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Question
Assertion: The highest oxidation state of osmium is +8.
Reason: Osmium is a 5d-block element.
Options
Both assertion and reason are true, and reason is the correct explanation of the assertion.
Both assertion and reason are true but reason is not the correct explanation of assertion.
Assertion is not true but reason is true.
Both assertion and reason are false.
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Solution
Both assertion and reason are true but reason is not the correct explanation of assertion.
Explanation:
Osmium has the capacity to expands its octet by utilising all the electrons from its 6s and 5d orbitals this results it attaining an oxidation state of +8.
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RELATED QUESTIONS
ln which pair highest oxidation states of transition metals are found:
|
`E_((M^(2+)/M)` |
Cr | Mn | Fe | Co | Ni | Cu |
| -0.91 | -1.18 | -0.44 | -0.28 | -0.25 | -0.34 |
From the given data of E0 values, answer the following questions :
(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive
(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements
(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.
Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?
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| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
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