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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

When acidified KX2CrX2OX7 solution is added to SnX2+ salts then SnX2+ changes to ______.

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प्रश्न

When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.

पर्याय

  • \[\ce{Sn}\]

  • \[\ce{Sn^{3+}}\]

  • \[\ce{Sn^{4+}}\]

  • \[\ce{Sn+}\]

MCQ
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उत्तर

When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to \[\ce{Sn^{4+}}\].

Explanation:

\[\ce{Cr2O7^{2-} + 14H^+ + 3Sn^{2+} -> 2Cr^{3+} + 3Sn^{4+} + 7H2O}\]

In the above redox reaction, oxidation of \[\ce{Sn^{2+}}\] is taking place. It gets converted to \[\ce{Sn^{4+}}\] whereas, reduction of chromium is occurring from +6 oxidation state to +3. 

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 18 | पृष्ठ १०८

संबंधित प्रश्‍न

Why do interstitial compounds have higher melting points than corresponding pure metals?


Explain why is Fe3+ more stable than Fe2+?


How would you account for the following? 

Transition metals exhibit variable oxidation states.

 


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element shows only +3 oxidation state?


How would you account for the following:

Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly oxidising.


Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.


The transition metals show _________ character because of the presence of unpaired· electrons and Cu+ is ____________ because of its electronic configuration is [Ar]3d10


Why do transition metal ions possess a great tendency to form complexes?


How is potassium dichromate prepared from chrome iron ore?


Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?


The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of \[\ce{Cr^{3+}}\] ion is ______.


Which of the following statements is not correct?


While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but reverse happens during the ionisation of the atom. Explain why?


Match the catalysts given in Column I with the processes given in Column II.

Column I (Catalyst) Column II (Process)
(i) \[\ce{Ni}\] in the presence of hydrogen (a) Zieglar Natta catalyst
(ii) \[\ce{Cu2C12}\] (b) Contact process
(iii) \[\ce{V2O5}\] (c) Vegetable oil to ghee
(iv) Finely divided iron (d) Sandmeyer reaction
(v) \[\ce{TiCl4 + Al (CH3)3}\] (e) Haber's Process
  (f) Decomposition of KCIO3

Account for the following:

Sc3+ is colourless whereas Ti3+ is coloured in an aqueous solution.


Which of the following transition metals shows +1 and +2 oxidation states?


Consider the following standard electrode potential values:

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V

\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V

What is the cell potential for the redox reaction?


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


Write the number of unpaired electrons in Cr3+.
(Atomic number of Cr = 24)


Give a reason for the following:

Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.


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