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प्रश्न
What is the principle behind the zone refining of metals?
Write the principles of Zone refining Methods
Describe the principle of the following process in detail.
Zone refining
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उत्तर १
This method is used for producing metal of high purity. Metal like germanium, gallium and indium are prepared by this method. This method is based on the principle that impurities are more soluble in molten state than in the solid state of the metal.
उत्तर २
When a metal with a high degree of purity is required, this method is used. For example, this process refines silicon, gallium, and germanium, which are utilized as semiconductors. The method depends on the observation that an impurity’s solubility varies depending on whether the metal to be purified is liquid or solid.

The impure metal is cast into a thin rod using this method. This pole has a round heater attached to it. Slowly, the heater is moved along the rod. The rod melts at the heated zone, and while the heater continues, the impurities move to the nearby molten zone, causing the remaining pure metal to recrystallize. As the heater travels along the rod, the pollutants continue to flow from one zone to the next before eventually gathering at the other end of the rod. After a number of repetitions, the end that contains the impurities is finally cut off. The metal that makes up the remaining rod is highly pure.
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संबंधित प्रश्न
Explain the principle of the method of electrolytic refining of metals. Give one example.
Describe the roles of the following: NaCN in froth floatation process
Out of PbS and PbCO3 (ores of lead), which one is concentrated by froth floatation process preferably?
Outline the principles behind the refining of metals by the following methods:
Chromatographic method
Write the principle behind the following methods of refining:
Vapour-phase refining
What happens when Silver is leached with NaCN in the presence of air?
In which of the following method of purification, metal is converted to its volatile compound which is decomposed to give pure metal?
(i) Heating with stream of carbon monoxide.
(ii) Heating with iodine.
(iii) Liquation.
(iv) Distillation.
Give two requirements for vapour phase refining.
Match the items of Column I with the items of Column II and assign the correct code:
| Column I | Column II |
| (A) Coloured bands | (1) Zone refining |
| (B) Impure metal to volatile complex | (2) Fractional distillation |
| (C) Purification of Ge and Si | (3) Mond Process |
| (D) Purification of mercury | (4) Chromatography |
| (5) Liquation |
Describe a method for refining nickel.
