Advertisements
Advertisements
Question
Write down the number of 3d electrons in the following ion:
Cu2+
Indicate how would you expect the five 3d orbitals to be occupied for this hydrated ions (octahedral).
Advertisements
Solution 1
| Metal ion | Number of d-electrons | Filling of d-orbitals |
| Cu2+ | 9 | \[\ce{t^6_{2g}e^3_g}\] |
Solution 2
Cu2+: 3d9
Filling of orbitals in an octahedral hydrated ion:
Cu2+: \[\ce{t^6_{2g}e^3_g}\]
| ↑↓ | ↑ | eg | |
| ↑↓ | ↑↓ | ↑↓ | t2g |
(1 unpaired electron)
RELATED QUESTIONS
How would you account for the following?
Transition metals exhibit variable oxidation states.
Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?
In what way is the electronic configuration of the transition elements different from that of the non-transition elements?
An analysis shows that FeO has a non-stoichiometric composition with formula Fe0.95O. Give reason.
Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.
Why do transition metal ions possess a great tendency to form complexes?
Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?
Why do transition metals exhibit higher enthalpy of atomization?
Two metallic elements A and B have the following standard oxidation potentials: A = 0·40v B = - 0·80v. What would you expect if element A was added to an aqueous salt solution of element B? Give a reason for your answer.
When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.
Identify A to E and also explain the reactions involved.

The element with atomic number 46 belongs to
The standard electrode potentials of four elements A, B, C and D are – 3.05, – 1.66, – 0.40 and + 0.80. The highest chemical reactivity will be exhibited by
Which of the following maxm magnetic moment?
The disproportionation of \[\ce{MnO^{2-}_4}\] in acidic medium resulted in the formation of two manganese compounds A and B. If the oxidation state of Mn in B is smaller than that of A, then the spin-only magnetic moment (µ) value of B in BM is ______. (Nearest integer)
Account for the following:
Sc3+ is colourless whereas Ti3+ is coloured in an aqueous solution.
Assertion (A): Transition metals have high enthalpy of atomisation.
Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.
Which one among the following metals of the 3d series has the lowest melting point?
The given graph shows the trends in melting points of transition metals:

Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.
A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.
Based on this information, answer the following question:
- Deduce the structural formula of the complex compound.
- Write the IUPAC name of the complex compound.
- Draw the geometrical isomers of the complex compound.
