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Study of Rate of Reaction between Hydrogen peroxide and Iodine Ion

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Estimated time: 3 minutes
CBSE: Class 12

Key Points: Study of Rate of Reaction between Hydrogen peroxide and Iodine Ion

In acidic medium: H₂O₂ + 2I⁻ + 2H⁺ → I₂ + 2H₂O (H₂O₂ oxidises I⁻ to I₂)

The iodine produced is immediately reduced back by sodium thiosulfate:

  • I₂ + 2S₂O₃²⁻ → S₄O₆²⁻ + 2I⁻

This continues until all S₂O₃²⁻ is consumed

  • After that, any I₂ produced reacts with starch → deep blue complex (I₂ + starch → blue)
  • Time for blue colour to appear indicates the rate of I₂ formation → clock reaction
  • The rate of reaction changes with a change in the concentration of iodide ions
  • As the thiosulphate amount added is fixed and the time for blue colour is measured → rate of I₂ production is determined
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