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प्रश्न
What is the principle behind the zone refining of metals?
Write the principles of Zone refining Methods
Describe the principle of the following process in detail.
Zone refining
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उत्तर १
This method is used for producing metal of high purity. Metal like germanium, gallium and indium are prepared by this method. This method is based on the principle that impurities are more soluble in molten state than in the solid state of the metal.
उत्तर २
When a metal with a high degree of purity is required, this method is used. For example, this process refines silicon, gallium, and germanium, which are utilized as semiconductors. The method depends on the observation that an impurity’s solubility varies depending on whether the metal to be purified is liquid or solid.

The impure metal is cast into a thin rod using this method. This pole has a round heater attached to it. Slowly, the heater is moved along the rod. The rod melts at the heated zone, and while the heater continues, the impurities move to the nearby molten zone, causing the remaining pure metal to recrystallize. As the heater travels along the rod, the pollutants continue to flow from one zone to the next before eventually gathering at the other end of the rod. After a number of repetitions, the end that contains the impurities is finally cut off. The metal that makes up the remaining rod is highly pure.
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संबंधित प्रश्न
Explain:
Zone refining
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?
What is meant by the term “chromatography”?
Write down the reaction taking place in blast furnace related to the metallurgy of iron in the temperature rnge 500 K – 800 K. What is the role of limestone in the metallurgy of iron?
In the extraction of chlorine from brine:
(i) ∆GΘ for the overall reaction is negative.
(ii) ∆GΘ for the overall reaction is positive.
(iii) EΘ for overall reaction has negative value.
(iv) EΘ for overall reaction has positive value.
Assertion: Nickel can be purified by Mond process.
Reason: \[\ce{Ni(CO)4}\] is a volatile compound which decomposes at 460 K to give pure Ni.
Assertion: Hydrometallurgy involves dissolving the ore in a suitable reagent followed by precipitation by a more electropositive metal.
Reason: Copper is extracted by hydrometallurgy.
Explain the following:
Vapour phase refining method is used for the purification of Ti.
Purification of crude metals by removing metallic and non-metallic impurities is known as ______ of metals.
Describe a method for refining nickel.
