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Intermolecular Forces

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Estimated time: 5 minutes
Maharashtra State Board: Class 12

Key Points: Intermolecular Forces

Intermolecular forces are attractive (and repulsive) forces acting between neighbouring molecules. They are weaker than covalent or ionic bonds but determine the physical state of matter.

As intermolecular forces increase: Gas → Liquid → Solid (thermal energy decreases in the same direction).

Types of Intermolecular Forces:

Type Occurrence Strength Key Point Example
Dipole–Dipole Between polar molecules Medium (3–4 kJ mol⁻¹) +ve end attracts –ve end HCl
Ion–Dipole Between ion & polar molecule Stronger than dipole–dipole Depends on charge & size of ion Na⁺ – H₂O
Dipole–Induced Dipole Polar + non-polar molecule Weak Polar molecule induces dipole NH₃ + C₆H₆
London Dispersion Non-polar molecules, noble gases Weakest Due to temporary dipoles N₂, O₂, noble gases
Hydrogen Bonding H with N, O, F Strong (but < covalent) Special dipole–dipole HF, H₂O

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