English

Account for the following: Cu+ ion is unstable in aqueous solution.

Advertisements
Advertisements

Question

Account for the following:

Cu+ ion is unstable in aqueous solution.

Short/Brief Note
Advertisements

Solution

Cu2+ is more stable than Cu+ in aqueous medium. Cu2+ has high hydration energy that compensates for the energy required to remove one electron from Cu+ to form Cu2+. So in aqueous medium, Cu+ gives Cu2+ and Cu.

Chemical reaction: \[\ce{2Cu^+_{( aq)} -> Cu^{2+}_{ (aq)} + Cu_{(s)}}\]

shaalaa.com
  Is there an error in this question or solution?
2014-2015 (March) Patna Set 2

Video TutorialsVIEW ALL [1]

RELATED QUESTIONS

Why do interstitial compounds have higher melting points than corresponding pure metals?


Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


The \[\ce{E^{\circ}_{(M^{2+}/M)}}\] value for copper is positive (+0.34 V). What is possible reason for this? (Hint: consider its high ΔaH° and low ΔhydH°)


To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.


How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.


How would you account for the following? 

Transition metals and their compounds act as catalysts.


The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?


When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised from the solution. When compound (C) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the reactions.


Catalytic hydrogenation of benzene gives


In the ground state of atomic Fe (Z = 26), the spin-only magnetic moment is ______ × 10-1 BM.
(Round off to the nearest integer).

[Given: `sqrt3 = 1.73, sqrt2 = 1.41`]


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×