मराठी
Tamil Nadu Board of Secondary EducationHSC Science Class 11

Spontaneity - Absolute Entropy and Third Law of Thermodynamics

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Estimated time: 2 minutes
CBSE: Class 12

Key Points: Third Law of Thermodynamics and Absolute Entropy

Third Law: The entropy of a perfectly ordered crystalline substance at absolute zero (0 K) is zero.

Absolute Entropy (Standard Molar Entropy, S°): The entropy value of a substance at 298 K and 1 bar pressure, relative to 0 K.

  • Unlike the enthalpy of formation, the absolute entropy of elements is not zero at standard conditions.
  • Standard entropy of reaction: \[\Delta_{r}S^{\circ}=\sum S_{products}^{\circ}-\sum S_{reactants}^{\circ}\]

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