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What are lanthanoids? - Chemistry

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प्रश्न

What are lanthanoids?

अति संक्षिप्त उत्तर
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उत्तर

The series involving the filling of 4f-orbitals following lanthanum La (Z = 57) is called the lanthanoid series. The elements present in this series are called lanthanoids.

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2013-2014 (March)

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संबंधित प्रश्‍न

Define lanthanoid contraction.


What are chemical twins? Write ‘two’ examples.


Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.


Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.


Explain effects of lanthanoid contraction.


What are the consequences of lanthanoid contraction?


Account for the following: 

Zn, Cd and Hg are soft metals.


Explain the cause of Lanthanoids contraction.


Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)? 

(at. no. of Lanthanum  = 57 and Lutetium = 71)


Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent? 


What is meant by Lanthanide contraction? Write the general electronic configuration of inner transition elements. 


What is Lanthanoid contraction?


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Match the compounds/elements given in Column I with uses given in Column II.

  Column I (Compound/element) Column II (Use)
(i)  Lanthanoid oxide (a) Production of iron alloy
(ii)  Lanthanoid (b) Television screen
(iii)  Misch metal (c) Petroleum cracking
(iv)  Magnesium based alloy is constituent of (d) Lanthanoid metal + iron
(v)  Mixed oxides of lanthanoids are employed (e) Bullets
    (f) In X-ray screen

On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].


On the basis of Lanthanoid contraction, explain the following:

Stability of the complexes of lanthanoids.


On the basis of Lanthanoid contraction, explain the following:

Trends in acidic character of lanthanoid oxides.


How would you account for the following:

There is a greater range of oxidation states among the actinoids than among the lanthanides.


In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.


Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of ______.


Write a note on lanthanoids.


State a reason for the following:

La(OH)3 is more basic than Lu(OH)3.


Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.

Reason: Lanthanoids do not show Lanthanoid contraction.


Name an important alloy which contains some of the lanthanoid metals.


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