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प्रश्न
What is lanthanoid contraction? Write the.............
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उत्तर
The regular decrease in atomic and ionic radii from lanthanum to lutetium with increasing atomic number is called lanthanoid contraction.
Consequences :
The net result of the lanthanoid contraction is that the second and third d-series exhibit similar radii
Zr =160 pm
and Hf = 159pm
They have very similar physical and chemical properties.
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संबंधित प्रश्न
Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.
Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?
Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?
(i) \[\ce{Ce}\]
(ii) \[\ce{Eu}\]
(iii) \[\ce{Yb}\]
(iv) \[\ce{Ho}\]
Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:
(i) it has variable ionisation enthalpy
(ii) it has a tendency to attain noble gas configuration
(iii) it has a tendency to attain f 0 configuration
(iv) it resembles Pb4+
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
Which of the following pairs has the same ionic size?
Write any two consequences of Lanthanoid Contraction.
The lathanide ion that would show colour is ______.
Name an important alloy which contains some of the lanthanoid metals.
