English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Identify A to E and also explain the reactions involved.

Advertisements
Advertisements

Question

Identify A to E and also explain the reactions involved.

Long Answer
Advertisements

Solution

A = \[\ce{Cu}\]

B = \[\ce{Cu(NO3)2}\]

C = \[\ce{[Cu(NH3)4]}\]

D = \[\ce{CO2}\]

E = \[\ce{CaCO3}\]

F = \[\ce{Cu2[Fe(CN)6]}\]

G = \[\ce{Ca (HCO3)2}\]

\[\ce{CuCO3 -> CuO + CO2}\]

\[\ce{CuO + CuS -> \underset{(A)}{Cu} + SO2}\]

\[\ce{Cu + 4HNO3 (Conc) -> Cu \underset{(B)}{(NO3)2} + 2NO + 2H2O}\]

\[\ce{\underset{(B)}{Cu^2+} + NH3 -> \underset{(C)}{[Cu(NH3)4]}}\]

\[\ce{Ca(OH)2 + \underset{(D)}{CO2} -> \underset{(E)}{CaCO3} + H2O}\]

\[\ce{CaCO3 + CO2 + H2O -> Ca(HCO3)2}\]

shaalaa.com
  Is there an error in this question or solution?
Chapter 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [Page 114]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 64 | Page 114

RELATED QUESTIONS

The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element has the highest m.p?


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element shows only +3 oxidation state?


Out of Mn3+ and Cr3+, which is more paramagnetic and why ?

(Atomic nos. : Mn = 25, Cr = 24)


What are inner transition elements?


Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.


Write balanced chemical equations for the conversion of `CrO_4^(2-)` to `Cr_2O_7^(2-)` in acidic medium and `Cr_2O_7^(2-)` to `CrO_4^(2-)`
 in basic medium.


Complete and balance the following chemical equations

`MnO_4^(-) + H_2O + I^(-) ->`


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


Read the passage given below and answer the following question:

The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.

In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.

Assertion: Crystal structure of oxides of transition metals often show defects.

Reason: Ligand field effect cause distortions in crystal structures.


Which of the following statements is not correct?


Which of the following will not act as oxidising agents?

(i) \[\ce{CrO3}\]

(ii) \[\ce{MoO3}\]

(iii) \[\ce{WO3}\]

(iv) \[\ce{CrO^{2-}4}\]


Match the solutions given in Column I and the colours given in Column II.

Column I
(Aqueous solution of salt)
Column II
(Colour)
(i) \[\ce{FeSO2.7H2O}\] (a) Green
(ii) \[\ce{NiCl2.4H2O}\] (b) Light pink
(iii) \[\ce{MnCl2.4H2O}\] (c) Blue
(iv) \[\ce{CoC12,6H2O}\] (d) Pale green
(v) \[\ce{Cu2 Cl2}\] (e) Pink
  (f) Colourless

Assertion: Separation of \[\ce{Zr}\] and \[\ce{Hf}\] is difficult.

Reason: Because \[\ce{Zr}\] and \[\ce{Hf}\] lie in the same group of the periodic table.


Catalytic hydrogenation of benzene gives


The spin magnetic moment of cobalt in the compound Hg [Co(SCN)4] is:-


The basic character of transition metals monoxide follow the order.


The value of Δ0 for \[\ce{RhCl^{3-}6}\] is 243 KJ/mol which wavelength of light will promote an electron from. The colour of the complex is ______.


Which of the following characteristics of transition metals is associated with their catalytic activity?


Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with H2S.


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Oxidation states


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×