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प्रश्न
On the basis of Lanthanoid contraction, explain the following:
Radii of 4d and 5d block elements.
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उत्तर
As an effect of lanthanide contraction, zirconium and hafnium have similar radius of 160 pm and 159 pm respectively. Due to this similarity in their size, they show similar physical and chemical properties. Lanthanoid contraction: Because the elements in Row 3 have 4f electrons. These electrons do not shield good, causing a greater nuclear charge. This greater nuclear charge has a greater pull on the electrons and result in the decrease in their size and atomic radii.
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संबंधित प्रश्न
What are chemical twins? Write ‘two’ examples.
What are lanthanoids?
Which among the following pairs of elements is 'not' an example of chemical twins?
Account for the following :
Zr and Hf have almost similar atomic radii.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
Write the different oxidation states of iron
Account for the following:
Zn, Cd and Hg are soft metals.
What is the action of the following on lanthanoids?
a. water
b. Sulphur, heat
c. nitrogen, heat
The f-block elements are known as ____________.
Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?
On the basis of Lanthanoid contraction, explain the following:
Nature of bonding in \[\ce{La2O3}\] and \[\ce{Lu2O3}\] .
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.
Write any two consequences of Lanthanoid Contraction.
Cerium (Z = S8) is an important member of lanthanoids. Which of the following statements about cerium is incorrect?
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.
Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.
Reason: Lanthanoids do not show Lanthanoid contraction.
