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प्रश्न
What is the principle behind the zone refining of metals?
Write the principles of Zone refining Methods
Describe the principle of the following process in detail.
Zone refining
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उत्तर १
This method is used for producing metal of high purity. Metal like germanium, gallium and indium are prepared by this method. This method is based on the principle that impurities are more soluble in molten state than in the solid state of the metal.
उत्तर २
When a metal with a high degree of purity is required, this method is used. For example, this process refines silicon, gallium, and germanium, which are utilized as semiconductors. The method depends on the observation that an impurity’s solubility varies depending on whether the metal to be purified is liquid or solid.

The impure metal is cast into a thin rod using this method. This pole has a round heater attached to it. Slowly, the heater is moved along the rod. The rod melts at the heated zone, and while the heater continues, the impurities move to the nearby molten zone, causing the remaining pure metal to recrystallize. As the heater travels along the rod, the pollutants continue to flow from one zone to the next before eventually gathering at the other end of the rod. After a number of repetitions, the end that contains the impurities is finally cut off. The metal that makes up the remaining rod is highly pure.
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संबंधित प्रश्न
Name the method used for the refining of Nickel metal.
Explain column chromatography.
Write down the reaction taking place in blast furnace related to the metallurgy of iron in the temperature rnge 500 K – 800 K. What is the role of limestone in the metallurgy of iron?
Electrolytic refining is used to purify which of the following metals?
In the extraction of chlorine from brine:
(i) ∆GΘ for the overall reaction is negative.
(ii) ∆GΘ for the overall reaction is positive.
(iii) EΘ for overall reaction has negative value.
(iv) EΘ for overall reaction has positive value.
How are metals used as semiconductors refined? What is the principle of the method used?
Match the items of Column I with the items of Column II and assign the correct code:
| Column I | Column II |
| (A) Coloured bands | (1) Zone refining |
| (B) Impure metal to volatile complex | (2) Fractional distillation |
| (C) Purification of Ge and Si | (3) Mond Process |
| (D) Purification of mercury | (4) Chromatography |
| (5) Liquation |
Assertion: Zone refining method is very useful for producing semiconductors.
Reason: Semiconductors are of high purity.
Which one of the following methods can be used to obtain highly pure metal which is liquid at room temperature?
Describe a method for refining nickel.
