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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

When acidified KX2CrX2OX7 solution is added to SnX2+ salts then SnX2+ changes to ______.

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प्रश्न

When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.

पर्याय

  • \[\ce{Sn}\]

  • \[\ce{Sn^{3+}}\]

  • \[\ce{Sn^{4+}}\]

  • \[\ce{Sn+}\]

MCQ
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उत्तर

When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to \[\ce{Sn^{4+}}\].

Explanation:

\[\ce{Cr2O7^{2-} + 14H^+ + 3Sn^{2+} -> 2Cr^{3+} + 3Sn^{4+} + 7H2O}\]

In the above redox reaction, oxidation of \[\ce{Sn^{2+}}\] is taking place. It gets converted to \[\ce{Sn^{4+}}\] whereas, reduction of chromium is occurring from +6 oxidation state to +3. 

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 18 | पृष्ठ १०८

संबंधित प्रश्‍न

Calculate magnetic moment of  `Fe_((aq))^(2+) ion (Z=26).`


In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?


Give reasons:

Transition metals show variable oxidation states.


The \[\ce{E^{\circ}_{(M^{2+}/M)}}\] value for copper is positive (+0.34 V). What is possible reason for this? (Hint: consider its high ΔaH° and low ΔhydH°)


Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{( aq)}}\] ion (Z = 27).


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


How would you account for the following:

The d1 configuration is very unstable in ions.


Use Hund’s rule to derive the electronic configuration of Ce3+ ion and calculate its magnetic moment on the basis of ‘spin-only’ formula.


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Electronic configurations


Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.


Give reasons for the following:

The transition metals generally form coloured compounds.


Transition metals with highest melting point is ____________.


Read the passage given below and answer the following question:

The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.

In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.

Assertion: Cations of transition elements occur in various valence states.

Reason: Large number of oxides of transition elements are possible.


\[\ce{KMnO4}\] acts as an oxidising agent in acidic medium. The number of moles of \[\ce{KMnO4}\] that will be needed to react with one mole of sulphide ions in acidic solution is ______.


Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]


When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.


Consider the following standard electrode potentials (E° in volts) in aqueous solution:

Element M3+/M M+/M
Al - 1.66 +0.55
Tl + 1.26 -0.34

Based on these data, which of the following statements is correct?


Account for the following:

Sc3+ is colourless whereas Ti3+ is coloured in an aqueous solution.


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


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