मराठी

Give Reasons: Sc3+ is Colourless in Aqueous Solution Whereas Ti3+ is Coloured.

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प्रश्न

Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.

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उत्तर १

Sc3+ has no unpaired electron. So, it is colourless, whereas Ti3+ has one unpaired electron. Hence, it is coloured

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उत्तर २

Compounds of transition elements are coloured due to the presence of unpaired electrons in d-orbitals as they show d-d-transition. In Sc+3 there are no d-electrons in Ti+3 there is one d-electrons.

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2017-2018 (March) Delhi Set 1

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.


How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.


Which of the following statements is not correct?


A solution of \[\ce{KMnO4}\] on reduction yields either a colourless solution or a brown precipitate or a green solution depending on pH of the solution. What different stages of the reduction do these represent and how are they carried out?


EΘ of Cu is + 0.34V while that of Zn is – 0.76V. Explain.


A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) and (C) of manganese are formed. Compound (C) reacts with KOH in the presence of potassium nitrate to give compound (B). On heating compound (C) with conc. \[\ce{H2SO4}\] and \[\ce{NaCl}\], chlorine gas is liberated and a compound (D) of manganese along with other products is formed. Identify compounds A to D and also explain the reactions involved.


It has been observed that first ionization energy of 5 d series of transition elements are higher than that of 3d and 4d series, explain why?


The complex showing a spin-span magnetic moment of 2.82 B.M. is :-


Assertion (A): Transition metals have high enthalpy of atomisation.

Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.


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