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प्रश्न
Describe a method for refining nickel.
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उत्तर
Mond’s process refines nickel. In this process, nickel is heated in the presence of carbon monoxide to form nickel tetracarbonyl, a volatile complex.
\[\ce{Ni + 4 CO ->[330 - 350 K] \underset{Nickel tetracarbonyl}{Ni(CO)4}}\]
Then, the obtained nickel tetracarbonyl is decomposed by subjecting it to a higher temperature (450-470 K) to obtain pure nickel metal.
\[\ce{\underset{tetracarbonyl}{\underset{Nickel}{Ni(CO)4}} ->[450-470 K] \underset{Nickel}{Ni} + 4CO}\]
संबंधित प्रश्न
Explain the principle of the method of electrolytic refining of metals. Give one example.
Describe the roles of the following: NaCN in froth floatation process
Outline the principles behind the refining of metals by the following methods:
Chromatographic method
Write the principle behind the following methods of refining:
Vapour-phase refining
What happens when Silver is leached with NaCN in the presence of air?
Match the items of Column I with the items of Column II and assign the correct code:
| Column I | Column II |
| (A) Coloured bands | (1) Zone refining |
| (B) Impure metal to volatile complex | (2) Fractional distillation |
| (C) Purification of Ge and Si | (3) Mond Process |
| (D) Purification of mercury | (4) Chromatography |
| (5) Liquation |
Assertion: Nickel can be purified by Mond process.
Reason: \[\ce{Ni(CO)4}\] is a volatile compound which decomposes at 460 K to give pure Ni.
Assertion: Zirconium can be purificed by Van Arkel method.
Reason: ZrI4 is volatile and decomposes at 1800 K.
Assertion: Zone refining method is very useful for producing semiconductors.
Reason: Semiconductors are of high purity.
Assertion: Hydrometallurgy involves dissolving the ore in a suitable reagent followed by precipitation by a more electropositive metal.
Reason: Copper is extracted by hydrometallurgy.
Purification of crude metals by removing metallic and non-metallic impurities is known as ______ of metals.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
