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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Which of the following statements is not correct? - Chemistry

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प्रश्न

Which of the following statements is not correct?

पर्याय

  • Copper liberates hydrogen from acids.

  • In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine.

  • \[\ce{Mn^{3+}}\] and \[\ce{Co^{3+}}\] are oxidising agents in aqueous solution.

  • \[\ce{Ti^{2+}}\] and \[\ce{Cr^{2+}}\]  are reducing agents in aqueous solution.

MCQ
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उत्तर

Copper liberates hydrogen from acids.

Explanation:

Copper does not liberate hydrogen from acids.

\[\ce{Cu + 2H2SO4 -> CuSO4 + SO2 + 2H2O}\]

\[\ce{3Cu + 8HNO3 -> 3Cu (NO3)2 + 2NO + 4H2O}\]

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 17 | पृष्ठ १०८

संबंधित प्रश्‍न

Explain why is Fe3+ more stable than Fe2+?


How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?


Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iodide.


Dissociation of H2S is suppressed in acidic medium.


Which is the most stable oxidation state of iron?


Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?


Generally transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compounds will be coloured in solid-state?


Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment?

(i) \[\ce{Co^{2+}}\]

(ii) \[\ce{Cr^{2+}}\]

(iii) \[\ce{Mn^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]


Why first ionisation enthalpy of Cr is lower than that of Zn?


Although \[\ce{Cr^3+}\] and \[\ce{Co^2+}\] ions have same number of unpaired electrons but the magnetic moment of \[\ce{Cr^3+}\] is 3.87 B.M. and that of \[\ce{Co^2+}\] is 4.87 B.M. Why?


Answer the following question:

Which element of the first transition series has lowest enthalpy of atomisation?


Account for the following: 

In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.


Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Why is Carbon-14 radioactive while Carbon-12 not? (Atomic number of Carbon: 6)


On adding NaOH, solution to the aqueous solution of K2CrO7 the colour of the solution changes from


Give reason for the following statement:

Physical and chemical properties of the 4d and 5d series of the transition elements are quite similar to expected.


Consider the following standard electrode potentials (E° in volts) in aqueous solution:

Element M3+/M M+/M
Al - 1.66 +0.55
Tl + 1.26 -0.34

Based on these data, which of the following statements is correct?


Which of the following characteristics of transition metals is associated with their catalytic activity?


The trend of which property is represented by the following graph?


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with H2S.


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