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Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?

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प्रश्न

Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?

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उत्तर

The electronic configuration of \[\ce{Ce is -4f^1 5d^1 6s^2}\]. Usually 5d’ and 6s2 electrons are lost by the lanthanoids in their reactions i.e., they exhibit +3 oxidation states. But Ce exhibit +4 oxidation state also because it gains extra stability by losing 4f1 electron because it will give rise to completely filled orbitals.

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 43 | पृष्ठ १११

संबंधित प्रश्न

What are chemical twins? Write ‘two’ examples.


What are lanthanoids?


Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.


Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.


Write the different oxidation states of iron


Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?


Account for the following: 

Zn, Cd and Hg are soft metals.


What is lanthanoid contraction?


Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?


On the basis of Lanthanoid contraction, explain the following:

Radii of 4d and 5d block elements.


How would you account for the following:

There is a greater range of oxidation states among the actinoids than among the lanthanides.


The titanium (Z = 22) compound that does not exist is:-


In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.


Mischmetal is an alloy consisting mainly of ______.


Cerium (Z = S8) is an important member of lanthanoids. Which of the following statements about cerium is incorrect?


Write a note on lanthanoids.


State a reason for the following:

La(OH)3 is more basic than Lu(OH)3.


Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.


Name an important alloy which contains some of the lanthanoid metals. Mention its uses.


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