English
Karnataka Board PUCPUC Science 2nd PUC Class 12

To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.

Advertisements
Advertisements

Question

To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.

Short Answer
Advertisements

Solution

  1. The ions in the oxidation state, in which the ions have fully filled or half-filled d shells, are more stable.
  2. For example, the +2 state of Mn is more stable than its other oxidation states.
  3. Because Mn2+ has a half-filled 3d5 shell. Similarly, the +2 state of Zn is its most stable state because it has a fully filled 3d10 shell.
shaalaa.com
  Is there an error in this question or solution?
Chapter 4: The d-block and f-block Elements - Exercises [Page 115]

APPEARS IN

NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Exercises | Q 4.4 | Page 115
Nootan Chemistry [English] Class 12 ISC
Chapter 4 d-and ƒ-Block Elements
'NCERT TEXT-BOOK, Exercises | Q 8.4 | Page 506

RELATED QUESTIONS

What are interstitial compounds?


Why do interstitial compounds have higher melting points than corresponding pure metals?


Which of the d-block elements may not be regarded as the transition elements?


Which one of the following ions is coloured?


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Account for the following : 
 Ti4+ is colourless whereas V4+  is coloured in an aqueous solutions. 


Explain why Zn2+ salts are white whereas Cu2+ salts are coloured.


When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.


Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.


When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


If enthalpies of formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm pressure are 52, – 394 and – 286 kJ/mol respectively, the change in ethalpy for combustion of C2H4 is equal to


Which of the following statements is not correct?


Give reasons for the following statement:

Zn, Cd, and Hg are soft metals.


Which of the following transition metals shows +1 and +2 oxidation states?


Assertion (A): Transition metals show their highest oxidation state with oxygen.

Reason (R): The ability of oxygen to form multiple bonds to metals.


Give a reason for the following:

Transition metals possess a great tendency to form complex compounds.


Account for the following:

Zirconium (Zr) and Hafnium (Hf) are difficult to separate.


‘Spin only’ magnetic moment is the same for which of the following ions?

  1. Ti3+
  2. Cr2+
  3. Mn2+
  4. Fe2+
  5. Sc3+

Choose the most appropriate answer from the options given below:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×