English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?

Advertisements
Advertisements

Question

Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?

Short Answer
Advertisements

Solution

  1. Copper (Cu) in the first series of transition metals most frequently exhibits the +1 oxidation state.
  2. This occurs because Cu has the electronic configuration [Ar] 3d10 4s1.
  3. When Cu forms the +1 ion (Cu+), it achieves a completely filled and very stable 3d10 configuration.
  4. The extra stability of the filled d-subshell makes the +1 oxidation state common for copper compared to other first transition metals.
shaalaa.com
  Is there an error in this question or solution?
Chapter 4: d-and ƒ-Block Elements - VERY SHORT ANSWER TYPE QUESTIONS [Page 496]

APPEARS IN

Nootan Chemistry [English] Class 12 ISC
Chapter 4 d-and ƒ-Block Elements
VERY SHORT ANSWER TYPE QUESTIONS | Q 54. | Page 496
Nootan Chemistry [English] Class 12 ISC
Chapter 4 d-and ƒ-Block Elements
'NCERT TEXT-BOOK, Exercises | Q 8.23 | Page 507
NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Exercises | Q 4.23 | Page 116

RELATED QUESTIONS

Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


What is meant by ‘disproportionation’? 


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Write balanced chemical equations for the conversion of `CrO_4^(2-)` to `Cr_2O_7^(2-)` in acidic medium and `Cr_2O_7^(2-)` to `CrO_4^(2-)`
 in basic medium.


Explain why transition metals and their compounds act as a catalyst.


\[\ce{KMnO4}\] acts as an oxidising agent in acidic medium. The number of moles of \[\ce{KMnO4}\] that will be needed to react with one mole of sulphide ions in acidic solution is ______.


Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]


While filling up of electrons in the atomic orbitals, the 4s orbital is filled before the 3d orbital but reverse happens during the ionisation of the atom. Explain why?


Assertion: \[\ce{Cu^2+}\] iodide is not known.

Reason: \[\ce{Cu^2+}\] oxidises \[\ce{I^-}\] to iodine.


Identify the metal and justify your answer.

\[\ce{MO3F}\]


If enthalpies of formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm pressure are 52, – 394 and – 286 kJ/mol respectively, the change in ethalpy for combustion of C2H4 is equal to


Mercury is the only metal liquid at room temperature due to its:-


The product of oxidation of I with \[\ce{MnO^{-}4}\] in alkaline medium is:-


A complex in which dsp2 hybridisation takes place is ______.


Why is the `"E"_(("V"^(3+)//"V"^(2+)))^"o"` value for vanadium comparatively low?


The trend of which property is represented by the following graph?


What is the oxidation state of chromium in chromate ion and dichromate ion?


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Ionisation enthalpies


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×