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On the basis of Lanthanoid contraction, explain the following: Trends in acidic character of lanthanoid oxides. - Chemistry

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प्रश्न

On the basis of Lanthanoid contraction, explain the following:

Trends in acidic character of lanthanoid oxides.

दीर्घउत्तर
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उत्तर

Acidic or basic character of oxides is related to the nature of oxides. As we move along the lanthanide series from \[\ce{La}\] to \[\ce{Lu}\], the covalent character increases. 

Therefore, their basic character decreases or acidic character increases. 

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 67.(e) | पृष्ठ ११५

संबंधित प्रश्न

What are chemical twins? Write ‘two’ examples.


Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.


Write the electronic configurations of the element with the atomic number 61.


Write the different oxidation states of iron


Explain effects of lanthanoid contraction.


What is the action of the following on lanthanoids?
a. water
b. Sulphur, heat
c. nitrogen, heat


Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]


Match the compounds/elements given in Column I with uses given in Column II.

  Column I (Compound/element) Column II (Use)
(i)  Lanthanoid oxide (a) Production of iron alloy
(ii)  Lanthanoid (b) Television screen
(iii)  Misch metal (c) Petroleum cracking
(iv)  Magnesium based alloy is constituent of (d) Lanthanoid metal + iron
(v)  Mixed oxides of lanthanoids are employed (e) Bullets
    (f) In X-ray screen

Match the statements given in Column I with the oxidation states given in Column II.

  Column I Column II
(i) Oxidation state of Mn in MnO2 is (a) + 2
(ii) Most stable oxidation state of Mn is (b) + 3
(iii) Most stable oxidation state of  (c) + 4
  Mn in oxides is (d) + 5
(iv) Characteristic oxidation state of lanthanoids is (e) + 7

On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].


How would you account for the following:

There is a greater range of oxidation states among the actinoids than among the lanthanides.


The titanium (Z = 22) compound that does not exist is:-


Write any two consequences of Lanthanoid Contraction.


Mischmetal is an alloy consisting mainly of ______.


Cerium (Z = S8) is an important member of lanthanoids. Which of the following statements about cerium is incorrect?


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