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प्रश्न
Write the chemical equations involved in van Arkel method for refining zirconium metal.
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उत्तर
This method is useful for removing impurities in the form of oxygen and nitrogen in metal like zirconium. The crude metal is heated in an evacuated vessel with iodine. The metal iodine volatilizes.
\[\ce{\underset{\text{Impure}}{Zr} + 2I2 -> \underset{\text{Vapour}}{ZrI4}}\]
The metal iodine is decomposed on tungsten filament, electrically heated to about 1800K. The pure metal is thus deposited on the filament
\[\ce{\underset{\text{Vapour}}{ZrI4} -> \underset{\text{Pure}}{Zr} + 2I2}\]
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संबंधित प्रश्न
Name the method used for the refining of Nickel metal.
Name the method used for the refining of zirconium.
Explain the principle of the method of electrolytic refining of metals. Give one example.
Describe the roles of the following: NaCN in froth floatation process
Explain:
Zone refining
What is meant by the term “chromatography”?
Indicate the principle behind the method used for the refining of Nickel.
Outline the principles behind the refining of metals by the following methods:
Zone refining method
Write the principle behind the following methods of refining:
Vapour-phase refining
Name the method of refining which is Used to obtain semiconductor of high purity.
Name the method of refining which is Used to obtain low boiling metal.
In the extraction of chlorine from brine:
(i) ∆GΘ for the overall reaction is negative.
(ii) ∆GΘ for the overall reaction is positive.
(iii) EΘ for overall reaction has negative value.
(iv) EΘ for overall reaction has positive value.
Which method is used for refining Zr and Ti? Explain with equation.
How are metals used as semiconductors refined? What is the principle of the method used?
Give two requirements for vapour phase refining.
Match the items of Column I with the items of Column II and assign the correct code:
| Column I | Column II |
| (A) Coloured bands | (1) Zone refining |
| (B) Impure metal to volatile complex | (2) Fractional distillation |
| (C) Purification of Ge and Si | (3) Mond Process |
| (D) Purification of mercury | (4) Chromatography |
| (5) Liquation |
Assertion: Zirconium can be purificed by Van Arkel method.
Reason: ZrI4 is volatile and decomposes at 1800 K.
Purification of crude metals by removing metallic and non-metallic impurities is known as ______ of metals.
Refining using liquation method is the most suitable for metals with ______.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
Describe a method for refining nickel.
