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प्रश्न
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
Account for the following:
Actinoids show more number of oxidation states than lanthanoids.
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उत्तर
Actinides exhibit larger oxidation states than lanthanides because of the very small energy gap between 5f, 6d, and 7s subshells as compared to 4f, 5d, and 6s orbitals in the case of lanthanoids. Thus, the outermost electrons get easily excited to the higher energy levels, giving variable oxidation states.
संबंधित प्रश्न
The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
Write the electronic configurations of the element with the atomic number 61.
Write the different oxidation states of iron
Explain the cause of Lanthanoids contraction.
Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?
Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate them. Why?
Match the property given in Column I with the element given in Column II.
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
| (ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
| (iii) | Radioactive lanthanoid | (c) Lu |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
| (f) Dy |
On the basis of Lanthanoid contraction, explain the following:
Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].
Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.
Reason: Lanthanoids do not show Lanthanoid contraction.
Mention uses of alloys.
