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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Nf3 is Possible, but Nf5 is Not. Why? - Chemistry

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प्रश्न

NF3 is possible, but NF5 is not. Why?

एका वाक्यात उत्तर
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उत्तर

According to the electronic configuration of nitrogen, it does not have 3d orbital that's why it can't expand the valency up to 5 and does not form .
N does not have vacant d orbitals. Hence, there is no excitation of ns2 electron to vacant orbitals. Thus, has only three unpaired electrons in p-orbitals showing +3 oxidation state and not +5 in halides like other elements of group.

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2012-2013 (October)

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