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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How would you account for the following : Transition metals form coloured compounds

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प्रश्न

How would you account for the following : Transition metals form coloured compounds

Explain The transition metals generally form coloured compounds.

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उत्तर १

In the presence of ligands, the d-orbitals of transition metal ions split up into two sets of orbitals having different energies. Thus, the transition of electrons takes place from one set to another. The energy required for these transitions is quite less and falls in the visible region of radiation. The ions of transition metals absorb the radiation of a particular wavelength and the rest is reflected, imparting colour to the solution.

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उत्तर २

Most of the complexes of transition metals are coloured. This is because of the absorption of radiation from visible light region to promote an electron from one of the d−orbitals to another. In the presence of ligands, the d-orbitals split up into two sets of orbitals having different energies. Therefore, the transition of electrons can take place from one set toanother. The energy required for these transitions is quite small and falls in the visible region of radiation. The ions of transition metals absorb the radiation of a particular wavelength and the rest is reflected, imparting colour to the solution

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2014-2015 (March) Delhi Set 1

संबंधित प्रश्‍न

Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?


What may be the stable oxidation state of the transition element with the following d electron configuration in the ground state of its atom?

3d3


Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.


An antifriction alloy made up of antimony with tin and copper, which is extensively used in machine bearings is called _______.

(A) Duralumin

(B) Babbitt metal

(C) Spiegeleisen

(D) Amalgam


NF3 is possible, but NF5 is not. Why?


Give reasons: 

E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.


In lake test for Al3+ ions, there is the formation of coloured ‘floating lake’. It is due to ______.


Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment?

(i) \[\ce{Co^{2+}}\]

(ii) \[\ce{Cr^{2+}}\]

(iii) \[\ce{Mn^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]


Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]


Identify A to E and also explain the reactions involved.


Which does not belong to first transition series?


Photographic film and plates have - au essential ingredient of


Why are all copper halides known except that copper iodide?


Account for the following:

Transition metals form alloys.


The value of Δ0 for \[\ce{RhCl^{3-}6}\] is 243 KJ/mol which wavelength of light will promote an electron from. The colour of the complex is ______.


In the ground state of atomic Fe (Z = 26), the spin-only magnetic moment is ______ × 10-1 BM.
(Round off to the nearest integer).

[Given: `sqrt3 = 1.73, sqrt2 = 1.41`]


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


Explain the magnetic properties of d-block (or transition) elements.


Account for the following:

Zirconium (Zr) and Hafnium (Hf) are difficult to separate.


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