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Answer the following question: Which element of the first transition series has highest second ionisation enthalpy? - Chemistry

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प्रश्न

Answer the following question:

Which element of the first transition series has highest second ionisation enthalpy?

दीर्घउत्तर
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उत्तर

Out of all the elements of the first transition series copper has the highest second ionisation enthalpy.

Electronic configuration of Copper is: \[\ce{3d^10 4s^1}\]

After the Loss of first electron from the 4s copper acquires \[\ce{3d^10}\] configuration which is stable. Therefore, removal of second electron from the field 3-D orbital is very difficult and requires high amount of energy.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(i).(a) | पृष्ठ ११५

संबंधित प्रश्‍न

Calculate magnetic moment of  `Fe_((aq))^(2+) ion (Z=26).`


Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


Give reasons:

Transition metals show variable oxidation states.


The `E_((M^(2+)//M))^Θ` value for copper is positive (+0.34 V). What is possibly the reason for this? (Hint: consider its high ΔaHΘ and low ΔhydHΘ)


Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{ (aq)}}\] ion (Z = 27).


How would you account for the following: 

The d1 configuration is very unstable in ions.


Write the factors which are related to the colour of transition metal ions.


Give reasons: 

E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.


Give reasons for the following:

The transition metals generally form coloured compounds.


Electronic configuration of Mn2+ is ____________.


Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment?

(i) \[\ce{Co^{2+}}\]

(ii) \[\ce{Cr^{2+}}\]

(iii) \[\ce{Mn^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]


Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]


Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?


Match the catalysts given in Column I with the processes given in Column II.

Column I (Catalyst) Column II (Process)
(i) \[\ce{Ni}\] in the presence of hydrogen (a) Zieglar Natta catalyst
(ii) \[\ce{Cu2C12}\] (b) Contact process
(iii) \[\ce{V2O5}\] (c) Vegetable oil to ghee
(iv) Finely divided iron (d) Sandmeyer reaction
(v) \[\ce{TiCl4 + Al (CH3)3}\] (e) Haber's Process
  (f) Decomposition of KCIO3

Answer the following question:

Which element of the first transition series has highest third ionisation enthalpy?


Identify the metal and justify your answer.

Carbonyl \[\ce{M(CO)5}\]


Photographic film and plates have - au essential ingredient of


Account for the following:

Ce4+ is a strong oxidising agent.


Which one among the following metals of the 3d series has the lowest melting point?


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