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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Answer the following question: Which element of the first transition series has highest second ionisation enthalpy?

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प्रश्न

Answer the following question:

Which element of the first transition series has highest second ionisation enthalpy?

दीर्घउत्तर
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उत्तर

Out of all the elements of the first transition series copper has the highest second ionisation enthalpy.

Electronic configuration of Copper is: \[\ce{3d^10 4s^1}\]

After the Loss of first electron from the 4s copper acquires \[\ce{3d^10}\] configuration which is stable. Therefore, removal of second electron from the field 3-D orbital is very difficult and requires high amount of energy.

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(i).(a) | पृष्ठ ११५

संबंधित प्रश्न

What are interstitial compounds?


Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?


What are the characteristics of the transition elements and why are they called transition elements?


Write down the number of 3d electrons in the following ion:

Cu2+

Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ion (octahedral).


Complete and balance the following chemical equations

`Fe^(2+) + MnO_4^(-) + H^+ ->`


Two metallic elements A and B have the following standard oxidation potentials: A = 0·40v B = - 0·80v. What would you expect if element A was added to an aqueous salt solution of element B? Give a reason for your answer.


Explain why transition elements form alloys.


Explain why Mn2+ is more stable than Fe2+ towards oxidation to +3 state. (At. no. of Mn = 25, Fe = 26)


\[\ce{KMnO4}\] acts as an oxidising agent in acidic medium. The number of moles of \[\ce{KMnO4}\] that will be needed to react with one mole of sulphide ions in acidic solution is ______.


The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is ______.


Transition metals can act as catalysts because these can change their oxidation state. How does \[\ce{Fe(III)}\] catalyse the reaction between iodide and persulphate ions?


Why are all copper halides known except that copper iodide?


The electrode potential of M2+/M of 3d-series elements shows the positive value for ______.


In the ground state of atomic Fe (Z = 26), the spin-only magnetic moment is ______ × 10-1 BM.
(Round off to the nearest integer).

[Given: `sqrt3 = 1.73, sqrt2 = 1.41`]


Which one among the following metals of the 3d series has the lowest melting point?


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


What is the oxidation state of chromium in chromate ion and dichromate ion?


Explain the magnetic properties of d-block (or transition) elements.


For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


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