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Karnataka Board PUCPUC Science 2nd PUC Class 12

Classification of Metals, Conductors and Semiconductors

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Estimated time: 12 minutes
CBSE: Class 12

Introduction

Every electronic device — from a simple LED to a smartphone chip — is built from materials chosen for their ability to conduct or resist electricity. Understanding how and why different materials conduct electricity is the foundation of all semiconductor electronics.

Solids are broadly classified based on two key electrical parameters:

Parameter Symbol SI Unit Relationship
Resistivity ρ Ω·m Lower → better conductor
Conductivity σ S·m⁻¹ σ = \[\frac {1}{ρ}\]
CBSE: Class 12

Classification by Resistivity & Conductivity

Comparison Table

Property Metals (Conductors) Semiconductors Insulators
Resistivity (ρ) 10−8 to 10−2 Ω·m 10−5 to 106 Ω·m 1011 to 1019 Ω·m
Conductivity (σ) 102 to 108 S·m−1 10−6 to 105 S·m−1 10−19 to 10−11 S·m−1
Band Gap (Eg) ~0 eV (overlapping bands) < 3 eV (Si: 1.1 eV, Ge: 0.7 eV) > 3 eV (Diamond: ~5.4 eV)
Effect of Temperature Resistance increases with temp Resistance decreases with temp Remains non-conducting
Free electrons at RT A very large number Small number (thermally excited) Virtually none
Examples Cu, Ag, Al, Fe Si, Ge, GaAs Glass, Rubber, Diamond
CBSE: Class 12

Energy Band Theory

Formation of Energy Bands

In a single isolated atom, electrons occupy discrete, well-defined energy levels (like rungs of a ladder).

When atoms are packed together in a crystal lattice, electrons are shared among neighbouring atoms. This causes:

  • Each discrete energy level splits into closely spaced levels
  • These closely spaced levels collectively form an energy band

Analogy: Think of a single tuning fork producing one frequency. When thousands of tuning forks are placed close together, they create a continuous range (band) of frequencies, not a single note.

Key Energy Bands

 
Band Description
Valence Band (VB) The highest-energy band that is completely or partially filled with electrons at 0 K. Electrons here are bound to atoms.
Forbidden Energy Gap (E_g) Energy region with no allowed states. Electrons cannot exist here. Also called the Band Gap.
Conduction Band (CB) Energy band above the valence band. Electrons here are free to move and conduct electricity.
CBSE: Class 12

Classification Based on Energy Band Theory

Metals (Conductors)

  • Valence band and conduction band overlap (Eg ≈ 0)  OR conduction band is partially filled
  • A large number of free electrons are available at room temperature (RT)
  • Even a tiny applied voltage drives current easily
  • Temperature effect: Resistance increases with temperature (increased lattice vibrations scatter electrons)

Insulators

  • The valence band is completely filled; the conduction band is completely empty
  • Very large energy gap (Eg > 3 eV, e.g., Diamond Eg ≈ 5.4 eV)
  • Thermal energy at RT (≈ 0.026 eV) is far too small to excite electrons across the gap
  • No conduction possible under normal conditions

Semiconductors

  • Valence band completely filled at 0 K → acts as an insulator at absolute zero
  • Small energy gap (Eg < 3 eV):
    Silicon (Si): Eg = 1.1 eV
    Germanium (Ge): Eg = 0.7 eV
  • At room temperature, some electrons gain sufficient thermal energy to jump into the conduction band, leaving behind holes in the valence band
  • Both electrons (in CB) and holes (in VB) contribute to conduction
CBSE: Class 12

Types of Semiconductors

Elemental Semiconductors

  • Composed of single-element atoms arranged in a crystal lattice
  • Each atom has 4 valence electrons, forming covalent bonds with 4 neighbours
  • Most important for electronics: Silicon (Si) and Germanium (Ge)
Property Silicon (Si) Germanium (Ge)
Atomic Number 14 32
Band Gap (E_g) 1.1 eV 0.7 eV
Melting Point 1414 °C 938 °C
Common Use Chips, solar cells High-speed devices

Si is preferred over Ge in most devices because its higher band gap provides better stability at room temperature, and its oxide (SiO₂) is an excellent insulator for fabrication.

Compound Semiconductors

Formed by combining two or more elements, it allows tailoring of the band gap for specific applications:

Category Examples Application
Inorganic CdS, GaAs, CdSe, InP LEDs, solar cells, laser diodes
Organic Anthracene, doped phthalocyanines OLEDs, sensors
Organic Polymers Polypyrrole, polyaniline, polythiophene Flexible electronics, biosensors
CBSE: Class 12

Real-World Analogy

  • A conductor is like a wide-open gateway — electrons flow freely at all times.
  • An insulator is like a locked door — no matter how hard you push, nothing gets through.
  • A semiconductor is like a turnstile with a spring — it normally stays locked, but with enough push (heat, light, or voltage), it lets electrons through. The more you push, the more it conducts.
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