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What are lanthanoids? - Chemistry

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प्रश्न

What are lanthanoids?

अति संक्षिप्त उत्तर
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उत्तर

The series involving the filling of 4f-orbitals following lanthanum La (Z = 57) is called the lanthanoid series. The elements present in this series are called lanthanoids.

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अध्याय 8: d-and ƒ-Block Elements - LONG ANSWER TYPE QUESTIONS [पृष्ठ ४९८]

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नूतन Chemistry Part 1 and 2 [English] Class 12 ISC
अध्याय 8 d-and ƒ-Block Elements
LONG ANSWER TYPE QUESTIONS | Q 11. i. | पृष्ठ ४९८

संबंधित प्रश्न

Define lanthanoid contraction.


What are chemical twins? Write ‘two’ examples.


What are the different oxidation states exhibited by the lanthanoids?


Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.


Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.


Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.


Write the electronic configurations of the element with the atomic number 61.


Write the different oxidation states of iron


Explain effects of lanthanoid contraction.


Account for the following: 

Zn, Cd and Hg are soft metals.


Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)? 

(at. no. of Lanthanum  = 57 and Lutetium = 71)


What is the action of the following on lanthanoids?
a. water
b. Sulphur, heat
c. nitrogen, heat


The f-block elements are known as ____________.


Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]


Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:

(i) it has variable ionisation enthalpy

(ii) it has a tendency to attain noble gas configuration

(iii) it has a tendency to attain f 0 configuration

(iv) it resembles Pb4+ 


Match the statements given in Column I with the oxidation states given in Column II.

  Column I Column II
(i) Oxidation state of Mn in MnO2 is (a) + 2
(ii) Most stable oxidation state of Mn is (b) + 3
(iii) Most stable oxidation state of  (c) + 4
  Mn in oxides is (d) + 5
(iv) Characteristic oxidation state of lanthanoids is (e) + 7

On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].


On the basis of Lanthanoid contraction, explain the following:

Trends in acidic character of lanthanoid oxides.


The lathanide ion that would show colour is ______.


Which one of the lanthanoids given below is the most stable in divalent form?


Why is Mn2+ ion more stable than Fe2+ ion?

(Atomic numbers of Mn = 25 and Fe = 26)


Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.


Mention uses of alloys.


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