Advertisements
Advertisements
प्रश्न
Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?
Advertisements
उत्तर
- Copper (Cu) in the first series of transition metals most frequently exhibits the +1 oxidation state.
- This occurs because Cu has the electronic configuration [Ar] 3d10 4s1.
- When Cu forms the +1 ion (Cu+), it achieves a completely filled and very stable 3d10 configuration.
- The extra stability of the filled d-subshell makes the +1 oxidation state common for copper compared to other first transition metals.
संबंधित प्रश्न
Which of the following cations are coloured in aqueous solutions and why ?
Sc3+, V3+, Ti4+, Mn2+ (At. Nos. Sc = 21, V = 23, Ti = 22, Mn = 25)
Calculate the number of unpaired electrons in the following gaseous ions:
Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in an aqueous solution?
Write the factors which are related to the colour of transition metal ions.
Dissociation of H2S is suppressed in acidic medium.
Two metallic elements A and B have the following standard oxidation potentials: A = 0·40v B = - 0·80v. What would you expect if element A was added to an aqueous salt solution of element B? Give a reason for your answer.
Which among the following transition metal has the lowest melting point?
The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition element, which shows highest magnetic moment.
Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic medium.
Answer the following question:
Which element of the first transition series has highest third ionisation enthalpy?
Transition metals can act as catalysts because these can change their oxidation state. How does \[\ce{Fe(III)}\] catalyse the reaction between iodide and persulphate ions?
The element with atomic number 53 belongs to
Match List - I with List - II.
| List - I | List - II | ||
| (A) | [Fe(CN)6]3− | (i) | 5.92 BM |
| (B) | [Fe(H2O)6]3+ | (ii) | 0 BM |
| (C) | [Fe(CN)6]4− | (iii) | 4.90 BM |
| (D) | [Fe(H2O)6]2+ | (iv) | 1.73 BM |
Choose the correct answer from the options given below.
Which one among the following metals of the 3d series has the lowest melting point?
Consider the following standard electrode potential values:
\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V
\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V
What is the cell potential for the redox reaction?
Which of the following ions has the electronic configuration 3d6?
(Atomic number: Mn = 25, Co = 27, Ni = 28)
The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.
Give a reason for the following:
Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.
A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.
Based on this information, answer the following question:
- Deduce the structural formula of the complex compound.
- Write the IUPAC name of the complex compound.
- Draw the geometrical isomers of the complex compound.
Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:
Atomic sizes
‘Spin only’ magnetic moment is the same for which of the following ions?
- Ti3+
- Cr2+
- Mn2+
- Fe2+
- Sc3+
Choose the most appropriate answer from the options given below:
