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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?

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प्रश्न

Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?

टीपा लिहा
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उत्तर

The electronic configuration of \[\ce{Ce is -4f^1 5d^1 6s^2}\]. Usually 5d’ and 6s2 electrons are lost by the lanthanoids in their reactions i.e., they exhibit +3 oxidation states. But Ce exhibit +4 oxidation state also because it gains extra stability by losing 4f1 electron because it will give rise to completely filled orbitals.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 43 | पृष्ठ १११

संबंधित प्रश्‍न

What are chemical twins? Write ‘two’ examples.


What are lanthanoids?


What are the different oxidation states exhibited by the lanthanoids?


The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.


Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.


Write the different oxidation states of iron


Explain effects of lanthanoid contraction.


Account for the following: 

Zn, Cd and Hg are soft metals.


What is meant by Lanthanide contraction? Write the general electronic configuration of inner transition elements. 


What is the action of the following on lanthanoids?
a. water
b. Sulphur, heat
c. nitrogen, heat


What is lanthanoid contraction?


The f-block elements are known as ____________.


Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]


Although Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to separate them. Why?


On the basis of Lanthanoid contraction, explain the following:

Stability of the complexes of lanthanoids.


On the basis of Lanthanoid contraction, explain the following:

Trends in acidic character of lanthanoid oxides.


The titanium (Z = 22) compound that does not exist is:-


In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.


Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of ______.


Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.

Reason: Lanthanoids do not show Lanthanoid contraction.


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