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Avogadro's Law

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Estimated time: 5 minutes
  • Definition: Atom
  • Definition: Molecule
  • Definition: Avogadro's Law
CISCE: Class 10

Definition: Atom

An atom is the smallest particle of an element that can take part in a chemical reaction; however, it may or may not exist independently. 

CISCE: Class 10

Definition: Molecule

A molecule is the smallest particle of an element or a compound that can exist by itself; it never breaks up except for taking part in a chemical reaction.

CBSE: Class 12
Maharashtra State Board: Class 12
CISCE: Class 10

Law: Avogadro's Law

"Equal volumes of all gases at the same temperature and pressure contain equal numbers of molecules."

  • Proposed by Avogadro in 1811.
  • 1 mole of any gas at STP = 22.4 L (at 0°C, 1 atm) or 22.71 L (at 0°C, 1 bar — new IUPAC STP).
  • 1 mole of any substance = 6.022 × 10²³ particles.

Avogadro's Law (Volume–Moles Relationship):

At constant temperature (T) and pressure (P), volume is directly proportional to number of moles.

\[V\propto n\quad\Rightarrow\quad\frac{V_1}{n_1}=\frac{V_2}{n_2}\]

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