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प्रश्न
Write the chemical equations involved in van Arkel method for refining zirconium metal.
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उत्तर
This method is useful for removing impurities in the form of oxygen and nitrogen in metal like zirconium. The crude metal is heated in an evacuated vessel with iodine. The metal iodine volatilizes.
\[\ce{\underset{\text{Impure}}{Zr} + 2I2 -> \underset{\text{Vapour}}{ZrI4}}\]
The metal iodine is decomposed on tungsten filament, electrically heated to about 1800K. The pure metal is thus deposited on the filament
\[\ce{\underset{\text{Vapour}}{ZrI4} -> \underset{\text{Pure}}{Zr} + 2I2}\]
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संबंधित प्रश्न
Explain the principle of the method of electrolytic refining of metals. Give one example.
Describe the roles of the following: NaCN in froth floatation process
Explain column chromatography.
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?
What is meant by the term “chromatography”?
Outline the principles of refining of metals by the following method:
Vapour phase refining
Indicate the principle behind the method used for the refining of Nickel.
Write the principle behind the following methods of refining:
Vapour-phase refining
Write down the reaction taking place in blast furnace related to the metallurgy of iron in the temperature rnge 500 K – 800 K. What is the role of limestone in the metallurgy of iron?
What happens when Silver is leached with NaCN in the presence of air?
Name the method of refining which is Used to obtain semiconductor of high purity.
In which of the following method of purification, metal is converted to its volatile compound which is decomposed to give pure metal?
(i) Heating with stream of carbon monoxide.
(ii) Heating with iodine.
(iii) Liquation.
(iv) Distillation.
Match the items of Column I with the items of Column II and assign the correct code:
| Column I | Column II |
| (A) Coloured bands | (1) Zone refining |
| (B) Impure metal to volatile complex | (2) Fractional distillation |
| (C) Purification of Ge and Si | (3) Mond Process |
| (D) Purification of mercury | (4) Chromatography |
| (5) Liquation |
Assertion: Nickel can be purified by Mond process.
Reason: \[\ce{Ni(CO)4}\] is a volatile compound which decomposes at 460 K to give pure Ni.
Explain the following:
Vapour phase refining method is used for the purification of Ti.
Purification of crude metals by removing metallic and non-metallic impurities is known as ______ of metals.
Which one of the following methods can be used to obtain highly pure metal which is liquid at room temperature?
Electrolytic reduction method is used for the extraction of ______.
Refining using liquation method is the most suitable for metals with ______.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
