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प्रश्न
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
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उत्तर
Ce(Z = 58)
Ce = 4f15d16s2
It is a strong oxidising agent.
⇒ Formationof Ce4+ is favoured because its noble gas configuration, but it is a strong oxidant due to the common +3 state. E° value Ce4+/ Ce3+ =+1.74 V
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संबंधित प्रश्न
Which among the following pairs of elements is 'not' an example of chemical twins?
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
Explain effects of lanthanoid contraction.
What are the consequences of lanthanoid contraction?
Explain the cause of Lanthanoids contraction.
Match the compounds/elements given in Column I with uses given in Column II.
| Column I (Compound/element) | Column II (Use) | |
| (i) | Lanthanoid oxide | (a) Production of iron alloy |
| (ii) | Lanthanoid | (b) Television screen |
| (iii) | Misch metal | (c) Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
| (f) In X-ray screen |
On the basis of Lanthanoid contraction, explain the following:
Radii of 4d and 5d block elements.
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
Write a note on lanthanoids.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
