Advertisements
Advertisements
Question
On the basis of the figure given below, answer the following questions:

- Why Manganese has lower melting point than Chromium?
- Why do transition metals of 3d series have lower melting points as compared to 4d series?
- In the third transition series, identify and name the metal with the highest melting point.
Advertisements
Solution
- Manganese is having lower melting point as compared to chromium, as it has highest number of unpaired electrons, strong interatomic metal bonding, hence no delocalisation of electrons.
- There is much more frequent metal-metal bonding in compounds of the heavy transition metals i.e 4d and 5d series, which accounts for lower melting point of 3d series.
- Tungsten
APPEARS IN
RELATED QUESTIONS
How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.
Account for the following :
Ti4+ is colourless whereas V4+ is coloured in an aqueous solutions.
Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?
Which of the following will not act as oxidising agents?
(i) \[\ce{CrO3}\]
(ii) \[\ce{MoO3}\]
(iii) \[\ce{WO3}\]
(iv) \[\ce{CrO^{2-}4}\]
The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?
While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but reverse happens during the ionisation of the atom. Explain why?
Assertion: The highest oxidation state of osmium is +8.
Reason: Osmium is a 5d-block element.
The electrode potential of M2+/M of 3d-series elements shows the positive value for ______.
Which of the following ions has the electronic configuration 3d6?
(Atomic number: Mn = 25, Co = 27, Ni = 28)
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iron (II) solution.
