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Account for the Following : 4 Ti4+ is Colourless Whereas 4 V  is Coloured in an Aqueous Solutions.

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Question

Account for the following : 
 Ti4+ is colourless whereas V4+  is coloured in an aqueous solutions. 

Sum
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Solution

`"_22 Ti = [Ar]3d  4s^2`
            22Ti4+ = [Ar]3d3 4S0  → No electrons for excitation so 4 Ti4+ is colourless. 
           23V = [Ar]3d3 4s2 

              V4+ = 3d1 4s0 → 1 electron is there for excitation and it impart blue colour in aquous

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2018-2019 (March) 56/3/2

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