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Cells, EMF, and Internal Resistance

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Estimated time: 9 minutes
CBSE: Class 12

Introduction

An electric cell is a device that converts chemical energy into electrical energy. It consists of two electrodes (positive and negative terminals) immersed in an electrolyte (a conducting solution or paste). Chemical reactions within the electrolyte maintain a potential difference between the electrodes, which drives current through an external circuit.

CBSE: Class 12

Definition: EMF of a Cell

The emf of a cell is defined as the work done in carrying a unit positive charge through the complete circuit, including the charge flow inside the cell.

Unit: J/C (or) volt

CBSE: Class 12

Definition: Internal Resistance of a Cell

The resistance offered by the electrolyte of the cell when an electric current flows through it is known as internal resistance.

CBSE: Class 12

Definition: Terminal Potential Difference (V)

When current is drawn through a cell or current is supplied to it, then the potential difference across its terminals is called the terminal potential difference.

\[V=E-Ir\]

CBSE: Class 12

Derivation

Relation Between EMF, Terminal Voltage, and Internal Resistance

Setup: Consider a cell of EMF εε and internal resistance r, connected to an external resistance R. Let current I flow in the circuit.

Step 1: The cell drives current through both the external resistance R and its own internal resistance r.

Step 2: By Ohm's law, the potential drop across the internal resistance is:

Vinternal = Ir

Step 3: The remaining potential difference appears across the external resistance (terminal voltage):

V = ε − Ir   ...(1)

Step 4: By Ohm's law applied to external resistance:

V = IR   ...(2)

Step 5: From equations (1) and (2):

IR = ε − Ir
ε = I(R + r)
I = \[\frac {ε}{R+r}\]   ...(3)

Step 6: Maximum current (when R = 0, i.e., short circuit):

Imax = \[\frac {ε}{r}\]
CBSE: Class 12

Discharging vs. Charging — Comparison Table

Parameter Discharging (Cell supplies current) Charging (Current enters cell) Open Circuit
Current direction Out of (+) terminal Into (+) terminal No current
Terminal voltage formula V = ε − Ir V = ε + Ir V = ε
Terminal voltage vs EMF V < ε V > ε V = ε
Energy conversion Chemical → Electrical Electrical → Chemical
CBSE: Class 12

Factors Affecting Internal Resistance

Internal resistance increases or decreases with the following factors:

Factor Effect on Internal Resistance
Distance between electrodes Increases as distance increases
Surface area of electrodes Decreases as the area increases
Nature of electrolyte Depends on the ionic mobility of the solution
Concentration of electrolyte Decreases with higher concentration
Temperature of the electrolyte Decreases as temperature increases

Shaalaa.com | Current Electricity part 3 (EMF :- Electro Motive Force)

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