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प्रश्न
Account for the following:
Cu+ ion is unstable in aqueous solution.
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उत्तर
Cu2+ is more stable than Cu+ in aqueous medium. Cu2+ has high hydration energy that compensates for the energy required to remove one electron from Cu+ to form Cu2+. So in aqueous medium, Cu+ gives Cu2+ and Cu.
Chemical reaction: \[\ce{2Cu^+_{( aq)} -> Cu^{2+}_{ (aq)} + Cu_{(s)}}\]
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संबंधित प्रश्न
Account for the following:
E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.
Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:
Electronic configurations
Give reasons:
E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.
Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?
Give reasons for the following:
The transition metals generally form coloured compounds.
Assertion (A): Cu cannot liberate hydrogen from acids.
Reason (R): Because it has positive electrode potential.
Passing H2S gas into a mixture of Mn2+ and Ni2+, Cu2+, ions in an acidified aqueous solution precipitates.
Which of the following ions will exhibit colour in aqueous solution?
Give a reason for the following:
Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.
Match List-I with List-II.
| List-I | List-II |
| A. Haber process | I. Fe catalyst |
| B. Wacker oxidation | II. PdCl2 |
| C. Wilkinson catalyst | III. [(PPh3)3RhCl] |
| D. Ziegler catalyst | IV. TiCl4 with Al(CH3)3 |
Choose the correct answer from the options given below:
