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Why is HCl not used to make the medium acidic in oxidation reactions of KMnOX4 in acidic medium? - Chemistry

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प्रश्न

Why is \[\ce{HCl}\] not used to make the medium acidic in oxidation reactions of \[\ce{KMnO4}\] in acidic medium?

पर्याय

  • Both \[\ce{HCl}\] and \[\ce{KMnO4}\] act as oxidising agents.

  • \[\ce{KMnO4}\] oxidises \[\ce{HCl}\] into \[\ce{Cl2}\] which is also an oxidising agent.

  • \[\ce{KMnO4}\] is a weaker oxidising agent than \[\ce{HCl}\].

  • \[\ce{KMnO4}\] acts as a reducing agent in the presence of \[\ce{HCl}\].

MCQ
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उत्तर

\[\ce{KMnO4}\] oxidises \[\ce{HCl}\] into \[\ce{Cl2}\] which is also an oxidising agent.

Explanation:

\[\ce{HCl}\] is not used to make the medium acidic in oxidation reactions of \[\ce{KMnO4}\] in acidic medium. The reason is that if \[\ce{HCl}\] is used, the oxygen produced from \[\ce{KMnO4 + HCl}\] is partly utilized in oxidizing \[\ce{HCl}\] to \[\ce{Cl}\], which itself acts as an oxidizing agent and partly oxidises the reducing agent.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १०९]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 21 | पृष्ठ १०९

संबंधित प्रश्‍न

The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Write the element which shows maximum number of oxidation states. Give reason.


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element has the highest m.p?


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element is a strong oxidising agent in +3 oxidation state and why?


How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.


Complete and balance the following chemical equations

`MnO_4^(-) + H_2O + I^(-) ->`


Explain why transition metals and their compounds act as a catalyst.


Transition metals with lowest melting point is ______.


Maximum oxidation state is shown by ____________.


The halides of transition elements become more covalent with increasing oxidation state of the metal. Why?


Assertion: Separation of \[\ce{Zr}\] and \[\ce{Hf}\] is difficult.

Reason: Because \[\ce{Zr}\] and \[\ce{Hf}\] lie in the same group of the periodic table.


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


Account for the following: 

In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.


Which of the following is non-metallic?


Which one of the following characters tie of the transition metal is associated with higher catalytic activity?


Agcl is soluble in NH4OH. The solubility is due to the information of:-


The disproportionation of \[\ce{MnO^{2-}_4}\] in acidic medium resulted in the formation of two manganese compounds A and B. If the oxidation state of Mn in B is smaller than that of A, then the spin-only magnetic moment (µ) value of B in BM is ______. (Nearest integer)


Write the number of unpaired electrons in Cr3+.
(Atomic number of Cr = 24)


Account for the following:

Eu2+ with electronic configuration [Xe]4f76s2 is a strong reducing agent.


The compounds of \[\ce{Ti^4+}\] ions are colourless due to ______.


Give a reason for the following:

Transition metals possess a great tendency to form complex compounds.


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