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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids? (i) Ce (ii) Eu (iii) Yb (iv) Ho

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प्रश्न

Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]

टीपा लिहा
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उत्तर

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

Explanation:

\[\ce{Ce}\] (Z = 57) = [Xe] 4f5 5d0 6s2, O.S. = + 3, + 4

\[\ce{Eu}\] (Z = 63) = [Xe] 4f7 5d0 6s2, O.S. = + 2, + 3

\[\ce{Yb}\] (Z = 70) = [Xe] 4f14 5d0 6s2, O.S. = + 2, + 3

\[\ce{Ho}\] (Z = 67) = [Xe] 4f11 5d0 6s2, O.S. = + 3

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 27 | पृष्ठ ११०

संबंधित प्रश्‍न

Define lanthanoid contraction.


What are chemical twins? Write ‘two’ examples.


What are lanthanoids?


Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.


What are the different oxidation states exhibited by the lanthanoids?


The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.


Write the different oxidation states of iron


Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?


Account for the following: 

Zn, Cd and Hg are soft metals.


Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)? 

(at. no. of Lanthanum  = 57 and Lutetium = 71)


Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent? 


Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:

(i) it has variable ionisation enthalpy

(ii) it has a tendency to attain noble gas configuration

(iii) it has a tendency to attain f 0 configuration

(iv) it resembles Pb4+ 


Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate them. Why?


Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?


On the basis of Lanthanoid contraction, explain the following:

Nature of bonding in \[\ce{La2O3}\] and \[\ce{Lu2O3}\] .


On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].


On the basis of Lanthanoid contraction, explain the following:

Trends in acidic character of lanthanoid oxides.


Which of the following pairs has the same ionic size?


Cerium (Z = S8) is an important member of lanthanoids. Which of the following statements about cerium is incorrect?


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