Advertisements
Advertisements
Question
Which of the following statements is not correct?
Options
Copper liberates hydrogen from acids.
In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine.
\[\ce{Mn^{3+}}\] and \[\ce{Co^{3+}}\] are oxidising agents in aqueous solution.
\[\ce{Ti^{2+}}\] and \[\ce{Cr^{2+}}\] are reducing agents in aqueous solution.
Advertisements
Solution
Copper liberates hydrogen from acids.
Explanation:
Copper does not liberate hydrogen from acids.
\[\ce{Cu + 2H2SO4 -> CuSO4 + SO2 + 2H2O}\]
\[\ce{3Cu + 8HNO3 -> 3Cu (NO3)2 + 2NO + 4H2O}\]
APPEARS IN
RELATED QUESTIONS
Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{ (aq)}}\] ion (Z = 27).
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?
What are the characteristics of the transition elements and why are they called transition elements?
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iodide.
Predict which of the following will be coloured in the aqueous solution?
Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.
Dissociation of H2S is suppressed in acidic medium.
The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.
Explain why Zn2+ salts are white whereas Cu2+ salts are coloured.
Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.
Why first ionisation enthalpy of Cr is lower than that of Zn?
Explain why does colour of \[\ce{KMNO4}\] disappear when oxalic acid is added to its solution in acidic medium.
Mercury is the only metal liquid at room temperature due to its:-
Passing H2S gas into a mixture of Mn2+ and Ni2+, Cu2+, ions in an acidified aqueous solution precipitates.
Give reasons for the following statement:
Transition metals and most of their compounds show paramagnetic behaviour.
A transition element X has an electronic configuration [Ar]4s23d3. Predict its likely oxidation states.
The trend of which property is represented by the following graph?

The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.
What is the oxidation state of chromium in chromate ion and dichromate ion?
For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:
| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
Decide which of the following atomic numbers are the atomic numbers of the inner transition elements:
29, 59, 74, 95, 102, 104
