English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which is a stronger reducing agent, Cr2+ or Fe2+ and why?

Advertisements
Advertisements

Question

Which is a stronger reducing agent, Cr2+ or Fe2+ and why?

Short Answer
Advertisements

Solution

Cr2+ is a stronger reducing agent than Fe2+. In the formation of Cr2+ to Cr3+, the change is d4 to d3, but in the formation of Fe2+ to Fe3+, the change is d6 to d5. In a medium like water, d3 is more stable than d5.

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: The d-block and f-block Elements - Intext Question [Page 101]

APPEARS IN

NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Intext Question | Q 4.7 | Page 101

RELATED QUESTIONS

Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?


Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?


Give reasons: 

E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.


Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.


Maximum magnetic moment is shown by ____________.


Maximum oxidation state is shown by ____________.


A solution of \[\ce{KMnO4}\] on reduction yields either a colourless solution or a brown precipitate or a green solution depending on pH of the solution. What different stages of the reduction do these represent and how are they carried out?


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i)  An element which can show +8 oxidation state (a) \[\ce{Mn}\]
(ii)  3d block element that can show (b) \[\ce{Cr}\]
  upto +7 oxidation state (c) \[\ce{Os}\]
(iii)  3d block element with highest melting point (d) \[\ce{Fe}\]

Assertion (A): Cu cannot liberate hydrogen from acids.

Reason (R): Because it has positive electrode potential.


When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised from the solution. When compound (C) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the reactions.


Identify the metal and justify your answer.

\[\ce{MO3F}\]


The spin magnetic moment of cobalt in the compound Hg [Co(SCN)4] is:-


Which does not belong to first transition series?


Which of the following ions acts as a typical transition metal ion?


The oxidation state of Fe in [Fe(CO)5] is ______.


Which one among the following metals of the 3d series has the lowest melting point?


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×