NCERT solutions for केमिस्ट्री पार्ट १ अँड २ [इंग्रजी] इयत्ता १२ chapter 4 - The d-block and f-block Elements [Latest edition]

Silver atom has completely filled d orbitals (4d¹⁰) in its ground state. How can you say that it is a transition element?

Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?

The `E_((M^(2+)//M))^Θ` value for copper is positive (+0.34 V). What is possibly the reason for this? (Hint: consider its high Δ_aH^Θ and low Δ_hydH^Θ)

How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?

Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?

Which is a stronger reducing agent, Cr²⁺ or Fe²⁺ and why?

Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{ (aq)}}\] ion (Z = 27).

Explain why Cu⁺ ion is not stable in aqueous solutions?

How would you account for the following:

Actinoid contraction is greater than lanthanoid contraction.

Write down the electronic configuration of Cr³⁺.

Write down the electronic configuration of Pm³⁺.

Write down the electronic configuration of Cu⁺.

Write down the electronic configuration of Ce⁴⁺.

Write down the electronic configuration of Co²⁺.

Write down the electronic configuration of Lu²⁺.

Write down the electronic configuration of Mn²⁺.

Write down the electronic configuration of Th⁴⁺.

Why are Mn²⁺ compounds more stable than Fe²⁺ towards oxidation to their +3 state?

Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?

To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.

What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of its atom?

3d³

Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.

What is Lanthanoid contraction?

What are the consequences of lanthanoid contraction?

What are the characteristics of the transition elements and why are they called transition elements? 

Which of the d-block elements may not be regarded as the transition elements?

In what way is the electronic configuration of the transition elements different from that of the non-transition elements?

What are the different oxidation states exhibited by the lanthanoids?

Explain giving reason:

Transition metals and many of their compounds show paramagnetic behaviour.

Why do the transition elements have higher enthalpies of atomisation?

Give reasons for the following:

The transition metals generally form coloured compounds.

How would you account for the following? 

Transition metals and their compounds act as catalysts.

What are interstitial compounds?

Why are interstitial compounds well known for transition metals?

How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.

Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?

Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iodide.

Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iron (II) solution.

Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with H₂S.

Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with iron (II) ions? Write the ionic equation for the reaction.

Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO₂? Write the ionic equation for the reaction.

Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with oxalic acid? Write the ionic equation for the reaction.

For M²⁺/M and M³⁺/M²⁺ systems, the E^Θ values for some metals are as follows:

Use this data to comment upon:

The stability of Fe³⁺ in acid solution as compared to that of Cr³⁺ or Mn³⁺.

For M²⁺/M and M³⁺/M²⁺systems, the E^Θ values for some metals are as follows:

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

Predict which of the following will be coloured in the aqueous solution?

Ti³⁺, V³⁺, Cu⁺, Sc³⁺, Mn²⁺, Fe³⁺ and Co²⁺. Give reasons for each.

Compare the stability of +2 oxidation state for the elements of the first transition series.

Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.

Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.

Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.

Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.

How would you account for the following:

Of the d⁴ species, Cr²⁺ is strongly reducing while manganese (III) is strongly oxidising.

How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.

How would you account for the following: 

The d¹ configuration is very unstable in ions.

What is meant by ‘disproportionation’? 

Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?

Calculate the number of unpaired electrons in the following gaseous ions:

Mn³⁺, Cr³⁺, V³⁺ and Ti³⁺. Which one of these is the most stable in an aqueous solution?

Give an example and suggest a reason for the following feature of the transition metal chemistry:

The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.

Give an example and suggest a reason for the following feature of the transition metal chemistry:

A transition metal exhibits the highest oxidation state in oxides and fluorides.

Give an example and suggest a reason for the following feature of the transition metal chemistry:

 The highest oxidation state is exhibited in oxoanions of a metal.

Indicate the steps in the preparation of K₂Cr₂O₇ from chromite ore.

Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO₂? Write the ionic equation for the reaction.

What are alloys?

Name an important alloy which contains some of the lanthanoid metals.

Mention uses of alloys.

What are inner transition elements?

Decide which of the following atomic numbers are the atomic numbers of the inner transition elements:

29, 59, 74, 95, 102, 104

The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.

Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.

Use Hund’s rule to derive the electronic configuration of Ce³⁺ ion and calculate its magnetic moment on the basis of ‘spin-only’ formula.

Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.

Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.

Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.

Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.

Write the electronic configurations of the element with the atomic number 61.

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Electronic configurations

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Oxidation states

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Ionisation enthalpies

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Atomic sizes

Write down the number of 3d electrons in the following ion:

Ti²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

V²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Cr³⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Mn²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Fe²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Fe³⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Co²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Ni²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Write down the number of 3d electrons in the following ion:

Cu²⁺

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).

Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.

What can be inferred from the magnetic moment value of the following complex species?

What can be inferred from the magnetic moment value of the following complex species?

What can be inferred from the magnetic moment value of the following complex species?