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Einstein’s Photoelectric Equation: Energy Quantum of Radiation

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Estimated time: 6 minutes
CBSE: Class 12

Need for Einstein’s Explanation

Classical wave theory could not explain why no electrons are emitted below a threshold frequency or why emission is instantaneous. Einstein explained these results by proposing that light energy is absorbed in discrete packets called photons.

Photon idea

  • Light consists of photons.
  • The energy of one photon is given by: E = hνE

where:

  • E = energy of a photon
  • h = Planck’s constant
  • ν = frequency of incident radiation

Higher frequency means higher photon energy.

CBSE: Class 12

Einstein’s Photoelectric Equation

When a photon strikes an electron in the metal, part of its energy is used to remove the electron from the surface, and the remaining part appears as kinetic energy.

hν = ϕ0 + Kmax

or,

Kmax = hν − ϕ0

where:

  • ϕ0 = work function of the metal
  • Kmax​ = maximum kinetic energy of emitted photoelectrons

Meaning of work function

The work function is the minimum energy required to remove an electron from the surface of a metal.

Threshold condition

For photoelectric emission to occur:

hν ≥ ϕ0

If the incident radiation has the threshold frequency ν0​, then:

ϕ0 = hν0

or,

ν0 = \[\frac {ϕ_0}{h}\]
CBSE: Class 12

Stopping Potential

The maximum kinetic energy of photoelectrons can also be written in terms of the stopping potential V0:

Kmax = eV0

Therefore,

eV0 = hν − ϕ0

or,

V0 = \[\frac {h}{e}\]ν − \[\frac {ϕ_0}{e}\]
CBSE: Class 12

Einstein’s Equation Explains the Laws

1. Existence of threshold frequency

If photon energy is less than the work function, electrons cannot escape from the metal surface. Therefore, no emission takes place below the threshold frequency.

2. Instantaneous emission

A single photon transfers its energy to a single electron in one interaction, so emission begins without measurable delay.

3. Kinetic energy depends on frequency

When frequency increases, photon energy increases, so the maximum kinetic energy of photoelectrons also increases.

4. The number of electrons depends on the intensity

If the frequency is above the threshold, greater intensity means more photons strike the surface per second, so more electrons are emitted.

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