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प्रश्न
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
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उत्तर
The general electronic configuration of lanthanoids is [Xe]54 4f1−14 5d0−1 6s2, while the general electronic configuration of actinoids is [Rn]86 5f1−14 6d1−2 7s2. Hence, lanthanoids belong to the 4f series, and actinoids belong to the 5f series.
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संबंधित प्रश्न
Define lanthanoid contraction.
What are chemical twins? Write ‘two’ examples.
What are lanthanoids?
Which among the following pairs of elements is 'not' an example of chemical twins?
What are the different oxidation states exhibited by the lanthanoids?
Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
Explain effects of lanthanoid contraction.
Account for the following:
Zn, Cd and Hg are soft metals.
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?
Match the statements given in Column I with the oxidation states given in Column II.
| Column I | Column II | |
| (i) | Oxidation state of Mn in MnO2 is | (a) + 2 |
| (ii) | Most stable oxidation state of Mn is | (b) + 3 |
| (iii) | Most stable oxidation state of | (c) + 4 |
| Mn in oxides is | (d) + 5 | |
| (iv) | Characteristic oxidation state of lanthanoids is | (e) + 7 |
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
On the basis of Lanthanoid contraction, explain the following:
Radii of 4d and 5d block elements.
On the basis of Lanthanoid contraction, explain the following:
Trends in acidic character of lanthanoid oxides.
Which of the following pairs has the same ionic size?
State a reason for the following:
La(OH)3 is more basic than Lu(OH)3.
Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.
Name an important alloy which contains some of the lanthanoid metals. Mention its uses.
