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Gay-Lussac's Law

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Estimated time: 7 minutes
  • Definition: Limiting Reagent or Limiting Reactant
  • Law: Gay-Lussac's Law of Combining Volumes
CISCE: Class 10

Definition: Limiting Reagent or Limiting Reactant

The reactant which is completely used up in a reaction is known as Limiting reagent or Limiting reactant.

CISCE: Class 10

Law: Gay-Lussac's Law of Combining Volumes

When gases react, they do so in volumes which bear a simple ratio to one another, and to the volume of the gaseous product, provided that all the volumes are measured at the same temperature and pressure.

Maharashtra State Board: Class 11, 12

Law: Gay-Lussac's Law

Gay-Lussac's Law (Pressure–Temperature Relationship):

At constant volume (V) and number of moles (n), pressure is directly proportional to absolute temperature.

\[P\propto T\quad\Rightarrow\quad\frac{P_1}{T_1}=\frac{P_2}{T_2}\]

or

Statement:

The pressure of a fixed mass of gas is directly proportional to its absolute temperature if volume is kept constant.

Mathematically, P ∝ T ⇒ \[\frac {P}{T}\] = constant

This means: heating a gas in a sealed (rigid) container increases its pressure.

Graph: P vs T (Isochore)

Gay-Lussac's Law P vs T graph showing straight line
P vs T graph at constant volume — a straight line through the origin (Kelvin scale).

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