes and Haloarenes

   Chapter 11: Alcohols, Phenols and Ethers

   Chapter 12: Aldehydes, Ketones and Carboxylic Acids

   Chapter 13: Organic Compounds containing Nitrogen

   Chapter 14: Biomolecules

    15: Polymers

   Chapter 16: Chemistry in Everyday Life

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी chapter 6 - General Principles and Processes of Isolation of Elements - Shaalaa.com
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Solutions for Chapter 6: General Principles and Processes of Isolation of Elements

Below listed, you can find solutions for Chapter 6 of CISCE Nootan for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी.


REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNCERT TEXT-BOOK ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
REVIEW EXERCISES [Pages 333 - 354]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements REVIEW EXERCISES [Pages 333 - 354]

6.1 i.Page 333

How do elements occur in nature?

6.1 ii.Page 333

What is the difference between minerals and ores?

6.2Page 333

How can the ores be classified? Give at least one example of each type of ore.

6.3 (i)Page 333

Which metal is extracted from bauxite ore?

6.3 (ii)Page 333

Name the elements which are extracted from the following ore:

Zinc blende

6.3 (iii)Page 333

Name the metal which is extracted from haematite ore.

6.3 (iv)Page 333

Name the elements which are extracted from the following ore.

Malachite

6.4 (i)Page 333

How does the following element occur in living systems?

Iron

6.4 (ii)Page 333

How does the following elements occur in living systems?

Iodine

6.4 (iii)Page 333

How does the following element occur in living system?

Zinc

6.4 (iv)Page 333

How does the following element occur in living system?

Carbon

6.5Page 333

Name some important metals whose ores are abundant in India.

6.6Page 350

To which groups of the periodic table do zinc and silver belong?

6.7Page 350

Name the important ores of zinc.

6.8Page 350

Describe vertical retort process used for the extraction of zinc.

6.9Page 350

How is crude zinc purified?

6.10Page 350

Mention the important uses of zinc and its alloys.

6.11 i.Page 350

In what forms does silver occur in nature?

6.11 ii.Page 350

Give the names and formulae of important ores of silver.

6.12 i.Page 350

Describe the principle involved in the cyanide process used for the extraction of silver.

6.12 ii.Page 350

Describe the principle involved in the Parke’s process used for the extraction of silver.

6.13 i.Page 350

What is cupellation process?

6. 13 ii.Page 350

For what cupellation process is used?

6. 13 iii.Page 350

Describe the process of cupellation process.

6.14 (i)Page 350

What happens when silver is treated with conc. HNO3?

6.14 (ii)Page 350

What happens when silver is treated with conc. H2SO4?

6.14 (iii)Page 350

What happens when silver is treated with Aq. KCN solution?

6.14 (iv)Page 350

What happens when silver is treated with sulphur?

6.15 i.Page 350

How is the purity of silver expressed?

6.15 ii.Page 350

What is meantby ‘930 fine silver?

6.16 i.Page 350

Give the composition and uses of the following alloy:

Dental amalgam

6.16 ii.Page 350

Give the composition and uses of the following alloy:

Coinage alloy

6.16 iii.Page 350

Give the composition and uses of the following alloy:

Palladium silver alloy

6.17Page 354

Explain the principle of coupling in metallurgical operations.

6.18Page 354

What is Ellingham diagram and how is it useful in metallurgical processes?

6.19 i.Page 354

What is pyrometallurgy?

6.19 ii.Page 354

Give an example of pyrometallurgy.

6.20Page 354

List the reactions that take place in a blast furnace in the metallurgy of iron.

6.21Page 354

Write a short note on electrochemical principles of metallurgy.

6.22 i.Page 354

What is the chief ore of iron?

6.22 ii.Page 354

Write chemical reactions taking place in the extraction of iron from its ore.

6.23 (a)Page 354

Name the principal ore of aluminium.

6.23 (b)Page 354

Describe the leaching of aluminium ore.

6.24Page 354

What do you understand by the beneficiation of the ore?

6.25Page 354

What is levigation and how is it carried out?

6.26Page 354

What type of ores are concentrated by magnetic separation techinique?

6.27Page 354

What is the role of collectors in froth floatation process?

6.28Page 354

What is the difference between calcination and roasting?

6.29 i.Page 354

What flux would you use to remove the following impurity?

SiO2

6.29 ii.Page 354

What flux would you use to remove the following impurity?

P2O5

6.29 iii.Page 354

What flux would you use to remove the following impurity?

FeO

6.29 iv.Page 354

What flux would you use to remove the following impurity?

CaO

6.30Page 354

Why is molten metal stirred with the logs of green wood in poling?

6.31Page 354

Which state in India is the richest in minerals?

VERY SHORT ANSWER TYPE QUESTIONS [Pages 355 - 356]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements VERY SHORT ANSWER TYPE QUESTIONS [Pages 355 - 356]

1.Page 355

What are minerals?

2.Page 355

What is the difference between minerals and ores?

3.Page 355

What do you understand by the term ‘metallurgy’?

4.Page 355

What process is used for the concentration of haematite ore?

5.Page 355

What is the role of ethyl xanthate in froth floatation process?

6. i.Page 355

What do you understand by the terms flux?

6. ii.Page 355

What do you understand by the term slag?

7.Page 355

Why are the logs of green wood used in poling for the refining of certain metals?

8.Page 355

Which part of the country is the richest in minerals?

9. (a)Page 355

Which metal is extracted from bauxite ore?

9. (b)Page 355

Name the metal which form following ore:

Galena

9. (c)Page 355

Name the metal which form following ore:

Gypsum

9. (d)Page 355

Which metal can be extracted from the following ore?

Calamine

10.Page 355

What type of ores are usually calcined?

11.Page 355

Name the furnace usually used for the roasting of ores.

12.Page 355

Define smelting.

13.Page 355

Which substance is usually used as flux when the ore contains the impurities of silica?

14.Page 355

Name the process involving the reduction of the roasted ore with aluminium.

15.Page 356

Which metallurgical process is involved in the metallurgy of copper?

16.Page 356

Which process is used to obtain silicon of very high degree of purity?

17.Page 356

Which is a better reducing agent at 710°C, C or CO?

18.Page 356

Indicate the temperature at which carbon can be used as a reducing agent for FeO.

19.Page 356

Is it true that under certain conditions Mg can reduce SiO2 and Si can reduce MgO?

20.Page 356

Name the most important ore of iron.

SHORT ANSWER TYPE QUESTIONS [Page 356]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements SHORT ANSWER TYPE QUESTIONS [Page 356]

1. i.Page 356

How do elements occur in nature?

1. ii.Page 356

How can the ores be classified? Give at least one example of each type of ore.

2. i.Page 356

What is froth floatation process?

2. ii.Page 356

On what principle froth floatation process is based?

3.Page 356

Distinguish between calcination and roasting. Illustrate your answer with examples.

4. i.Page 356

What is the role of a flux in carbon reduction process?

4. ii.Page 356

How is a particular flux chosen for a particular metallurgical process?

5. i.Page 356

What is hydrometallurgy?

5. ii.Page 356

How hydrometallurgy is useful in the extraction of silver and gold?

6. (i)Page 356

Write short notes on levigation.

6. (ii)Page 356

Write short notes on aluminothermic process.

6. (iii)Page 356

Write short notes on cupellation.

7.Page 356

Explain the difference between leaching and levigation.

8.Page 356

Name the three elements which occur in nature both in the free state as well as in the combined state.

9.Page 356

Comment on the statement that - “All ores are minerals but all minerals are not ores”.

10.Page 356

Give a brief account of the gravity separation process used for the concentration of ores.

11.Page 356

What type of ores are concentrated by magnetic separation techinique?

12. i.Page 356

What is the role of activators in the froth floatation process?

12. ii.Page 356

What is the role of depressant in froth floatation process?

13.Page 356

Name the process used for the concentration of bauxite ore. Give a brief account of the process.

14. i.Page 356

Why is the concentrated ore usually converted into its oxidised form?

14. ii.Page 356

What are the processes used for the purpose of conversion of concentrated ore into its oxidised form?

15. i.Page 356

Define roasting.

15. ii.Page 356

What changes do take place when a concentrated ore is subjected to roasting?

16. i.Page 356

What do you understand by smelting?

16. ii.Page 356

Describe the role of flux in smelting process.

17.Page 356

Describe briefly the Goldschmidt aluminothermic process.

18.Page 356

What is electrolytic reduction and for what type of metals is it used? Give an example.

19.Page 356

What type of metals can be purified by liquation technique? Describe the technique.

20. i.Page 356

What is poling?

20. ii.Page 356

What is the role of logs of green wood in poling process?

21.Page 356

Describe zone refining method used to obtain metals of high degree purity.

22.Page 356

Giving a suitable example, describe Van Arkel method for the purification of metals.

23.Page 356

Copper and silver are below hydrogen in electrochemical series and yet they are found in the combined state as sulphides in nature. Comment.

24. (a)Page 356

Name the main form of occurrence of the following in the earth’s crust:

Aluminium

24. (b)Page 356

Name the main form of occurrence of the following in the earth’s crust:

Iron

24. (c)Page 356

Name the main form of occurrence of the following in the earth’s crust:

Zinc

24. (d)Page 356

Name the main form of occurrence of the following in the earth’s crust:

Copper

25.Page 356

The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.

26. (a)Page 356

Predict the mode of occurrence of the following type of metal:

Highly reactive (e.g., Na)

26. (b)Page 356

Predict the mode of occurrence of the following type of metal:

Moderately reactive (e.g., Fe)

26. (c)Page 356

Predict the mode of occurrence of the following type of metal:

Noble metal (e.g., Au)

27. i.Page 356

Which type of ores can be concentrated by the froth floatation method? Give two examples for such ores.

27. ii.Page 356

What is meant by a depressant?

28.Page 356

What is the thermodynamic consideration in the choice of a reducing agent in metallurgy?

29.Page 356

Carbon monoxide is a more effective reducing agent than carbon below 983 K but above this temperature the reverse is true. Explain.

30.Page 356

Which metals are generally extracted by the electrolytic process? What positions do these metals generally occupy in the periodic table?

31. (i)Page 356

Name the metal which is associated with the following term in the extraction from its ores.

Bessemer converter

31. (ii)Page 356

Name the metal which is associated with the following term in the extraction from its ores.

Blast furnace

31. (iii)Page 356

Name the metal which is associated with the following term in the extraction from its ores.

Aluminothermic process

31. (iv)Page 356

Name the metal which is associated with the following term in the extraction from its ores.

Magnetic separation

32. (i)Page 356

Which method would you suggest for the separation of the metal in the following mixture?

Zinc and iron

Give reasons for your choice.

32. (ii)Page 356

Which method would you suggest for the separation of the metal in the following mixture?

Copper and magnesium

Give reasons for your choice.

32. (iii)Page 356

Which method would you suggest for the separation of the metal in the following mixture?

Rare earths

Give reasons for your choice.

LONG ANSWER TYPE QUESTIONS [Page 357]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements LONG ANSWER TYPE QUESTIONS [Page 357]

1. i.Page 357

How do elements occur in nature?

1. ii.Page 357

How can the ores be classified? Give at least one example of each type of ore.

1. iii.Page 357

Give an account of some common ores and their occurrence in India.

2.Page 357

Discuss the various processes used for the concentration of different types of ores.

3.Page 357

Discuss various techniques used for the production of a metal from the concentrated ore.

4.Page 357

Describe various processes used for the refining of a crude metal.

5. i.Page 357

On what principle froth floatation process is based?

5. ii.Page 357

What is the role of a stabiliser in froth floatation process?

5. iii.Page 357

What is the role of depressant in froth floatation process?

5. iv.Page 357

Give one example of stabiliser in froth floatation process.

5. v.Page 357

Give one example of depressant in froth floatation process.

6. (a)Page 357

Explain the principle of electrolytic refining with an example.

6. (b)Page 357

What is the principle behind the zone refining of metals?

6. (c)Page 357

Describe the principle of the following process in detail.

Chromatographic refining

7.Page 357

You are provided with samples of some impure metals such as zinc, copper and germanium. Describe the methods you recommend for the purification of each of these metals.

8.Page 357

Describe the factors which are necessary to be considered before deciding on the method of extraction of a metal from its ore.

9.Page 357

Giving suitable examples, explain how the reactivity of a metal is related to its mode of occurrence in nature.

10.Page 357

How do non-metals occur in nature and how are they extracted/isolated from their natural sources?

11. i.Page 357

Name the important ores of zinc. What methods are employed for the concentration of the ores?

11. ii.Page 357

Name the important ores of iron. What methods are employed for the concentration of the ores?

11. iiiPage 357

Name the important ores of aluminium. What methods are employed for the concentration of the ores?

12. (i)Page 357

Write short notes on the following:

Roasting

12. (ii)Page 357

Write short note on the following:

Calcination

12. (iii)Page 357

Write short note on the following:

Smelting

13.Page 357

What are thermodynamic principles of metallurgy? Explain with a suitable example.

14.Page 357

What is Ellingham diagram and how is it useful in metallurgical processes?

15. i.Page 357

How is iron extracted from its ores?

15. ii.Page 357

State two important uses of following metals: 

Uses of iron   

16. i.Page 357

How is copper extracted from its ores?

16. ii.Page 357

State two important uses of following metal. 

Uses of copper  

17. i.Page 357

How is zinc extracted from zinc oxide?

17. ii.Page 357

State two important uses of following metal: 

Uses of zinc  

18.Page 357

What are electrochemical principles of metallurgy? Explain with a suitable example.

19. i.Page 357

How is aluminium extracted from its ores?

19. ii.Page 357

State two important uses of following metal:

Uses of aluminium

20.Page 357

How are non-metals extracted by oxidation? Give an example.

OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 357 - 360]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements OBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONS [Pages 357 - 360]

Choose the correct option in the following questions.

1.Page 357

A naturally occurring substance from which a metal can be profitably extracted is known as ______.

  • mineral

  • gangue

  • ore

  • flux

2.Page 357

The most abundant element in earth’s crust is ______.

  • hydrogen

  • oxygen

  • silicon

  • carbon

3.Page 357

Which of the following is not an ore?

  • Bauxite

  • Malachite

  • Zinc blende

  • Pig iron

4.Page 357

In the froth floatation process for the purification of ores, the ore particles float because ______.

  • they are light.

  • their surface is hydrophobic, i.e., not easily wetted by water.

  • they bear electrostatic charge.

  • they are insoluble.

5.Page 357

Which of the following processes involve smelting?

  • \[\ce{ZnCO3 -> ZnO + CO2}\]

  • \[\ce{Fe2O3 + 3C -> 2Fe + 3CO}\]

  • \[\ce{2PbS + 3O2 -> 2PbO + 2SO2}\]

  • \[\ce{Al2O3 * 2H2O -> Al2O3 + 2H2O}\]

6.Page 358

A substance which reacts with gangue to form fusible material is called ______.

  • flux

  • catalyst

  • ore

  • slag

7.Page 358

Which of the following metals is obtained by leaching its ore with dilute cyanide solution?

  • Silver

  • Titanium

  • Vanadium

  • Zinc

8.Page 358

Which method of purification is represented by the following equation?

\[\ce{Ti + 2I2 ->[773 K] Til4 ->[1675 K] Ti + 2I2}\]

  • Cupellation

  • Poling

  • Van Arkel

  • Zone refining

9.Page 358

Bauxite, an ore of aluminium, is ______.

  • a sulphide ore

  • carbonate ore

  • an oxide ore

  • a halide ore

10.Page 358

Which of the following statements is (are) correct?

  • Levigation is generally used for the extraction of oxide ores.

  • Haematite is usually concentrated by froth floatation process.

  • Ethyl xanthate used in froth floatation process acts as a frothing agent.

  • Leaching is a chemical method.

11.Page 358

Which of the following process does not involve calcination?

  • \[\ce{CaCO3 -> CaO + CO2}\]

  • \[\ce{2FeS + 3O2 -> Fe2O3 + 2SO2}\]

  • \[\ce{Fe2O3 * 3H2O -> Fe2O3 + 3H2O}\]

  • \[\ce{CuCO3 * Cu(OH)2 -> 2CuO + H2O + CO2}\]

12.Page 358

Which of the following metals is (are) obtained by leaching its (their) ore(s) with dilute cyanide solution?

  • Zinc

  • Aluminium

  • Silver

  • Gold

13.Page 358

The ore of a metal contains P2O5 as impurity. The suitable flux for the ore is ______.

  • SiO2

  • CaO

  • B2O3

  • PbO

14.Page 358

Which of the following ores is (are) roasted to produce metals?

  • Bauxite

  • Copper pyrites

  • Iron pyrites

  • Horn silver

15.Page 358

Froth floatation process is used for the concentration of ______.

  • sulphide ores

  • oxide ores

  • carbonate ores

  • silicate ores

16.Page 358

In zone refining method, the molten zone consists of ______.

  • impurities only

  • pure metal only

  • a higher percentage of metal

  • a higher percentage of impurities

17.Page 358

The process of reducing the roasted ore with aluminium powder is called ______.

  • aluminothermic process

  • cyanide process

  • leaching

  • electrolytic reduction

18.Page 358

The roasted sulphide ore of Cu contains ______.

  • Cu2O only

  • Cu2S only

  • both Cu2O and Cu2S

  • metallic copper

19.Page 358

Which of the following metals can be purified by liquation method?

  • Sn

  • Hg

  • Bi

  • All of these

20.Page 358

In the poling method used to purify a metal, the molten metal is stirred with the logs of green wood. This is because the logs of green wood ______.

  • stir the molten metal thoroughly.

  • absorb the impurities present in the crude metal.

  • release hydrogen which reduces the impurities present in the crude metal.

  • release hydrocarbon gases which reduce the impurities present in the crude metal.

21.Page 358

Van Arkel method of purification of metals involves the conversion of the metal into a ______.

  • volatile stable compound

  • non-volatile unstable compound

  • non-volatile stable compound

  • volatile unstable compound

22.Page 358

During electrolytic refining ______.

  • The metal is directly transferred from the anode to the cathode.

  • The metal is directly transferred from the cathode to the anode.

  • The metal ions from the electrolytic solution get deposited on the cathode.

  • An equivalent of metal passes from the anode to the electrolyte solution.

23.Page 358

In zone refining ______.

  • The impure metal rod is kept stationary and the heater ring is moved.

  • The heater ring is kept stationary and the metal rod is moved.

  • The impurities get accumulated at the centre of the rod.

  • The impurities get accumulated at one end of the rod.

24.Page 358

Which of the following ores does not contain oxygen?

  • Magnesite

  • Zincite

  • Epsom salt

  • Cryolite

25.Page 358

Which of the following ores is not concentrated by electromagnetic method?

  • Haematite

  • Wolframite

  • Casseterite

  • Galena

26.Page 358

In the context of the Hall-Heroult process for the extraction of Al, which of the following statements is false?

  • CO and CO2 are produced in this process.

  • Al2O3 is mixed with CaF2 which lowers the melting point of the mixture and brings conductivity.

  • Al3+ is reduced at the cathode to form Al.

  • Na3AlF5 serves as the electrolyte.

27.Page 358

Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is (are):

  • impure Cu strip is used as cathode.

  • acidified aqueous CuSO4 is used as electrolyte.

  • pure Cu deposits at cathode.

  • impurities settle as anode-mud.

28.Page 358

Which one of the following ores is best concentrated by froth floatation method?

  • Magnetite

  • Siderite

  • Galena

  • Malachite

29.Page 359

Match items of Column I with the items of Column II and assign the correct code.

  Column I   Column II
(A) Cyanide process (i) Ultrapure Ge
(B) Froth floatation process (ii) Dressing of ZnS
(C) Electrolytic reduction (iii) Extraction of Al
(D) Zone refining (iv) Extraction of Au
    (v) Purification of Ni
  • (A) (B) (C) (D)
    (iv) (ii) (iii) (i)
  • (A) (B) (C) (D)
    (ii) (iii) (i) (v)
  • (A) (B) (C) (D)
    (i) (ii) (iii) (iv)
  • (A) (B) (C) (D)
    (iii) (iv) (v) (i)
30.Page 359

Extraction of gold and silver involves leaching with CN ion. Silver is later recovered by ______.

  • Liquation

  • Distillation

  • Zone refining

  • Displacement with Zn

31.Page 359

Considering the Ellingham diagram, which of the following metals can be used to reduce alumina?

  • Fe

  • Cu

  • Mg

  • Zn

32.Page 359

Match the refining methods (Column I) with metals (Column II).

Column I (Refining methods) Column II (Metals)
(I) Liquation (a) Zr
(II) Zone Refining (b) Ni
(III) Mand Process (c) Sn
(IV) Van Arkel Method (d) Ga
  • (I) - (c); (II) - (a); (III) - (b); (IV) - (d)

  • (I) - (c); (II) - (d); (III) - (b); (IV) - (a)

  • (I) - (b); (II) - (d); (III) - (a); (IV) - (c)

  • (I) - (b); (II) - (c); (III) - (d); (IV) - (a)

33.Page 359

The correct statement is:

  • Zincite is a carbonate ore.

  • Sodium cyanide cannot be used in the metallurgy of silver.

  • Aniline is a froth stabilizer.

  • Zone refining process is used for the refining of titanium.

34.Page 359

The idea of froth floatation method came from a person X and this method is related to the process Y of ores. X and Y, respectively, are:

  • washer woman and concentration

  • fisher woman and concentration

  • washer man and reduction

  • fisher man and reduction

35.Page 359

Identify the incorrect statement.

  • Gangue is an ore contaminated with undesired materials.

  • The scientific and technological process used for isolation of the metal from its ore is known as metallurgy.

  • Minerals are naturally occurring chemical substances in the earth’s crust.

  • Ores are minerals that may contain a metal.

36.Page 359

Identify the correct statement from the following:

  • Wrought iron is impure iron with 4% carbon.

  • Blister copper has blistered appearance due to evolution of CO2.

  • Vapour phase refining is carried out for nickel by van Arkel method.

  • Pig iron can be moulded into a variety of shapes.

37.Page 359

An Ellingham diagram provides information about ______.

  • the kinetics of the reduction process.

  • the conditions of pH and potential under which a species is thermodynamically stable.

  • the pressure dependence of the standard electrode potentials of reduction reactions involved in the extraction of metals.

  • the temperature dependence of the standard Gibbs energies of formation of some metal oxides.

38.Page 359

The maximum temperature that can be achieved in blast furnace is ______.

  • up to 5000 K

  • up to 1200 K

  • up to 2200 K

  • up to 1900 K

39.Page 359

Which one of the following methods can be used to obtain highly pure metal which is liquid at room temperature?

  • Zone refining

  • Electrolysis

  • Chromatography

  • Distillation

40.Page 359

The process that involves the removal of sulphur from the ores is ______.

  • Refining

  • Roasting

  • Smelting

  • Leaching

41.Page 359

Which of the following reduction reaction can not be carried out with coke?

  • \[\ce{Al2O3 -> Al}\]

  • \[\ce{ZnO -> Zn}\]

  • \[\ce{Fe2O3 -> Fe}\]

  • \[\ce{Cu2O -> Cu}\]

42.Page 359

Match List-I and List-II.

  List-I   List-II
(A) Haematite (i) Al2O3 . xH2O
(B) Bauxite (ii) Fe2O3
(C) Magnetite (iii) CuCO3 . Cu(OH)2
(D) Malachite (iv) Fe3O4

Choose the correct answer from the options given below.

  • A - (ii), B - (iii), C - (i), D - (iv)

  • A - (iv), B - (i), C - (ii), D - (iii)

  • A - (i), B - (iii), C - (ii), D - (iv)

  • A - (ii), B - (i), C - (iv), D - (iii)

43.Page 359

The chemical that is added to reduce the melting point of the reaction mixture during the extraction of aluminium is ______.

  • Cryolite

  • Bauxite

  • Calamine

  • Kaolite official

44.Page 359

Match List-I with List-II.

  List-I   List-II
(A) Mercury (i) Vapour phase refining
(B) Copper (ii) Distillation refining
(C) Silicon (iii) Electrolytic refining
(D) Nickel (iv) Zone refining

Choose the most appropriate answer from the option given below.

  • A - (i), B - (iv), C - (ii), D - (iii)

  • A - (ii), B - (iii), C - (i), D - (iv)

  • A - (ii), B - (iii), C - (iv), D - (i)

  • A - (ii), B - (iv), C - (iii), D - (i)

45.Page 360

The role of depressants in froth floatation method is to ______.

  • Selectively prevent one component of the ore from coming to the froth.

  • Reduce the consumption of oil for froth formation.

  • Stabilize the froth.

  • Enhance non-wettability of the mineral particles.

46.Page 360

In the metallurgical extraction of copper, following reaction is used:

\[\ce{FeO + SiO -> FeSiO3}\]

FeO and SiO3 respectively are ______.

  • Gangue and flux

  • Flux and slag

  • Slag and flux

  • Gangue and slag

47.Page 360

The correct statement(s) related to the metal extraction processes is (are):

  • A mixture of PbS and PbO undergoes self reduction to produce Pb and SO2.

  • In the extraction process of copper from copper pyrites, silica is added to produce copper silicate.

  • Partial oxidation of sulphide ore of copper by roasting followed by self reduction produces blister copper.

  • In cyanide process, Zinc powder is utilized to precipitate gold from Na[Au(CN)2].

48.Page 360

Match List-I with List II.

  List I (ores)   List II (composition)
(i) Haematite (A) Fe3O4
(ii) Magnetite (B) ZnCO3
(iii) Calamine (C) Fe2O3
(iv) Kaolinite (D) [Al2(OH)4 Si2O5]

Choose the correct answer from the options given below:

  • (i) - (C), (ii) - (A), (iii) - (B), (iv) - (D)

  • (i) - (C), (ii) - (A), (iii) - (D), (iv) - (B)

  • (i) - (A), (ii) - (C), (iii) - (B), (iv) - (D)

  • (i) - (A), (ii) - (B), (iii) - (C), (iv) - (D)

49.Page 360

Which of the following chemical reactions represents Hall- Heroult Process?

  • \[\ce{Cr2O3 + 2Al -> Al2O3 + 2Cr}\]

  • \[\ce{2Al2O3 + 3C -> 4Al + 3CO2}\]

  • \[\ce{FeO + CO -> Fe + CO2}\]

  • \[\ce{2[Au(CN)2]_{(aq)} + Zn_{(s)} -> 2Au_{(s)} + [Zn(CN4)^{2-}]}\]

50.Page 360

In isolation of which one of the following metals from their ores, the use of cyanide salt is not commonly involved?

  • Zinc

  • Gold

  • Silver

  • Copper

51.Page 360

Match List-I with List-II.

  List-I   List-II
(A) Concentration of gold ore (i) Aniline
(B) Leaching of alumina (ii) NaOH
(C) Froth stabiliser (iii) SO2
(D) Blister copper (iv) NaCN

Choose the correct answer from the options given below:

  • A - (iv), B - (iii), C - (ii), D - (i)

  • A - (iv), B - (ii), C - (i), D - (iii)

  • A - (iii), B - (i), C - (i), D - (iv)

  • A - (ii), B - (iv), C - (iii), D - (i)

52.Page 360

The electrochemical extraction of aluminium from bauxite ore involves ______.

  • The reaction of Al2O3 with coke (C) at a temperature > 2500°C.

  • The neutralization of aluminate solution by passing gas to precipitate hydrated alumina (Al2O3 . 3H2O).

  • The dissolution of Al2O3 in hot aqueous NaOH.

  • The electrolysis of Al2O3 mixed with Na3AIF6 to give Al and CO2.

FILL IN THE BLANKS TYPE QUESTIONS [Pages 360 - 361]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements FILL IN THE BLANKS TYPE QUESTIONS [Pages 360 - 361]

1.Page 360

The compounds of metals which occur in the earth’s crust and are obtained by mining are called ______ and the ______ from which a metal can be extracted profitably are called ______.

2.Page 360

Levigation is generally used for the concentration of ______ ores.

3.Page 360

The frothing agent used in froth floatation process is ______.

4.Page 360

Calcination and roasting processes are carried out in ______ furnace.

5.Page 360

An ______ is used to remove basic impurities; it combines with the impurities to form a fusible substance known as ______.

6.Page 360

In electrolytic refining, impure metal is made ______ while pure metal acts as ______.

7.Page 361

The formula of the sylvine ore is ______.

8.Page 361

Feldspar is a ______ ore of ______ and ______.

9.Page 361

Baeyer’s process is used when ______ ore contains higher percentage of ______.

10.Page 361

The process used for refining of aluminium is known as ______.

ASSERTION-REASON TYPE QUESTIONS [Page 361]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements ASSERTION-REASON TYPE QUESTIONS [Page 361]

The questions given below consist of an Assertion and a Reason. You have to choose the correct answer according to the following clue.

1.Page 361

Assertion: All the reactive elements occur in the combined state in nature.

Reason: The compounds of reactive metals are more stable than the metals themselves.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

2.Page 361

Assertion: Fe is more abundant than C on earth.

Reason: Fe is a volatile element, whereas C is non-volatile.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

3.Page 361

Assertion: The core of the earth is basically made of Fe alloyed with Ni.

Reason: The core is the outermost part of the earth.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

4.Page 361

Assertion: Sedimentary rocks are formed by the solidification of the molten substance during the cooling of the planet.

Reason: Sedimentary rocks are secondary rocks.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

5.Page 361

Assertion: The collectors used in froth floatation. process help ore particles to pass on into the froth.

Reason: The collectors get attached to the polar groups of the grains of mineral and make them water repellent.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

6.Page 361

Assertion: Copper obtained after bessemerisation is known as blister-copper.

Reason: Blisters are produced on the surface of the metal due to escaping of sulphur dioxide gas during cooling.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

7.Page 361

Assertion: Magnesium can reduce Al2O3 at a temperature below 1350°C while above 1350°C aluminium can reduce MgO.

Reason: The melting and boiling points of magnesium are lower than those of aluminium.

  • If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion.

  • If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.

  • If Assertion is CORRECT but Reason is INCORRECT.

  • If Assertion is INCORRECT but Reason is CORRECT.

NCERT TEXT-BOOK Exercises [Pages 361 - 363]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements NCERT TEXT-BOOK Exercises [Pages 361 - 363]

6.1Page 361

Copper can be extracted by hydrometallurgy but not zinc. Explain.

6.2Page 361

What is the role of depressant in froth floatation process?

6.3Page 261

Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

6.4 (i)Page 362

Explain the zone refining process with an example.

6.4 (ii)Page 362

Explain column chromatography.

6.5Page 362

Out of C and CO, which is a better reducing agent at 673 K?

6.6Page 362

Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?

6.7Page 362

Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.

6.8Page 362

Write chemical reactions taking place in the extraction of zinc from zinc blende.

6.9Page 362

State the role of silica in the metallurgy of copper.

6.10Page 362

What is chromatography?

6.11Page 362

What criterion is followed for the selection of the stationary phase in chromatography?

6.12Page 362

Describe a method for refining nickel.

6.13Page 362

How can you separate alumina from silica in a bauxite ore associated with silica? Give equations, if any.

6.14Page 362

Giving examples, differentiate between ‘roasting’ and ‘calcination’.

6.15Page 362

How is ‘cast iron’ different from ‘pig iron’?

6.16Page 362

Differentiate between “minerals” and “ores”.

6.17Page 362

Why copper matte is put in silica lined converter?

6.18Page 362

What is the role of cryolite in the metallurgy of aluminium?

6.19Page 362

How is leaching carried out in case of low grade copper ores?

6.20Page 362

Why is zinc not extracted from zinc oxide through reduction using CO?

6.21Page 363

The value of ΔfG° for formation of Cr2O3 is −540 kJ mol−1 and that of Al2O3 is −827 kJ mol−1. Is the reduction of Cr2O3 possible?

6.22Page 363

Out of C and CO, which is a better reducing agent for ZnO?

6.23Page 363

The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.

6.24 i.Page 363

Name the processes from which chlorine is obtained as a by-product.

6.24 ii.Page 363

What will happen if an aqueous solution of NaCl is subjected to electrolysis?

6.25Page 363

What is the role of graphite rod in the electrometallurgy of aluminium?

6.26 (i)Page 363

Explain the zone refining process with an example.

6.26 (ii)Page 363

Explain the principle of electrolytic refining with an example.

6.26 (iii)Page 363

Outline the principles of refining of metals by the following method:

Vapour phase refining

6.27Page 363

Predict conditions under which Al might be expected to reduce MgO.

QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 363 - 364]

Nootan solutions for केमिस्ट्री पार्ट १ एण्ड २ [अंग्रेजी] कक्षा १२ आईएससी 6 General Principles and Processes of Isolation of Elements QUESTIONS FROM ISC EXAMINATION PAPERS [Pages 363 - 364]

1.Page 363

Give the balanced equations for the conversion of argentite (Ag2S) to metallic silver. 

2.Page 363

Name the sulphide ore of Copper. Describe how pure copper is extracted from this ore. 

3. (i)Page 363

Describe the role of the cryolite in the extraction of aluminium from pure alumina.

3. (ii)Page 363

Describe the role of the NaCN in the extraction of silver from silver ore.

3. (iii)Page 363

What is the role of coke in the extraction of iron from its oxides?

4. i.Page 363

Name an important ore of silver.

4. ii.Page 363

How is silver extracted from its sulphide ore?

4. iii.Page 363

Give balanced chemical equations involved in the extraction of pure silver.

Select and write the correct alternative from the choices given below:

5. (i)Page 363

In the extraction of copper from its sulphide ore, the metal is finally obtained by the reduction of cuprous oxide (Cu2O) with ______.

  • Cuprous sulphide (Cu2S)

  • Iron sulphide (FeS)

  • Sulphur dioxide (SO2)

  • Carbon monoxide (CO)

5. (ii)Page 364

What is used in the blast furnace to obtain iron from haematite ore?

  • Electrolytic reduction

  • Carbon dioxide

  • Carbon monoxide

  • Aluminium

5. (iii) 1.Page 364

With reference to extraction of metal, answer the following:

What is the process of removing impurity from crude metal called?

  • Roasting

  • Calcination

  • Refining

  • Concentration

5. (ii) 2.Page 364

With reference to extraction of metal, answer the following:

Which of the following is not a method for the concentration of ores?

  • Froth floatation

  • Smelting

  • Magnetic separation

  • Gravity separation

5. (iv) 1.Page 364

Answer the following questions with reference to the extraction of copper from its ore.

Which one of the following is the sulphide ore?

  • Cuprite

  • Malachite

  • Azurite

  • Chalcopyrite

5. (iv) 2.Page 364

Answer the following questions with reference to the extraction of copper from its ore.

In the Bessemer converter, copper sulphide is reduced to copper by which one of the following reactions?

  • \[\ce{Cu2S + FeO -> 2Cu + FeO + S}\]

  • \[\ce{Cu2S + FeS -> 2Cu + FeS}\]

  • \[\ce{Cu2S + 2Cu2O -> 6Cu + SO2}\]

  • \[\ce{Cu2S + Fe -> 2Cu + FeS}\]

5. (v) 1.Page 364

Extraction of silver is done mainly from argentite (Ag2S) ore.

The concentrated ore on treatment with dil. NaCN solution and then followed by continuous agitation for several hours, which of the following products are obtained?

  • AgCN and Na2S

  • Ag and NaCN

  • Na2SO4 and Na2SO3

  • Na[Ag(CN)2] and Na2S

5. (v) 2.Page 364

Extraction of silver is done mainly from argentite (Ag2S) ore.

What is the above process of extraction of silver using dilute sodium cyanide known as?

  • Deacon’s process

  • Pattinson’s process

  • Mac-Arthur Forest cyanide process

  • Parke’s process

Solutions for 6: General Principles and Processes of Isolation of Elements

REVIEW EXERCISESVERY SHORT ANSWER TYPE QUESTIONSSHORT ANSWER TYPE QUESTIONSLONG ANSWER TYPE QUESTIONSOBJECTIVE (MULTIPLE CHOICE) TYPE QUESTIONSFILL IN THE BLANKS TYPE QUESTIONSASSERTION-REASON TYPE QUESTIONSNCERT TEXT-BOOK ExercisesQUESTIONS FROM ISC EXAMINATION PAPERS
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